三线交叉D梁施工过渡方法

为解决隧道近接施工极易造成的隧道塌方问题,以达成线新建铁路与既有线为依托,阐述了三线交叉D梁施工的过渡方法,即在保证既有线铁路和高速公路安全运营的前提下,对既有线下新建铁路右线路基进行D梁过渡爆破拆除.该方法很好地解决了施工时间紧、施工条件和施工环境受限的难点,为类似工程问题的解决提供了参考依据.     

特殊条件下巷道锚索支护结构与参数研究

现场采集五家沟矿5#煤层及顶板煤岩试样,实验室测定其力学参数。运用数值模拟方法,研究简式桁架锚索与单体锚索不同组合结构围岩控制效果,得出厚煤顶块裂煤巷简式桁架锚索关键支护参数。结合工程类比法设计5#煤层辅运大巷简式桁架锚索与单体锚索"交错布置"组合支护方案。实测顶底板相对移近量152 mm、两帮移近量125 mm,围岩控制效果良好。     

义马煤田煤矿水害规律与防治技术

为了掌握义马煤田水害规律以正确指导煤矿的防治水工作,分析研究了历次突水资料、地质构造、小煤矿分布、河流流经区域、主要含水层和隔水层、采煤厚度及采后导水裂隙发育情况等,指出:随着小煤矿的关闭、河道疏浚、浅部地裂缝充填和大矿采掘活动向深部转移,矿井主要水害由大气降水、地表河水和小窑水转化为顶板水;顶板水威胁主要在义马向斜的核部、采深大于700 m的区域,断层尖灭端和断层带富水性较强,顶板突水及其强度与采厚、周期来压关系密切。针对顶板水害,提出了采用"三图—双预测法"对顶板突水的水源、通道和强度做出预测和评价;采用井上下物探方法,圈出顶板疑似富水区,并进行采前预疏放;完善工作面排水系统,提高抗水灾能力等防治水技术。     

“Grafting through” polymerization involving surface-bound monomers

“Grafting through” polymerization represents copolymerization of free monomers in solution and polymerizable units bound to a substrate. Free polymer chains are formed initially in solution and can incorporate the surface-bound monomers, and thereby, get covalently bonded to the surface during the polymerization process. As more growing chains attach to the surface-bound monomers, an immobilized polymer layer is formed on the surface. We use a combination of computer simulation and experiments to comprehend this process for monomers bound to a flat impenetrable substrate. We concentrate specifically on addressing the effect of spatial density of the surface-bound monomers on the formation of the surface-attached polymers. We employ a lattice-based Monte Carlo model utilizing the bond fluctuation model scheme to provide molecular-level insight into the grafting process. For experimental validation, we create gradients of density of bound methacrylate units on flat silicon wafers using organosilane chemistry and carry out “grafting through” free radical polymerization initiated in bulk. We report that the proximity of the surface-bound polymerizable units promotes the “grafting through” process but prevents more free growing chains to “graft through'' the polymerizable units. The “grafting through” process is self-limiting in nature and does not affect the overall density of the surface-bound polymer layer, except in case of the highest theoretical packing density of surface-bound monomers. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 263–274     

石圪台煤矿71203工作面过断层分析

介绍了71203工作面断层情况及前期准备工作,阐述了综采过断层的工艺,指出在断层部分进行回采卧底留顶快速直推法通过断层,可取得很好的经济效益.     

Flow Through Diffusion Cell Method: A Better Approach to Study Drug Release Behavior as Compared to Traditional Dissolution Test Method

Co‐polymeric hydrogels consisting of N‐vinyl‐2‐pyrrolidone (NVP) and acrylic acid (AAc) were synthesized and evaluated for release of a model drug, i.e., vitamin B₁₂. Release studies in simulated gastric fluid (pH 1.2) and intestinal fluid (pH 7.4), at 37°C, showed the hydrogels to be pH sensitive. An in vitro release study by ‘traditional dissolution test’ (TDT) showed that percent drug released from the hydrogel was nearly 8.6±2.1 and 83.2±4.8 in the media of pH 1.2 and 6.8, respectively. However, in order to incorporate in vivo GI conditions such as acidic pH and high water content in the stomach, low water content and the presence of a semi–solid mass in the large intestine, a new test model, called flow through diffusion cell (FTDC) was also used. The two approaches yielded almost different release profiles. The gels were characterized by thermogravimetric analysis and FTIR spectroscopy.     

