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171.
Poly(vinyl chloride) (PVC)-based membrane of pentathia-15-crown-5 exhibits good potentiometric response for Hg2+ over a wide concentration range (2.51 × 10−5 to 1.00 × 10−1 mol dm−3) with a slope of 32.1 mV per decade of Hg2+ concentration. The response time of the sensor is as fast as 20 s. The electrode has been used for a period of six weeks and exhibits fairly good discriminating ability towards Hg2+ in comparison to alkali, alkaline and some heavy metal ions. The electrode can be used in the pH range from 2.7 to 5.0. 相似文献
172.
An ultra-thin layer of polypyrrole can be coated on non-conducting substrates, e.g., acrylic, by dip coating into a colloidal suspension of polypyrrole. This thin coating reversibly combines with low concentrations of ammonia or hydrazine with a concomitant reversible increase in resistance; 0.1 μg cm?3 of ammonia can readily be detected with a 1 cm2 area of sensor. 相似文献
173.
M. D'Apuzzo A. Aronne S. Esposito P. Pernice 《Journal of Sol-Gel Science and Technology》2000,17(3):247-254
The sol-gel synthesis of silicophosphate gels using phosphoryl chloride and tetraethoxysilane as molecular precursors is reported and discussed. Gel-derived glasses and films having the molar compositions 10P2O5 · 90SiO2 and 30P2O5 · 70SiO2 have been obtained. The structure of the dried gels as well as the structural modifications that occurs during the transformations in gel-derived glasses are analyzed by Fourier transform infrared spectroscopy (FTIR). It has been found that the evidence of the P—O—Si linkages begins to appear only on the FTIR spectra of the bulk gels heat treated up to 400°C while they are well resolved on the FTIR spectra of the bulk gel samples heated up to 1000°C indicating that at this temperature the transformation in the corresponding gel-derived glasses occurs. The humidity sensitive properties of the gel-films have been evaluated by electrochemical impedance spectroscopy (EIS). The phosphorous content as well as the temperature of the heat treatments strongly affect the sensitivity to RH of the gel-derived films. 相似文献
174.
J.F. Fernández-Sánchez C. Cruces-Blanco A. Fernández-Gutiérrez 《Analytica chimica acta》2004,506(1):1-7
We describe here a method for detecting and quantifying the highly carcinogenic polycyclic aromatic hydrocarbon (PAH) benzo[a]pyrene (BaP) in water, based on a flow-trough optical sensor. The technique is fast (response time of 40 s) and simple and at the same time meets the standards of sensitivity and selectivity required by the European Guidelines on Water for Human Consumption. The optosensor is based on the on-line immobilization of BaP on a non-ionic resin (Amberlite XAD-4) solid support in a continuous-flow system. BaP was analyzed in a 15 mM H2PO4−/HPO42− buffer solution with 25% (v/v) 1,4-dioxane at pH 7. Fluorescence intensity was measured at λex/em=392/406 nm. The experimental conditions (reagent phase, pH, type and concentration of buffer solution and organic solvent) and flow-injection values (flow rate and injection volume) were carefully controlled. Under these conditions the optosensor was sensitive to a linear concentration range of between 3.0 and 250.0 ng l−1 with a detection limit of 3.0 ng l−1 and a standard deviation of 1.5% at 150 ng l−1. The optosensor was applied to the quantification of BaP in drinking and waste water samples (95-105% recovery) in presence of the other 15 EPA PAHs at 1000 ng l−1 concentration level. The influence of other fluorescent polycyclic aromatic hydrocarbons and potential interference from ions usually present in water was also evaluated. 相似文献
175.
