全文获取类型
收费全文 | 18995篇 |
免费 | 2748篇 |
国内免费 | 1116篇 |
专业分类
化学 | 2956篇 |
晶体学 | 169篇 |
力学 | 2123篇 |
综合类 | 187篇 |
数学 | 2869篇 |
物理学 | 3779篇 |
综合类 | 10776篇 |
出版年
2025年 | 80篇 |
2024年 | 354篇 |
2023年 | 347篇 |
2022年 | 426篇 |
2021年 | 473篇 |
2020年 | 534篇 |
2019年 | 507篇 |
2018年 | 471篇 |
2017年 | 618篇 |
2016年 | 646篇 |
2015年 | 713篇 |
2014年 | 1040篇 |
2013年 | 1156篇 |
2012年 | 1111篇 |
2011年 | 1148篇 |
2010年 | 860篇 |
2009年 | 1059篇 |
2008年 | 989篇 |
2007年 | 1134篇 |
2006年 | 1095篇 |
2005年 | 976篇 |
2004年 | 821篇 |
2003年 | 777篇 |
2002年 | 690篇 |
2001年 | 589篇 |
2000年 | 544篇 |
1999年 | 520篇 |
1998年 | 449篇 |
1997年 | 386篇 |
1996年 | 358篇 |
1995年 | 337篇 |
1994年 | 244篇 |
1993年 | 237篇 |
1992年 | 225篇 |
1991年 | 190篇 |
1990年 | 170篇 |
1989年 | 166篇 |
1988年 | 128篇 |
1987年 | 77篇 |
1986年 | 50篇 |
1985年 | 44篇 |
1984年 | 35篇 |
1983年 | 5篇 |
1982年 | 20篇 |
1981年 | 16篇 |
1980年 | 5篇 |
1979年 | 9篇 |
1971年 | 4篇 |
1957年 | 5篇 |
1955年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
81.
新型三球销移动副的间隙模型研究 总被引:6,自引:0,他引:6
为了研究含间隙机构的动力学特性 ,首先要建立运动副的间隙模型。目前常用的几种间隙模型都存在一定的不足 ,不完全符合实际运动。针对这几种模型中存在的问题 ,基于弹性接触理论 ,考虑副元素的非线性特征 ,建立了非线性等效弹簧和阻尼器 ,并给出了运动副力学描述方程。结合三球销移动副的特殊结构 ,建立了该运动副提供的力约束方程。通过仿真计算和实验研究 ,两者具有很好的一致性 ,证明了该模型的合理性和实用性。研究结果为含间隙运动副机构的动力学研究提供了理论基础。 相似文献
82.
83.
84.
85.
徐宝民 《华南理工大学学报(自然科学版)》1998,26(4):95-101
在文「1」的基础上,讨论了单电子晶体管在两态情况下,的散粒噪声的行为和噪声谱与各个 电路因子的关系,从而给出了优化单电子晶体管操作环境的一些重要结论:信噪比可以通过调节电路参数而得到抑制,通过调节门电压可以起到降低温度扰动的作用。 相似文献
86.
CH3COSbCl6催化四氢呋喃聚合的研究 总被引:4,自引:0,他引:4
CH_3COSbCl_6催化四氢呋喃聚合的研究栗方星,王红军,马克勤(南开大学化学系,天津,300071)关键词聚四氢呋喃,乙酰基六氯锑酸盐,表观聚合反应速率常数,五氯化锑THF聚合为平衡聚合反应应[1,2],文献报道[3,4]Et3OBF4、Et3O... 相似文献
87.
The elevated strain rate compressive response of closed-cell polyvinyl chloride (PVC) foam at various densities is investigated. Two loading directions, (i.e., parallel and perpendicular to foam rise direction) were considered to investigate structural anisotropy. The elevated strain rates tests (up to 200 s−1) were performed using a customized drop tower device. Engineering stress/strain behavior, energy dissipation, and maximum stress capacity were obtained for each density and compared against each other. Except for the lowest density of 45 kg/m3, strain rate effects were clearly observed through increased compressive strength and plateau stress when loading in the foam rise direction. The strain rate effect is more evident at higher densities. However, no significant strain rate effect was observed when loading perpendicular to the foam rise direction. Scanning electron microscopy (SEM) analysis showed that plastic hinges are the primary deformation mechanism for PVC foam cells. An analytical model has been calibrated using the experimental results and successfully predicted the mechanical response of the foam. Shape anisotropy has been measured employing the SEM images. The analytical approach was also able to predict the foam's anisotropic mechanical response. 相似文献
88.
Thomas R. Gengenbach Zoran R. Vasic Sheng Li Ronald C. Chatelier Hans J. Griesser 《Plasmas and Polymers》1997,2(2):91-114
The properties and composition of plasma polymer surfaces stored in air can change considerably over time, especially as a
result of oxidative reactions. When plasma polymers contain an element other than O, it is possible to probe for mechanisms
in addition to oxidation that contribute to the aging of the surface. Plasma polymers containing N were fabricated from either
1,3-diaminopropane (DAP),n-heptylamine (nHA), or allylamine (AA), and studied by X-ray photo-electron spectroscopy (XPS) and air/water contact angles
(CA). For each of the plasma polymers, a multiexponential increase in the O/C ratio was observed over time using XPS. The
N/C ratios remained constant (AA) or decreased somewhat (nHA and DAP). In contrast, the trends in CA values differed, declining
for the nHA surfaces, rising for the AA, and changing little for the DAP. Surface roughness, assessed by scanning tunnelling
or atomic force microscopy, did not change over time. The diverse adjustments in the polarity of each surface and the similar
compositional changes between them are reconcilable if the aging of the plasma polymer surface is a manifestation of the superposition
of concurrent oxidative reactions and partial surface reorientation; the former introduce polar groups and the latter transports
then from the surface to deeper regions beyond the CA probe depth but within the XPS analysis depth. These processes vary
between different plasma polymers. Data for the alkylamine plasma polymers is also compared with that for two plasma polymers
fabricated from methanol. The change in composition, but not polarity, of the DAP surface after 4 days of storage demonstrates
the importance of using multiple techniques to characterize the aging of plasma polymer surfaces. 相似文献
89.
DEEB MARJI KHAMIS ABBAS 《Journal of inclusion phenomena and macrocyclic chemistry》1997,27(4):269-277
The effect of 18-crown-6 and kryptofix (2,2,1) on the oxidation of triethylamine byaqueous ferricyanide ion has been studied at pH 4, 7, and 9.The macrocycle retarded the normal oxidation process at all pH values,the effect depending on the macrocyclic ligand concentration Kryptofix (2,2,1) had a greater effect than 18-crown-6 at all pHvalues in this study. For 18-crown-6, retardation decreases in the order pH 9 > 4 > 7 while forkryptofix it follows the order pH 9 > 7 > 4. 相似文献
90.
触头用银合金粉末的氧化性能和氧化后的组织结构 总被引:1,自引:0,他引:1
通过热重实验和扫描电子显微等方法,研究了4种触头用银合金粉末的氧化性能及氧化后的组织结构。发现Ag-Sn-RE合金粉末氧化以后,在粉末表层形成一层纯银层,其组织结构理想;它的氧化性能最好,适于制备触头材料。Ag-Sn-RE合金粉末的优良氧化性能与其氧化后理想的组织结构有关。稀土元素可以降低合金粉末的氧化温度,其它影响作用有待于进一步研究。 相似文献