Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis

The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties.     

市级党校图书馆功能转变研究

为了更好应对信息技术发展带来的挑战，市级党校图书馆应明确功能定位，确定图书馆功能转变的路径方式，客观分析影响图书馆功能转变的不利因素，制定具体措施，实现市级党校图书馆的功能转变。     

利用反预报方法从截面预言近滴线丰质子核的结合能

在Origin等数据处理软件中,当实验数据较少时,自由参数的不同初始化设置会导致较大的结果差异,这为物理结果的确定带来较大不确定性.通过最小二乘法分析了345MeV/u ~(78) Kr+~9Be反应中产生的丰质子同位素的截面和结合能,并得到线性回归方程.通过回归方程,利用结合能预报部分丰质子核素的截面,以及通过实验截面对近质子滴线核素的结合能进行反预报测量.这对于近质子滴线的丰质子核素实验测量具有较好的借鉴意义.     

Binary functions,degeneracy, and alternating dimaps

This paper continues the study of combinatorial properties of binary functions — that is, functions $f:2^E\to ?$ such that $f(0?)=1$, where $E$ is a finite set. Binary functions have previously been shown to admit families of transforms that generalise duality, including a trinity transform, and families of associated minor operations that generalise deletion and contraction, with both these families parameterised by the complex numbers. Binary function representations exist for graphs (via the indicator functions of their cutset spaces) and indeed arbitrary matroids (as shown by the author previously). In this paper, we characterise degenerate elements – analogues of loops and coloops – in binary functions, with respect to any set of minor operations from our complex-parameterised family. We then apply this to study the relationship between binary functions and Tutte’s alternating dimaps, which also support a trinity transform and three associated minor operations. It is shown that only the simplest alternating dimaps have binary representations of the form we consider, which seems to be the most direct type of representation. The question of whether there exist other, more sophisticated types of binary function representations for alternating dimaps is left open.     

带变量核的分数次积分交换子在变指数Herz-Morrey空间上的有界性

证明了带变量核的分数次积分算子T_(Ω,μ)与Lipschitz函数b生成的高阶交换子[b~m,T_(Ω,μ)]在变指数Herz-Morrey空间MK_(q,p)~(α,λ)(·)(R~n)上的有界性.     

一种自适应步长的复合梯度加速优化算法

自适应步长加速(Adam)类算法由于其计算效率高、兼容性好的特点，成为近期相关领域的研究热点.针对Adam收敛速度慢的问题，本文基于当前梯度、预测梯度以及历史动量梯度，提出一种新型Adam类一阶优化算法——复合梯度下降法(C-Adam)，并对其收敛性进行了理论证明.与其他加速算法的区别之处在于，C-Adam将预测梯度与历史动量区别开，通过一次真实的梯度更新找到下一次迭代更精准的搜索方向.利用两组常用测试数据集及45钢静拉伸破坏实验的实验数据对所提算法进行验证，实验结果表明C-Adam与其他流行算法相比较具有更快的收敛速度及更小的训练损失.     

大尺寸工程模型试验中的相似材料配比试验研究

大型物理模型试验是研究复杂工程问题的重要方法，如何快速、准确地确定相似材料配比是试验中至关重要的一环.为降低试验成本、简化试验步骤、充分调用原料性能，采用河砂、水泥和石膏这三种最普通的原料，以骨胶比(河砂与水泥石膏的质量比)和水膏比(水泥与石膏的质量比)为变量，进行了45组对比试验，对相似材料的物理及动、静力学参数进行了研究.获得了以河砂、水泥和石膏为原料配制的相似材料各物理量的变化区间；探讨了骨胶比和水膏比对相似材料各物理量的控制作用，并对比了其敏感性；基于多元线性回归分析建立了各因素与物理量间的定量关系，得到的拟合公式能较好地描述相似材料的性质.     

Reconsideration on Homogeneous Quadratic Riemann Boundary Value Problem

The homogeneous quadratic Riemann boundary value problem (1) with Hoelder continuous coefficients for the normal case was considered by the author in 1997. But the solutions obtained there are incomplete. Here its general method of solution is obtained.     

含PM-映射的变分不等式

文章在自反Banach空间中，利用锐角原理讨论了含PM-映射的变分不等式解的存在性问题。     

新时期档案工作浅议

为接受新时期档案工作所面临的机遇与挑战，档案工作必须体现其时代性、把握其规律性、并要富于创造性，实现服务功能的多元化与服务效率的最大化，为两个文明事业的发展提供源源不断的信息资源支持。