多参数耦合下冷轧铝带工作辊分段冷却调节特性

为得到多参数耦合下冷轧铝带工作辊分段冷却调节特性,建立了工作辊和轧件的一体化耦合传热模型。耦合传热建模过程包含工作辊和轧件导热微分方程的建立、轧件变形热和摩擦热的求解、换热边界条件的确立、工作辊热辊形的计算及采用二维交替差分对微分方程进行求解。仿真结果表明,同一轧制参数下工作辊分段冷却正负方向调节能力近似相等,但单向调节幅度受轧制参数影响较大,轧制长度、喷射梁工作压力和摩擦系数的增加对分段冷却调控能力具有促进作用,轧制速度的作用则相反。     

楔横轧多楔轧制高铁空心车轴壁厚均匀性

在空心轴楔横轧多楔轧制中,控制壁厚均匀性是衡量车轴成形质量的重要标准。本文先分析空心轴楔横轧多楔轧制的稳定轧制条件,得到了确定空心车轴楔横轧压扁失稳的准则。在此基础上,基于DEFORM-3D软件,建立楔横轧多楔同步轧制高铁空心车轴的三维刚塑性有限元模型,分析展宽角、成形角等工艺参数对壁厚均匀性的影响,获得了工艺参数影响轧制空心车轴壁厚变化的规律。结果表明：成形角越大,壁厚均匀性越好;展宽角越大,壁厚均匀性越好,但在展宽角大于10。时,壁厚均匀性反而下降。基于多楔轧制实验,轧制1：5缩比的空心车轴,测量了轧制力矩和轧制空心轴的壁厚,与仿真结果作比较,相对误差均在10%以内,验证了所建有限元模型的正确性。     

旋转圆柱层流绕流出现二次不稳定现象的数值模拟

采用数值模拟方法,计算了旋转圆柱在层流状态下流场随雷诺数和转速的变化.针对旋转圆柱在均匀流中引起的涡脱落以及二次不稳定现象,进行了分析.选取雷诺数为Re=60,80,100,130,160,240时,将圆柱的转速一直增大,直到流场第二次达到稳定状态.比较了圆柱的旋转在流场达到第一次及第二次不稳定状态时对其表面的气动力、涡量以及周围流场影响的不同.计算结果表明,低转速下,流场出现初次不稳定状态时,雷诺数为Re=60,80,100,130,160,240,所对应的临界转速比分别为α=1.40,1.70,1.80,1.85,1.90,1.95;随着转速的升高,流场再次出现不稳定状态,所对应的转速比区间分别为5.1< α < 5.6,4.9< α < 5.4,4.6< α < 5.2,4.4< α < 5.0,4.3< α < 4.9,4.2< α < 4.7.      

中厚板边部折叠模拟实验及机理研究

通过对中厚板边部折叠试样的检测分析,对其产生机理和影响因素进行研究. 结果显示,中厚板边部折叠现象是板材横轧宽展过程中侧面材料在轧制中受轧辊作用而翻转到板材表面的结果. 折叠缺陷处所观察到的微观组织结构,是轧制前板材表面在高温下形成的氧化铁及脱碳层形成的. 建立了轧制有限元数值模型,证实折叠缺陷是在轧制过程中由侧面的折叠翻转所造成的. 通过实验室实验,得到铸坯边部质量、轧制制度、宽展道次及轧制压下量对中厚板折叠缺陷的影响. 实验结果表明横轧宽展导致折叠缺陷的出现,铸坯边部质量对其没有影响,轧制过程中铸坯侧边的折叠经翻平形成表面折叠缺陷,随着横轧展宽的道次及压下量增加,折叠缺陷距边部距离变大.     

一类风险模型的破产概率及生存概率的积分—微分方程研究

对保费收取为Poison过程,索赔次数为Poison-Geometric过程的带干扰风险模型进行研究,证明了调节系数的存在性,给出了风险模型破产概率的一般表达式,推导了生存概率所满足的一个积分-微分方程.     

