Radiation-Induced Oxidation Reactions of 2-Selenouracil in Aqueous Solutions: Comparison with Sulfur Analog of Uracil

One-electron oxidation of 2-selenouracil (2-SeU) by hydroxyl (^●OH) and azide (^●N₃) radicals leads to various primary reactive intermediates. Their optical absorption spectra and kinetic characteristics were studied by pulse radiolysis with UV-vis spectrophotometric and conductivity detection and by the density functional theory (DFT) method. The transient absorption spectra recorded in the reactions of ^●OH with 2-SeU are dominated by an absorption band with an λ_max = 440 nm, the intensity of which depends on the concentration of 2-SeU and pH. Based on the combination of conductometric and DFT studies, the transient absorption band observed both at low and high concentrations of 2-SeU was assigned to the dimeric 2c-3e Se-Se-bonded radical in neutral form (2^●). The dimeric radical (2^●) is formed in the reaction of a selenyl-type radical (6^●) with 2-SeU, and both radicals are in equilibrium with K_eq = 1.3 × 10⁴ M⁻¹ at pH 4 (below the pK_a of 2-SeU). Similar equilibrium with K_eq = 4.4 × 10³ M⁻¹ was determined for pH 10 (above the pK_a of 2-SeU), which admittedly involves the same radical (6^●) but with a dimeric 2c-3e Se-Se bonded radical in anionic form (2^●−). In turn, at the lowest concentration of 2-SeU (0.05 mM) and pH 10, the transient absorption spectrum is dominated by an absorption band with an λ_max = 390 nm, which was assigned to the ^●OH adduct to the double bond at C5 carbon atom (3^●) based on DFT calculations. Similar spectral and kinetic features were also observed during the ^●N₃-induced oxidation of 2-SeU. In principle, our results mostly revealed similarities in one-electron oxidation pathways of 2-SeU and 2-thiouracil (2-TU). The major difference concerns the stability of dimeric radicals with a 2c-3e chalcogen-chalcogen bond in favor of 2-SeU.     

图书借阅量预测模型

将统计学中的一元线性回归模型方法,引入到图书管理领域,以1993年至2005年之间的十二个学年度的读者总指数为自变量,以对应十二个学年度的借阅量为相依变量,得出回归方程,进行F-检验,利用2005-2006学年度的读者总指数,预测对应的未来下一个学年度的借阅量.     

关于数学与应用数学专业课程设置与教学方法的调查报告

在当前高等院校数学专业课程设置上,大学生对现行课程设置满意度不高,他们希望加强实用性、应用性课程,希望有更多类型的选修课可供选择.在数学方式、方法上他们要求改变传统的教学方式,提倡师生互动教学方式和计算机辅助教学,传统的闭卷考试的单一考核方式也受到大学生们的质疑.     

DEA方法在非营利性科研机构绩效评价中的应用

在介绍DEA方法的基础上,详细阐述了采用DEA方法对非营利性科研机构进行绩效评价的思路,最后给出具体评价的实例.     

松花蛋中痕量铅的方波溶出伏安法测定

用方波溶出伏安法测定松花蛋中痕量铅,在抗坏血酸存在下,以0.1 mol/L硝酸溶液为底液,玻碳电极为工作电极,测得铅的溶出峰电位是-0.48 V。峰高与铅浓度在1.00×10-4~1.00×10-6mol/L范围内呈良好的线性关系,铅的检出限为5.00×10-8mol/L,回收率为90%~108%。此法干扰较少,易于掩蔽,灵敏度较高,适用于松花蛋等食品中微量铅的测定。     

SOURCE TERM IDENTIFICATION WITH DISCONTINUOUS DUAL RECIPROCITY APPROXIMATION AND QUASI-NEWTON METHOD FROM BOUNDARY OBSERVATIONS

This paper deals with discontinuous dual reciprocity boundary element method for solving an inverse source problem.The aim of this work is to determine the source term in elliptic equations for nonhomogenous anisotropic media,where some additional boundary measurements are required.An equivalent formulation to the primary inverse problem is established based on the minimization of a functional cost,where a regularization term is employed to eliminate the oscillations of the noisy data.Moreover,an efficient algorithm is presented and tested for some numerical examples.     

电化学方法用于氯代芳烃污染物去除的研究

本文介绍了电化学方法用于氯代芳烃污染物去除的原理、反应历程及影响因素,分析了进一步实用化应考虑的主要问题,展望了该方向今后的发展趋势。     

农村初中化学新课程实施的影响因素分析

课程实施是课程改革的关键环节,而中国的13亿人口,8亿在农村,所以关注农村中学新课程的实施情况,关系到课程改革的成败。本研究主要运用质性研究方法,辅以问卷调查,对影响农村初中化学新课程实施的影响因素进行了分析。     

化学浴沉积法制备纳米氧化亚铜薄膜

用改进后的化学浴沉积法制备了纳米Cu2O薄膜,并对成膜条件及膜的性能进行了研究．结果表明：化学浴沉积法改进后有利于制备高质量的纳米Cu2O薄膜;最佳反应温度为60～70C,此温度范围内Cu2O薄膜的膜厚随着循环次数线性增加．制备的薄膜纯度较高．表面较平整和致密,Cu2O粒径为14～22nm,其禁带宽度为2．01eV．     

取压方式对微通道内单相摩擦阻力特性的影响

本文以去离子水和氮气为工质,在水平圆形微通道(dh=0．336 mm)中采用两种直接取压方式-缝隙取压和小孔取压,对单相摩擦阻力特性进行了实验研究,并通过改变缝隙宽度,研究缝隙宽度对压降测量偏差的影响．