混凝土箱梁日照温度场仿真分析

混凝土箱梁的日照温度场可通过理论分析并进行仿真分析,建立箱梁的有限元分析模型,对箱梁的日照温度场进行仿真分析,分别对箱梁各结构面温度的时程变化和各结构面的温差分布情况进行分析.分析结果表明,顶板、底板、腹板外表面的最高温度均出现在14:00,各板内表面的出现最高温度相对于外表面存在滞后,出现时刻为20:00.箱梁各板在日照作用下会出现相应的横向温差,沿梁高方向的竖向温差在14:00达到15.69℃.     

美汉草（Meehania fargesii Levl）生物量分配分析

调查阔叶红松林林下早春开花植物美汉草(Meehania fargesii Levl)各个器官生物量分配变化情况.结果表明:在整个生长季节中,美汉草各器官生物量总体上呈现先增加后减少的趋势,5月初~7月初,根生长速率先快后慢,茎叶生长速率先慢后快,7月中旬以后各器官生物量逐渐减少;美汉草有性生殖的生殖分配占总生物量的比例较小(4%~6%);根冠比在5~6月不断上升,6~7月迅速下降,7月以后保持稳定;根和茎叶生物量分别与总生物量呈显著的线性正相关关系.分析显示:为了适应阔叶红松林林下的光照变化,在林分郁闭前,能量主要分配给地下部分;林分郁闭后,茎叶生长占主导.美汉草主要以营养繁殖为主,第2年的地下根状茎来自第1年地上茎的繁殖方式及生物量分配策略,可能是美汉草成为林下优势草本的重要原因.     

长江口崇明东滩风况统计分析

本文基于长江口崇明东滩气象站实测资料,给出逐月平均和主导风速及风向.观测资料和统计结果表明,从1月至12月,各月平均风速分别为4.2、4.6、4.9、4.9、4.7、4.4、4.9、4.9、4.5、4.0、4.1和4.3 m/s,平均风向分别为N、NE、NE、SE、SE、SE、S、SE、NE、NE、N和N.统计给出了各月第一、第二风向频率风,最大平均风速所在方位风,强风风向优势和风速优势风的风向、频率和平均速度.总体来看,长江口具有春夏季盛行东南风、秋冬季盛行偏北风的亚热带季风特征.强风频率有明显的季节性变化,3、4月和7、8月明显高于其他月份,且3、4月明显低于7、8月份,分别达到了0.8%和1.52%,相对应的平均风速为11.5和12.4 m/s.     

糖多孢红霉菌保藏过程中生理生化变化的研究

对糖多孢红霉菌菌种保藏过程中一些生理生化变化规律进行研究.采用氮蓝四唑还原法、愈创木酚法、紫外吸收法、硫代巴比妥酸(TBA)比色法和双组分分光光度计法,分别测定超氧化物歧化酶(SOD)、过氧化物酶(POD)、过氧化氢酶(CAT)的活性及丙二醛(MDA)与可溶性糖的含量.结果表明:在糖多孢红霉菌保藏过程中,SOD、POD、CAT酶活性与可溶性糖的含量随着菌种保藏时间的延长呈现先上升后下降,MDA随着时间的延长先下降再上升趋势.上述3种酶活性与MDA和可溶性糖含量的变化呈现出一定的规律,可以用SOD和MDA作为判断该菌种是否老化的一种生理生化指标.     

利用线性回归模型对季节指数的估计

利用季节虚拟变量建立回归模型,通过季节虚拟变量的参数估计间接地估计季节指数,并且利用模型进行了一些传统的季节指数方法无法进行的推断统计.这是一种分析季节指数和季节变动的新思路。     

Environmental changes reflected by n-alkanes of lake core in Nam Co on the Tibetan Plateau since 8.4 kaB.P.