基于IOWHA算子的区间预测模型及应用

针对实际值序列和预测值序列均为区间数的组合预测问题,把区间数的左右端点作为两个独立的时序数列,通过引入诱导有序加权调和平均(IOWHA)算子,分别建立以区间数左右端点的倒数离差相关系数最大化为准则的IOWHA算子的变权系数最优组合预测模型,再通过引入偏好系数把多目标最优化模型转化为单目标最优化模型,并尝试给出各模型最优解的性质.最后利用数据进行分析,并和其他单项预测方法或组合预测方法相比较,从而证明该方法确实能够提高区间预测的精度.     

Migration of Stabilizers from Polypropylene into Simulated Food

This study has investigated the migration of stabilizers from three polypropylene materials: a polypropylene homopolymer, a polypropylene block copolymer, and a polypropylene random copolymer in 10% ethanol, 3% acetic acid, 20% ethanol, 50% ethanol, and isooctane according to Regulation (EU) No. 10/2011. Measurements were performed at 20, 40, and 70°C and migration was evaluated from 10?min to 10 days. Measurements were performed by high-performance liquid chromatography (HPLC) with external calibration. The HPLC method provided high correlation coefficients, good precision, good accuracy, and suitable reproducibility. Diffusion coefficients for stabilizers were obtained using a rigorous model based on Fick’s second law and the values were between 6.1?×?10^?13 and 3.8?×?10^?9?cm²?s^?1. By applying an Arrhenius-type equation to the diffusion coefficients, an estimation of activation energy of the diffusion was obtained. The activation energies were from 39.97 to 98.75?kJ?mol^?1 for the stabilizers. The results indicate that the polypropylene material structure influenced the migration rate, which decreased in the order of the increasing crystallinity in the materials. The diffusion coefficients for stabilizers in the polypropylene random copolymer were higher than in the polypropylene block copolymer and polypropylene homopolymer. The random polypropylene copolymer had the lowest activation energy. These results show that a higher diffusion coefficient indicates a higher migration rate, and a system with a lower activation energy allows more migration.     

Physicochemical investigation of sulfonamide-derived compounds interacting with conventional cationic surfactants in aqueous media

The sulfonamide core in compounds is effective synthons, which offer exciting perspectives in chemotherapeutic and pharmacological research. In this study, we investigated the molecular interaction of potent sulfonamide derivatives (SDs), 2-benzenesulfonamido-3-methylbutyric acid (BSB) and tetraaquabis{3-methyl-2-[(phenylsulfonyl)amino]butanoate}copper(II) (Cu-BSB), with cationic surfactants, cetyltrimethyl ammonium bromide (CTAB) and ethylhexadecyl dimethyl ammonium bromide (EHDAB), using UV-visible spectroscopy and steady-state fluorescence measurements. Various mathematical models were applied to quantify the effect of cationic surfactants on physicochemical characteristics of BSB and Cu-BSB. These interactions were confirmed by estimating the partition coefficient (K_x), binding capacities (K_b), Stern-Volmer quenching constant (K_sv), and related Gibbs free energies (ΔG_b). The in-depth mechanism revealed that the binding mode in SD–surfactants combinational system is spontaneous and quenching exists in static mode initiated by ground-state complex formation. We believe that the true knowledge of host–guest interaction mechanisms concerning model membrane with entrapped moiety can help in better understanding of molecular recognition in related phospholipid membrane models.     

稳恒扩展裂纹尖端的弹粘塑性场

采用弹粘塑性力学模型代替通常的弹塑性模型，对于I型和Ⅱ型问题，分别求得了不可压缩材料中平面应变动态扩展裂纹尖端的指数奇异性场和对数奇异性场，消除了弹塑性解中存在的塑性激波。通过数值计算，分别求得了两种奇异属性的分界线，建立起统一的裂纹尖端奇异性场。     

Percolation theory approach to transport phenomena in porous media

The percolation theory approach to static and dynamic properties of the single- and two-phase fluid flow in porous media is described. Using percolation cluster scaling laws, one can obtain functional relations between the saturation fraction of a given phase and the capillary pressure, the relative permeability, and the dispersion coefficient, in drainage and imbibition processes. In addition, the scale dependency of the transport coefficient is shown to be an outcome of the fractal nature of pore space and of the random flow pattern of the fluids or contaminant.