4-(二甲胺基)苯甲醛缩-2,4-二硝基苯腙分子特性的预测研究

利用Gaussian98程序,采用密度泛涵方法(B3LYP/6-31G)对4-(二甲胺基)苯甲醛缩-2,4-二硝基苯腙化合物的晶体结构进行了量化计算,利用相关参数推测了它的分子特性,结果表明,该化合物的分子结构为一大平面结构,难与金属形成配合物.     

A MODEL OF TROPICAL MARINE RESERVE‐FISHERY LINKAGES

ABSTRACT. The excessive and unsustainable exploitation of our marine resources has led to the promotion of marine reserves as a fisheries management tool. Marine reserves, areas in which fishing is restricted or prohibited, can offer opportunities for the recovery of exploited stock and fishery enhancement. In this paper we examine the contribution of fully protected tropical marine reserves to fishery enhancement by modeling marine reserve‐fishery linkages. The consequences of reserve establishment on the long‐run equilibrium fish biomass and fishery catch levels are evaluated. In contrast to earlier models this study highlights the roles of both adult (and juvenile) fish migration and larval dispersal between the reserve and fishing grounds by employing a spawner‐recruit model. Uniform larval dispersal, uniform larval retention and complete larval retention combined with zero, moderate and high fish migration scenarios are analyzed in turn. The numerical simulations are based on Mombasa Marine National Park, Kenya, a fully protected coral reef marine reserve comprising approximately 30% of former fishing grounds. Simulation results suggest that the establishment of a fully protected marine reserve will always lead to an increase in total fish biomass. If the fishery is moderately to heavily exploited, total fishery catch will be greater with the reserve in all scenarios of fish and larval movement. If the fishery faces low levels of exploitation, catches can be optimized without a reserve but with controlled fishing effort. With high fish migration from the reserve, catches are optimized with the reserve. The optimal area of the marine reserve depends on the exploitation rate in the neighboring fishing grounds. For example, if exploitation is maintained at 40%, the ‘optimal’ reserve size would be 10%. If the rate increases to 50%, then the reserve needs to be 30% of the management area in order to maximize catches. However, even in lower exploitation fisheries (below 40%), a small reserve (up to 20%) provides significantly higher gains in fish biomass than losses in catch. Marine reserves are a valuable fisheries management tool. To achieve maximum fishery benefits they should be complemented by fishing effort controls.     

潮流计算中的数学方法——牛顿—拉夫逊法

本文介绍了一种解非线性代数方程组的数学方法——牛顿-拉夫逊法,并将其应用于电力系统潮流计算中。采用本文方法的计算结果表明该教学方法在电力系统潮流问题中是收敛的;同时计算结果与电力专业软件的计算结果保持了一致,从而验证了结果的正确性。     

漳州某基坑抽水引起地面沉降的初探

由于基坑快速抽水导致基坑周边地面沉降。通过对场地因抽水引起地面沉降的计算和试抽水等方面的前期工作,分析了因基坑降水对地面沉降的影响,并据此来调整完善基坑降水方案,取得了明显的社会和经济效益。     

"藏汇于国"到"藏汇于民"的外汇投资渠道探讨

为了更好地落实藏汇于民,必须拓展外汇投资渠道,使藏汇于民成为可能。文章主要探讨当前可能的主要外汇投资渠道,并就在外汇投资活动中需要注意的事项给予说明。     

The epitaxial growth of gaas using alkylarsine: Part 2. molecular orbital calculation

Semi-empirical molecular orbital calculations were carried out for the compounds (C₂H₅)₃As, (C₂H₅)₃Ga and RAsH₂ (R = C₂H₅, i-C₃H₇, i-C₄H₉, and t-C₄H₉) by using the CNDO/2-U program, and their capability of β-elimination reaction is compared on the basis of the torsion energy to the transition state, electrostatic interactions and orbital overlapping between the central atom and the β-hydrogen, and bond order of the metal-carbon, and carbon-hydrogen bond. In the comparison of (C₂H₅)₃As with (C₂H₅)₃Ga, we found that the β-elimination of (C₂H₅)₃As could hardly be expected to take place in the thermal decomposition. The capability of β-elimination would be smaller in C₂H₅AsH₂ than that in (C₂H₅)₃As. Moreover when the ethyl group is replaced by a t-butyl group in RAsH₂, the β-elimination reaction appears to become more difficult and a large possibility for a radical process is suggested.     

汽车拖拉机转向机构的优化设计

本文提出用一种新的时间离散化方法对汽车拖拉机的转向机构进行优化设计．该离散化方法是按被实现函数变化率的大小划分时间单元，在被实现函数变化率较大的区域，分点较密；在率化率较小的区域，分点较稀．笔者还分别用等间距的时间离散化及切比雪夫时间离散化方法，对同一机构使用同一种优化方法进行了优化设计，并将三种计算结果进行了比较．结果表明，笔者提出的方法，没有增加计算工作量，而能提高计算精度．     

Principle of Mangling Correction of Plate-welding Section Steel and its Application

Thanks to the fantastic development of power, transportation, chemical engineering, architecture and other fields, there has been an increasing demand for new type of section steel with large sections used for construction frame, such as type-H, type-T, and type-C section steel. New types of section steel usually are long and with large cross section. Therefore, for the sake of the cost, steel plate welding structure is used home and abroad. During the welding process, welding distortion seems unavoidable. ...     

一种新的保费定价原理及其性质

K—阶均值保费定价原理具有成比例性、次可加性、保持随机序等等性质,揭示出它与较为熟悉的几种保费定价原理之间的联系。