An improved version of the disposable multichannel immunochemical biosensor for the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) based on a screen-printed amperometric transducer and monoclonal antibodies (MAb) against 2,4-D is reported. Entrapment within a thin Nafion film was used for the direct immobilization of MAb at the electrode surface. The amount of the tracer (2,4-D conjugated to acetylcholinesterase) bound in a competitive immunochemical reaction was determined amperometrically using acetylthiocholine iodide as substrate. The measuring procedure (times of incubation with tracer and substrate, pH, tracer concentration) was optimized. The sensor was able to detect less than 0.01 μg/L of free 2,4-D in water. One analysis (8 samples) was completed in 30 min (20 min for immunochemical reaction, 5 min incubation with substrate, 5 min measurement). The performance of the immunosensor (two configurations) was evaluated on real samples (tap water) with added 2,4-D. The determined amounts (mean values 0.097 to 0.105 and 0.89 to 1.13) corresponded well with the added contents of 2,4-D (0.100 and 1.00 μg/L, respectively). 相似文献
176.
An amperometric artemisinin (ARN) sensor based on the supramolecular recognition of glycosylated metalloporphyrin, which is included in the Au-nanoparticles-chitosan film coated on the glass carbon electrodes, was developed. For the improvement of the selectivity of artemisinin detection, 5,10,15,20-tetrakis[2-(2,3,4,6-tetraacetyl-β-d-glucopyranosyl)-1-O-phenyl]porphyrin (T(o-glu)PPH) metal complex [FeT(o-glu)PPCl] was synthesized and employed as a ARN-sensitive and -selective material in the amperometric sensors. The proposed [FeT(o-glu)PPCl]/Au-nanoparticles modified electrodes showed excellent selectivity and sensitivity toward ARN with respect to a number of interferents and exhibited stable current response, which can be attributed to the coordination of ARN with the [FeT(o-glu)PPCl] in the electrodes. The calibration graph obtained with the proposed sensor was linear over the range of 1.8 × 10−7-1.7 × 10−9 mol l−1, with a detection limit of 1.7 × 10−9 mol l−1 for ARN. Significant advantages of the proposed procedure over the conventional reductive electrochemical methods are the selective detection and the relatively low applied potential requirement of the ARN-sensor. The prepared sensor is applied for the determination of ARN in plant samples and the results agreed with the values obtained by the pharmacopoeia method. 相似文献
177.
以苯乙烯-马来酸酐共聚物钠盐(Na-SMA)为湿敏材料,采用浸涂的方法,在小型叉指金电极上成膜,制备了高分子电阻型湿度传感器.研究了浸涂液组成对传感器响应特性的影响.研究表明,随着浸涂液中Na-SMA浓度的提高,元件的电阻、湿滞降低;而随着浸涂液中聚乙烯醇(PVA)浓度的提高,元件的电阻降低,湿滞增加. 相似文献
178.
光纤传感器及其应用研究 总被引:1,自引:0,他引:1
光纤传感器技术在现代检测及自动控制中的应用非常广泛,本文从光纤基本原理及光纤特性等方面,对光线的物理特性进行分析和研究,并利用其不同于传统传感器的优越性能,针对我省采矿工业的安全监控系统,提出一种全光网络的安全监控方法.此方法安全、可靠、精度高. 相似文献
179.
采用BP多层前馈神经网络及其改进算法对传感器特性进行补偿,有效地改善了BP传统算法收敛慢、容易收敛到局部最小点的缺陷,并编制了训练程序.结果表明,经BP改进算法处理后,传感器性能大幅度改善,网络的收敛速度更快,精度更高. 相似文献
180.
自主车辆视觉系统的摄像机动态自标定算法 总被引:3,自引:0,他引:3
为了解决自主车辆视觉传感器在姿态变化后摄像机旋转外参数的在线自标定问题,提出了一种利用道路图像消失点相对不变量的摄像机旋转外参数的动态自标定算法.它首先从汽车采集到的道路视频序列中实时分析道路消失点,然后依据中心极限定理并使用相应的统计量,动态地估计主消失点与消失线参数,最后利用小孔成像模型下的消失线与消失点方程,解析地求得对应于当前统计特征的摄像机外部参数动态解.实验结果表明,在摄像机进行姿态调整后,实验系统使用本算法可在不超过90帧有效图像样本的基础上,能对摄像机旋转外参数进行精确标定,使旋转外参数的绝对误差值收敛于0.001 rad的误差带之内. 相似文献