Indirectly Detected DNP-Enhanced 17O NMR Spectroscopy: Observation of Non-Protonated Near-Surface Oxygen at Naturally Abundant Silica and Silica-Alumina

Recent studies have shown that dynamic nuclear polarization (DNP) can be used to detect ¹⁷O solid-state NMR spectra of naturally abundant samples within a reasonable experimental time. Observations using indirect DNP, which relies on ¹H mediation in transferring electron hyperpolarization to ¹⁷O, are currently limited mostly to hydroxyls. Direct DNP schemes can hyperpolarize non-protonated oxygen near the radicals; however, they generally offer much lower signal enhancements. In this study, we demonstrate the detection of signals from non-protonated ¹⁷O in materials containing silicon. The sensitivity boost that made the experiment possible originates from three sources: indirect DNP excitation of ²⁹Si via protons, indirect detection of ¹⁷O through ²⁹Si nuclei using two-dimensional ²⁹Si{¹⁷O} D-HMQC, and Carr-Purcell-Meiboom-Gill refocusing of ²⁹Si magnetization during acquisition. This ²⁹Si-detected scheme enabled, for the first time, 2D ¹⁷O−²⁹Si heteronuclear correlation spectroscopy in mesoporous silica and silica-alumina surfaces at natural abundance. In contrast to the silanols showing motion-averaged ¹⁷O signals, the framework oxygens exhibit unperturbed powder patterns as unambiguous fingerprints of surface sites. Along with hydroxyl oxygens, detection of these moieties will help in gaining more atomistic-scale insights into surface chemistry.     

Hydromagnetic parametric resonance instability of two superposed conducting fluids in porous medium

Rayleigh–Taylor instability of a heavy fluid supported by a lighter one through porous medium, in the presence of a uniform, horizontal and oscillating magnetic field is studied. The fluids are taken as viscous (obeying Darcy's law), uniform, incompressible, and infinitely conducting. The amplitude of the oscillating part of the field is taken to be small compared with its steady part. The dispersion relation is obtained in the form of a third-order differential equation, with time as the independent variable and with periodic coefficients, for the vertical displacement of the surface of separation of the two fluids from its equilibrium position. The oscillatory magnetic field of frequency ω$\omega$ and steady part _H0$H_0$ has a stabilizing influence on a mode of disturbance which is unstable in a steady magnetic field of strength _H0$H_0$. It is found that the oscillatory magnetic field and porosity of the porous medium have stabilizing effects, while the medium permeability has a destabilizing influence on the considered system. For a constant value of any of these physical parameters, the system has been found to be unstable (for small wavenumbers) as well as stable afterwards after a definite wavenumber value. The marginal stability case of parametric resonance holds when _M1=_M2=0$M_1=M_2=0$ (and hence m=0$m=0$), in which the characteristic exponents, and the corresponding solutions for u$u$ break down, is also investigated in detail. It is found, to order ?$?$, that the effect of an oscillating magnetic field has no stabilizing influence on a disturbance which is marginally stable in the steady magnetic field; while to order ?²${?}^2$, and when the magnetic field oscillates, a resonance between this mode of disturbances and the oscillating field leads to instability when _ρ2>_ρ1${\rho }_2>{\rho }_1$. It is found also, in this resonant case, that all the constant or varied physical parameters, mentioned above, have destabilizing influences on the considered system. Finally, the other two resonance points appear in non-porous media (i.e., when m=±iω$m=\pm \mathrm{i}\omega$ and m=±2iω$m=\pm 2\mathrm{i}\omega$), are disappeared here due to the presence of the porous medium.     

综放工作面顶煤承载能力和支架工作阻力的探讨

支架工作阻力计算是综放开采研究的主要问题之一.在对顶煤力学性质进行了实验室试验的基础上,总结出顶煤破坏时的强度满足主应力表示的莫尔-库仑强度准则.根据综放工作面顶煤体的受力特点,运用损伤力学应变等效原理,建立了综放工作面控顶距内顶煤体受力力学模型.从顶煤体承载能力的角度,研究综放面支架-顶煤体之间相互作用关系,推出了支架工作阻力的理论计算公式.该模型较好地解释了综放工作面支架工作阻力随顶煤强度的提高而增加的矿山压力显现.研究结论对综放面支架工作阻力计算具有一定的理论指导意义.