全文获取类型
收费全文 | 19684篇 |
免费 | 1308篇 |
国内免费 | 1123篇 |
专业分类
化学 | 11960篇 |
晶体学 | 28篇 |
力学 | 1045篇 |
综合类 | 52篇 |
数学 | 350篇 |
物理学 | 2271篇 |
综合类 | 6409篇 |
出版年
2024年 | 74篇 |
2023年 | 302篇 |
2022年 | 589篇 |
2021年 | 468篇 |
2020年 | 653篇 |
2019年 | 592篇 |
2018年 | 549篇 |
2017年 | 715篇 |
2016年 | 824篇 |
2015年 | 853篇 |
2014年 | 947篇 |
2013年 | 1119篇 |
2012年 | 1235篇 |
2011年 | 1198篇 |
2010年 | 931篇 |
2009年 | 1066篇 |
2008年 | 988篇 |
2007年 | 1110篇 |
2006年 | 984篇 |
2005年 | 939篇 |
2004年 | 843篇 |
2003年 | 763篇 |
2002年 | 612篇 |
2001年 | 484篇 |
2000年 | 454篇 |
1999年 | 402篇 |
1998年 | 316篇 |
1997年 | 280篇 |
1996年 | 250篇 |
1995年 | 231篇 |
1994年 | 244篇 |
1993年 | 178篇 |
1992年 | 172篇 |
1991年 | 150篇 |
1990年 | 131篇 |
1989年 | 126篇 |
1988年 | 113篇 |
1987年 | 65篇 |
1986年 | 38篇 |
1985年 | 26篇 |
1984年 | 21篇 |
1983年 | 14篇 |
1982年 | 18篇 |
1981年 | 13篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 6篇 |
1976年 | 5篇 |
1959年 | 2篇 |
1955年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
ZHANG BaoMin ZHANG ShuiChang BIAN LiZeng JIN ZhiJun WANG DaRui 《科学通报(英文版)》2007,52(A01):77-91
Based on the researches on rock type, the mode of occurrence, diagnostic minerals and creatures, the sedimentary geochemistry and organic facies of Chinese marine source rocks from wells and outcrops, and on the research findings of developmental modes of foreign marine source rock, the authors consider that it is impossible to objectively make clear the formation mechanism of hydrocarbon source rock with high organic matter abundance by either single mode of preservation or high organic matter productivity. According to the Chinese geological features, the formation mechanism of the Neoproterozoic-Lower Paleozoic marine source rock is generalized into four modes, namely, thermal water activity-upwelling flow-anoxic; carbonate gentle slope-upwelling flow; xerothermic climate-brine euxinic milieu; and humid climate-retained euxinic milieu; as the Lower Cambrian undercompensation basin organic facies (the Tarim Basin, South China and southwestern margin of North China), carbonate gentle lime mud bound organic facies (the Upper Ordovician in Tazhong region of the Tarim Basin and the Lower Silurian in the Upper Yangtze Platform), the Middle Cambrian evaporation laggon organic facies (the Tarim Basin and the Upper Yangtze Platform), enclosed undercompensation terrigenous bay organic facies (the Middle-Upper Ordovician in the west of the Tarim Basin, the Lower Silurian Long- maxi Formation in the Upper Yangtze platform). Chinese marine sedimentations with lower organic matter abundance are generalized into two modes of consumption-dilution mode of open epicontinental sea and depletion-dilution mode of supercompensation basin. 相似文献
12.
MC模式下顾客需求与厂商供应的纳什均衡 总被引:3,自引:0,他引:3
在大规模定制(MC,Mass Customization)模式下,基于市场需求的复杂化,厂商对个性化的顾客需求很难做出及时准确的反应,而且由于其自身生产能力的限制,不可能对所有的个性化用户进行一一地满足,只可能对已经存在的个性化需求,根据自身的生产能力和规模,以利润最大化及顾客对产品的满意度为目标,对个性化需求进行较准确地预测,从而正确指导生产。本通过博弈论的方法,提出了一个基于顾客对产品的满意度及企业的利润的一个非合作博弈模型,并给出求解纳什均衡的方法。 相似文献
13.
G. Richard Geier III 《Tetrahedron》2004,60(50):11435-11444
To better understand the effects of diverse substituents on reactions leading to porphyrins, pyrrole+aldehyde condensations and related reactions of dipyrromethanes were examined. The course of pyrrole+aldehyde condensations was investigated by monitoring the yield of porphyrin (by UV-Vis spectroscopy), reaction of aldehyde (by TLC), and changes in the composition of oligomers (by laser desorption mass spectrometry). Reaction reversibility was examined via exchange experiments. Reversibility of reactions leading to porphyrin was further probed with studies of dipyrromethanes. The reaction course was found to depend on the nature of the substituent and the acid catalyst. Alkyl or electron-donating substituents displayed levels of reversibility (exchange/scrambling) on par or greater than that of the phenyl substituent, whereas electron-withdrawing or sterically bulky substituents exhibited little to no reversibility. The results obtained provide insight into the electronic and steric effects of different substituents and should facilitate the design of synthetic plans for preparing porphyrinic macrocycles. 相似文献
14.
