全文获取类型
收费全文 | 81276篇 |
免费 | 5462篇 |
国内免费 | 4829篇 |
专业分类
化学 | 9953篇 |
晶体学 | 152篇 |
力学 | 2765篇 |
综合类 | 844篇 |
数学 | 12904篇 |
物理学 | 12921篇 |
综合类 | 52028篇 |
出版年
2024年 | 261篇 |
2023年 | 772篇 |
2022年 | 1473篇 |
2021年 | 1748篇 |
2020年 | 1497篇 |
2019年 | 1562篇 |
2018年 | 1555篇 |
2017年 | 2017篇 |
2016年 | 2115篇 |
2015年 | 2365篇 |
2014年 | 3978篇 |
2013年 | 4329篇 |
2012年 | 4280篇 |
2011年 | 4746篇 |
2010年 | 3722篇 |
2009年 | 4560篇 |
2008年 | 4922篇 |
2007年 | 6125篇 |
2006年 | 5540篇 |
2005年 | 4707篇 |
2004年 | 4132篇 |
2003年 | 3641篇 |
2002年 | 3249篇 |
2001年 | 2652篇 |
2000年 | 2315篇 |
1999年 | 1906篇 |
1998年 | 1570篇 |
1997年 | 1360篇 |
1996年 | 1139篇 |
1995年 | 1021篇 |
1994年 | 808篇 |
1993年 | 729篇 |
1992年 | 756篇 |
1991年 | 545篇 |
1990年 | 490篇 |
1989年 | 409篇 |
1988年 | 372篇 |
1987年 | 324篇 |
1986年 | 204篇 |
1985年 | 147篇 |
1984年 | 129篇 |
1983年 | 68篇 |
1982年 | 129篇 |
1981年 | 186篇 |
1980年 | 192篇 |
1979年 | 192篇 |
1978年 | 172篇 |
1977年 | 110篇 |
1976年 | 114篇 |
1973年 | 82篇 |
排序方式: 共有10000条查询结果,搜索用时 140 毫秒
171.
Kurt Majewski 《Queueing Systems》2005,50(2-3):199-230
We consider multiclass feedforward queueing networks under first in first out and priority service disciplines driven by long-range dependent arrival and service time processes. We show that in critical loading the normalized workload, queue length and sojourn time processes can converge to a multi-dimensional reflected fractional Brownian motion. This weak heavy traffic approximation is deduced from a deterministic pathwise approximation of the network behavior close to constant critical load in terms of the solution of a Skorokhod problem. Since we model the doubly infinite time interval, our results directly cover the stationary case.AMS subject classification: primary 90B15, secondary 60K25, 68M20 相似文献
172.
本文利用我国上市公司1997至2002年的有关财务数据,建立了我国上市公司资本成本面板数据模型,运用该模型分析了我国上市公司资本成本与财务杠杆、企业规模的关系.结果表明,财务杠杆的提升、企业规模的扩大将使资本成本下降.该结论对我国上市公司优化资本结构、提高企业价值具有一定的参考价值. 相似文献
173.
Grishin D. F. Semyonycheva L. L. Telegina E. V. Smirnov A. S. Nevodchikov V. I. 《Russian Chemical Bulletin》2003,52(2):505-507
Organometallic compounds Cp2TiCl2, (EtC5H4)2NbCl2, and (PriC5H4)2WCl2 were assessed as additives that control polymer chain growth in the polymerization of methyl methacrylate. In the presence of compounds mentioned in amounts comparable with that of the initiator, a uniform process with no gel-effect occured and respective linear increase in the molecular weight of the polymer up to high degrees of the monomer conversion was observed. 相似文献
174.
We present a practical polynomial-time algorithm for computing the
zeta function of a Kummer curve over a finite field of small
characteristic. Such algorithms have recently been obtained using a
method of Kedlaya based upon Monsky–Washnitzer cohomology, and are of
interest in cryptography. We take a different approach.
The problem is reduced to that of computing the L-function
of a multiplicative character sum. This latter task is achieved via a
cohomological formula based upon the work of Dwork and Reich. We show,
however, that our method and that of Kedlaya are very closely related.Dedicated to the memory of Gian-Carlo Rota 相似文献
175.
Twenty-five years ago, we introduced the phenomenon of negative luminescence (NL) into semiconductor physics. This paper provides an overview of work conducted to develop this fundamental concept. Initially, we consider the first-principle approach to radiation interaction with basic matter and the major properties of NL. Then we describe the problems of NL direct measurements in homogeneous materials and structures. Finally, we emphasize the use of NL approach in applications involving devices for infrared (IR) wavelength (3–12 μm) high-temperature (300–400 K) optoelectronics. Our subjects will include NL IR emitting diodes, radiative coolers, IR dynamic scene simulators, light up-conversion devices, and the Stealth effect in IR. 相似文献
176.