The n-alkanes are extracted from NMLC-1 core that was drilled in the Nam Co, central Tibet. They are measured by using Gas Chromatography and Mass Spectrometry (GC/MS) for componential and quantitative analyses. According to the constructed depth-age model, the component and concentration of n-alkanes, together with total organic carbon (TOC), total nitrogen (TN) and carbonate are used to elu- cidate palaeoenvironmental changes of Nam Co during the past 8.4 ka. The results indicate that Holo- cene environment performs three stages in the lake area. In the stage of 8.4―6.7 kaB.P., it was warmer while precipitation slightly increased. This stage was ended by an obvious cold/dry event. During 6.7― 5.8 kaB.P., temperature increased rapidly and reached its maximum values at about 6.0 kaB.P. The environments were warm/wet optimum for the blooming of terrestrial plants and submerged aquatic plants. After that, temperature decreased continuously and showed the lowest values at about 3.0 kaB.P. From 2.9 kaB.P. to the present, temperature rose again but alternated with cold and warm. The lake area tended to be dry after 1.4 kaB.P. During 600―400 aB.P., the environmental feature was the reflection of Little Ice Age.     

Does a Reinforced Kinetic Macrocyclic Effect Exist? The Demetallation in Strong Acid of Copper(II) Complexes with Open and Cyclic Tetramines Containing a Piperazine Fragment

The demetallation in acidic solution of the Cu(II) complexes with open-chain and cyclic tetramines containing a piperazine unit (2 and 3) has been investigated in terms of its kinetic aspects and compared with the behaviour of unsubstituted counterparts (tetramines 1 and 4). The presence of the piperazine fragment slows demetallation of the open-chain-ligand complex owing to the activation barrier associated with the conformational change from boat-to-half-boat; however, it does not affect the demetallation of the macrocyclic complex, which involves the spontaneous boat-to-twist conformational change. Thus, lateral reinforcement of a cyclam-like ligand does not add any further contribution to the typical inertness in demetallation of macrocyclic complexes.     

Transport properties and microstructure changes of alumina coatings characterized by emanation thermal analysis

Emanation thermal analysis was used to characterize the thermal behaviour of alumina coatings as deposited on EUROFER 97 steel surface by filtered vacuum arc technique. Temperature ranges of the healing of cracks and structure irregularities observed by SEM were determined from the ETA results. Transport properties of the alumina coatings were assessed from the ETA results by the evaluation of radon diffusion parameters in the temperature range from 50 to 300°C. Healing microstructure irregularities of the alumina coatings can be expected in the range 300–700°C as indicated by the decrease of the radon release rate. From the ETA results it followed that the onset of healing the cracks observed by the SEM on the surface of one alumina coating sample can be expected at 430°C. Dedicated to Dr. K. Habersberger, Past-Chairman of the thermal analysis working group of the Czech Chemcial Society, at the occasion of his 75^th birthday     

Determination of Pharmaceuticals by Dynamic Cell Membrane Chromatography Coupled with High-Performance Liquid Chromatography

As a biological affinity chromatographic method, cell membrane chromatography (CMC) using a silica stationary phase covered with specific cell membrane has been used in screening active components. The innovation of this work is that the bioactive cell membrane and the chromatographic packing are mixed and absorbed for the first time to form the pre-column. The pre-column was placed in front of a C₁₈ column to create dynamic CMC online high-performance liquid chromatography (HPLC) system. The retention behavior and dynamic changes of pharmaceuticals were studied for this system. The results indicate that the retention time of the drug was increased and the symmetry factor reached the analytical level after the addition of the dynamic cell membrane pre-column. Therefore, the dynamic CMC coupled with HPLC system may be a potentially rapid and efficient drug analysis approach for the interaction of drug molecule and receptor on red blood cell membranes.     

The Photodecomposition of 1,l-Dichloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethylene (MPE), an Analogue of DDE

The solution-phase photodecomposition of l, l-dichloro-2,2-bis(5′-chloro-2′-methoxy-phenyl)ethylene (MPE) has been studied at an excitation wavelength of 313 nm in the presence of O₂ as well as in vacuum-degassed solutions. Only two non-volatile compounds are produced: 2,5-dichloro-3-(5′-chloro-2′-methoxyphenyl)benzofuran (BFD) and a minor product which was not identified. The BFD represents approximately 90% of the total non-volatiles. The volatile products were identified as CH₃Cl, CH₄ and HC1, with CH₃C1 being approximately 99.9 % of the total volatiles. Photolyses were carried out in C₆H₁₂ and CCI₄ solvents, the same products being observed in both solvents. Variation of MPE concentration has little or no effect on the relative quantum yield of decomposition. The photodecomposition of MPE does not follow the same pathway as the photodecomposition of DDE.