Grigor'ev S. A. Kalinnikov A. A. Porembskii V. I. Baranov I. E. Borisova E. V. Fateev V. N. 《Russian Journal of Electrochemistry》2004,40(11):1188-1192
A two-dimensional mathematical model for the transport of reactants in a fuel cell with a solid polymer electrolyte is developed. The model is used for analyzing spatial distributions of the concentration of reactants and current density over the cell. The effect of the catalytic-layer activity, reactant speed, bipolar-plate geometry, thickness and porosity of current collector and/or gas-diffusion sublayer, and the reaction mixture composition on the fuel cell efficiency is estimated theoretically and experimentally. 相似文献
15.
Mass distributions of fragments in the low-energy fission of nuclei from 187Ir to 213At have been analysed. This analysis has shown that shell effects in symmetric-mode fragment mass yields from the fission of pre-actinide nuclei could be described if one assumes the existence of two strongly deformed neutron shells in the arising fragments with neutron numbers N1 ≈ 52 and N2 ≈ 68. A new method has been proposed for quantitatively describing the mass distributions of the symmetric fission mode for pre-actinides with A ≈ 180–220. 相似文献
16.
B. Sadashive Gowda G.S.V.L. Narasimham M.V. Krishna Murthy 《International Journal of Heat and Fluid Flow》1997,18(6):613-624
In this paper, a mathematical model for forced-air precooling of spherical food products in bulk is developed. The foods are arranged in horizontal layers stacked one above the other to form a rectangular parallelepiped with a vertical gap in between the product layers. The foods are cooled by chilled air blown along the height of the package. The governing equations for the conduction heat transfer in the foods, simultaneous heat and mass transfer at the food-air interface and in the air stream are solved numerically using finite-difference methods. A comprehensive numerical study is performed by varying the process parameters over a wide range. Typical results showing the variation of moist air properties along the height of the package and the effect of each parameter on the process time are presented. The ranges of parameters for advantageous operation of the precooling system are identified. Correlations are obtained for the process time based on the product center and mass-averaged temperatures in terms of process parameters. 相似文献
17.
A. S. Lobach B. P. Tarasov Yu. M. Shul'ga A. A. Perov A. N. Stepanov 《Russian Chemical Bulletin》1996,45(2):464-465
Fullerene deuteride was obtained by the reaction of deuterium with solid palladium fulleride C60Pd4.9 under fairly mild conditions. The compound was identified by FD-MS, UV-Vis and IR spectroscopies, and TLC.Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 483–484, February, 1996 相似文献
18.
On‐line coupling of LC and ICP‐MS has been used for fractionation and detection of species of Cu, Fe, I, Se and Zn in human serum. It has been shown that anion exchange chromatography provided better separation capability (both intra‐ and inter‐element) than size‐exclusion chromatography. The mobile phases for ion exchange chromatography consisted of Tris–HNO3 buffer and ammonium salt (nitrate, acetate or formate). Formate was found to be the best mobile phase counter ion, enabling good chromatographic separation, and is acceptable for mass spectrometry too. The quantitative evaluation of element concentrations adhering to individual fractions was performed by the peak area normalization method. The repeatability of results ranged from 3 to 15% (depending on the element concentration level) and represented the main part of the result uncertainty. The accuracy of Cu and Zn fraction determinations was confirmed by comparison with the isotope dilution technique. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
19.
E. V. Ermanyuk 《Experiments in fluids》2002,32(2):242-251
This paper presents a study on affine similitude for the force coefficients of an arbitrary body oscillating in a uniformly
stratified fluid. A simple formula is derived that gives a relation between the force coefficients for a body oscillating
in homogeneous and uniformly stratified ideal fluids. In particular, it implies the existence of a universal nondimensional
similitude criterion for a family of affinely similar bodies, namely, the bodies that can be transformed into each other by
vertical dilation of the initial coordinate system. Theoretical results are verified by experiments with a set of spheroids
having different length-to-diameter ratios. The experimental technique for evaluation of the frequency-dependent force coefficients
is based on Fourier analysis of the time-history of damped oscillation tests.
Received: 25 September 2000 / Accepted: 6 July 2001 Published online: 29 November 2001 相似文献
20.
P. Paasche T. Valenzuela D. Biswas C. Angelescu G. Werth 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(3):295-300
We have examined experimentally the motional spectrum of an electron cloud confined in a Penning trap. When the axial oscillation
is excited by a radio frequency field the resonance exhibits a double structure. Both components depend differently on the
number of trapped electrons and have different shape and width. We conclude that one of them corresponds to the excitation
of the individual electrons while the other is the center-of-mass mode of the cloud. The threshold behaviour of the center-of-mass
resonance suggests that it is a parametric instability of a Mathieu type equation of motion.
Received 11 July 2001 and Received in final form 12 November 2001 相似文献