A solution to the phase problem in optics is considered within the context of the analysis of signals changing in time and of the effect of an object under investigation on the probing radiation. The solution is based on the use of a twin-wave interferometer with phase modulation in one of the channels and a spectrometer. The analysis is concerned, in particular, with signals and processes of ultrashort duration. To shift the frequency in the interferometer channel, an electrooptical crystal of ferroelectric perovskite is used as the modulator. Errors of amplitude and phase structures determined are analyzed. 相似文献
177.
Xiaojuan Hao Camilla Nilsson Martin Jesberger Martina H. Stenzel Eva Malmstrm Thomas P. Davis Emma
stmark Christopher Barner‐Kowollik 《Journal of polymer science. Part A, Polymer chemistry》2004,42(23):5877-5890
The synthesis and characterization of novel first‐ and second‐generation true dendritic reversible addition–fragmentation chain transfer (RAFT) agents carrying 6 or 12 pendant 3‐benzylsulfanylthiocarbonylsulfanylpropionic acid RAFT end groups with Z‐group architecture based on 1,1,1‐hydroxyphenyl ethane and trimethylolpropane cores are described in detail. The multifunctional dendritic RAFT agents have been used to prepare star polymers of poly(butyl acrylate) (PBA) and polystyrene (PS) of narrow polydispersities (1.4 < polydispersity index < 1.1 for PBA and 1.5 < polydispersity index < 1.3 for PS) via bulk free‐radical polymerization at 60 °C. The novel dendrimer‐based multifunctional RAFT agents effect an efficient living polymerization process, as evidenced by the linear evolution of the number‐average molecular weight (Mn) with the monomer–polymer conversion, yielding star polymers with molecular weights of up to Mn = 160,000 g mol?1 for PBA (based on a linear PBA calibration) and up to Mn = 70,000 g mol?1 for PS (based on a linear PS calibration). A structural change in the chemical nature of the dendritic core (i.e., 1,1,1‐hydroxyphenyl ethane vs trimethylolpropane) has no influence on the observed molecular weight distributions. The star‐shaped structure of the generated polymers has been confirmed through the cleavage of the pendant arms off the core of the star‐shaped polymeric materials. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5877–5890, 2004 相似文献
178.
Chun‐Yan Hong Ye‐Zi You Cai‐Yuan Pan 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4873-4881
Well‐defined diblock and triblock copolymers composed of poly(N‐isopropylacrylamide) (PNIPAM) and poly(ethylene oxide) (PEO) were successfully synthesized through the reversible addition–fragmentation chain transfer polymerization of N‐isopropylacrylamide (NIPAM) with PEO capped with one or two dithiobenzoyl groups as a macrotransfer agent. 1H NMR, Fourier transform infrared, and gel permeation chromatography instruments were used to characterize the block copolymers obtained. The results showed that the diblock and triblock copolymers had well‐defined structures and narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight < 1.2), and the molecular weight of the PNIPAM block in the diblock and triblock copolymers could be controlled by the initial molar ratio of NIPAM to dithiobenzoate‐terminated PEO and the NIPAM conversion. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4873–4881, 2004 相似文献
179.
The reversible nonlinear conduction (RNC) in of high‐density polyethylene/acetylene carbon black composites with different degrees of crosslinking was studied above room temperature and below the melting point of high‐density polyethylene (HDPE). The experimental current density‐electric field strength curves can be overlapped onto a master curve, suggesting that the microscopic mechanisms for the appearance of RNC exist regardless of the ambient temperature and the crosslinking degree of the HDPE matrix. The relationship between the crossover current density and the linear conductivity can be explained in the framework of the dynamic random‐resistor‐network model. According to these results, two electron‐tunneling models are suggested to interpret the microscopic conduction behavior. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1212–1217, 2004 相似文献
180.
Tae Young Kim Dong Myung Kim Won Jung Kim Tae Hee Lee Kwang S. Suh 《Journal of Polymer Science.Polymer Physics》2004,42(15):2813-2820
The effect of the triblock copolymer poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] (SEBS) on the formation of the space charge of immiscible low‐density polyethylene (LDPE)/polystyrene (PS) blends was investigated. Blends of 70/30 (wt %) LDPE/PS were prepared through melt blending in an internal mixer at a blend temperature of 220 °C. The amount of charge that accumulated in the 70% LDPE/30% PS blends decreased when the SEBS content increased up to 10 wt %. For compatibilized and uncompatibilized blends, no significant change in the degree of crystallinity of LDPE in the blends was observed, and so the effect of crystallization on the space charge distribution could be excluded. Morphological observations showed that the addition of SEBS resulted in a domain size reduction of the dispersed PS phase and better interfacial adhesion between the LDPE and PS phases. The location of SEBS at a domain interface enabled charges to migrate from one phase to the other via the domain interface and, therefore, resulted in a significant decrease in the amount of space charge for the LDPE/PS blends with SEBS. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2813–2820, 2004 相似文献