全文获取类型
收费全文 | 1908篇 |
免费 | 277篇 |
国内免费 | 125篇 |
专业分类
化学 | 295篇 |
晶体学 | 4篇 |
力学 | 183篇 |
综合类 | 12篇 |
数学 | 214篇 |
物理学 | 708篇 |
综合类 | 894篇 |
出版年
2024年 | 12篇 |
2023年 | 18篇 |
2022年 | 47篇 |
2021年 | 59篇 |
2020年 | 39篇 |
2019年 | 51篇 |
2018年 | 50篇 |
2017年 | 89篇 |
2016年 | 84篇 |
2015年 | 72篇 |
2014年 | 122篇 |
2013年 | 111篇 |
2012年 | 124篇 |
2011年 | 134篇 |
2010年 | 94篇 |
2009年 | 119篇 |
2008年 | 134篇 |
2007年 | 120篇 |
2006年 | 112篇 |
2005年 | 99篇 |
2004年 | 89篇 |
2003年 | 64篇 |
2002年 | 62篇 |
2001年 | 79篇 |
2000年 | 45篇 |
1999年 | 38篇 |
1998年 | 32篇 |
1997年 | 42篇 |
1996年 | 30篇 |
1995年 | 33篇 |
1994年 | 13篇 |
1993年 | 21篇 |
1992年 | 11篇 |
1991年 | 11篇 |
1990年 | 14篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有2310条查询结果,搜索用时 0 毫秒
51.
一条理想的量子线同一条无序量子线耦合在一起,理想链中能量为E的电子波函数,能被无序链中某些格点能量Vn,2在电子能量E附近的格点强烈散射.在Vn,2=E格点,能量为E的电子波函数能发生全反射,也就是"反共振效应".在无序度W较大时,随着W的增大,无序链中能够强烈影响周期链的格点数减少,这使得周期链中电子的局域长度增大,与数值计算结果一致. 相似文献
52.
A large sample size is required for Monte Carlo localization (MCL) in multi-robot dynamic environ- ment, because of the "kidnapped robot" phenomenon, which will locate most of the samples in the regions with small value of desired posterior density. For this problem the crossover and mutation operators in evolutionary computation are introduced into MCL to make samples move towards the regions where the desired posterior density is large, so that the sample set can represent the density better. The proposed method is termed genetic Monte Carlo localization (GMCL). Application in robot soccer system shows that GMCL can considerably reduce the required number of samples, and is more precise and robust in dynamic environment. 相似文献
53.
《Physics letters. A》2020,384(21):126426
Using density functional theory combined with a global crystal structure search with the particle swarm optimization method, we propose three stable three-dimensional (3D) metallic RhP structures, namely, the Cmcm (RhP-I), P6/mmm (RhP-II), and P63mc (RhP-III) phases. All these structures are found to be dynamically stable through vibrational normal mode calculations, indicating that they could be successfully synthesized in experiments. We show that the RhP-I phase has a relatively high thermodynamic stability and high mechanical strength in comparison with the others. The RhP-II and RhP-III phases have porous structures which could accommodate small atoms or molecules. However their thermodynamics are poor, especially the RhP-III phase. The RhP-II structure is stable at 500 K, but the RhP-III fails to survive even at the freezing point of water. Importantly, all these materials have one dimensional conducting channels corresponding to ultrahigh Fermi velocities. Moreover, the porous hexagonal RhP-II and III structures exhibit excellent ability to trap lithium, hydrogen, oxygen, and boron atoms. The RhP-II structure could be especially useful for directly dissociating the hydrogen molecule into two atoms without an energy barrier. In the present study, we identify three new metallic structures to the family of RhP structures, and anticipate their potential for technological applications. 相似文献
54.
We present the analysis of a nonlinear controlsystem that is used to excite and maintain a specified amplitude ofoscillation in the Jet Propulsion Laboratory vibratory gyroscope.This experimental application shows that nonlinear localizationthrough active means can be implemented in a practical system when itis desirable to confine the response to a favorable mode. Theclosed-loop system response predicted by the model shows very closeagreement with the experimental results for a significant range ofcontroller parameters. We also experimentally demonstrate that theactively localized motion is eliminated through bifurcation, similarto what was observed in previous passive localization studies appliedto extended flexible oscillators. 相似文献
55.
基于一阶振型斜率的剪切型建筑结构损伤定位 总被引:3,自引:0,他引:3
提出了一种利用结构一阶振型斜率改变判断剪切型结构损伤位置的方法.首先,进行结构振型和振型斜率对损伤的敏感性分析,导出敏感性系数表达式.然后,计算结构损伤前后的一阶振型斜率差.最后,在敏感性分析和计算得到的结构一阶振型斜率差的基础上,通过迭代计算消除多损伤引起的振型斜率改变叠加进行损伤定位.通过10层剪切型框架结构不同损伤工况的数值分析表明,所提出的算法能够正确识别所有的损伤位置. 相似文献
56.
《中国科学:化学(英文版)》2012,(7):1387-1394
The nature of the Ga-Ga bonding in Na2[Arx*GaGaArx*](Arx* = C6H3-2,6-(C6H5)2) has been investigated and compared with that of in H2[Arx*GaGaArx*] using electron localization function(ELF) and orbital analysis.The calculation results show that in Na2[Arx*GaGaArx*],the Ga-Ga interaction is a non-classical triple bond,the heart of Na2[Arx*GaGaArx*] is the Ga2Na2 cluster rather than a simple Ga-Ga bond,and the contribution of the sodium atoms to the short Ga-Ga bond length is considerable.As the two sodium atoms are substituted by two hydrogen atoms,the Ga-Ga bond is replaced by two 3-center,2-electron(3c-2e) Ga-H-Ga covalent bridged bonding. 相似文献
57.
通过在位库伦校正的密度泛函理论(DFT+U)方法计算,我们研究了CO和NOx分子在Au负载CeO2(110)表面的吸附. 结果表明,CO在Au纳米颗粒的顶位有很强的吸附能,大约为1.2 eV,而NO在Au纳米颗粒上或者Au与CeO2载体界面处都是弱吸附. 然而,当NOx在界面处形成N2O2二聚体之后,通过断裂末端的N-O键能够有效地被降解. 纵观整个反应过程,第一步CO+N2O2的反应遵循了Langmuir-Hinshelwood机理,活化能只有0.4 eV,通过形成ONNOCO的中间物种最终产生N2O和CO2. 不同的是,第二步消除N2O反应遵循了Eley-Rideal碰撞机理,需要相当高的能垒,约为1.8 eV. 通过进一步分析表明,稀土Ce元素独特的电子特性能够使电子从Au上转移并且局域到载体表面的Ce阳离子上,并且有助于形成带负电的N2O2分子. 而且Au纳米颗粒有很强的结构流动性,能够促进吸附的CO分子靠近界面处的N2O2并与之反应. 相似文献
58.
Aneta Sulborska-Rycka Elbieta Weryszko-Chmielewska Beata Polak Beata Stefaczyk Anna Matysik-Wo
niak Robert Rejdak 《Molecules (Basel, Switzerland)》2022,27(4)
(1) Background: Centaurea cyanus L. is a medicinal plant whose flowers are widely used in herbal medicine. The aim of the study was to localise flower tissues that are responsible for the production of secretory products in petals and to analyse the volatile compounds. The volatile compounds of the flowers of this species have not been investigated to date. (2) Methods: Light, fluorescence, scanning and transmission electron microscopy techniques were used in the study. Lipophilic compounds were localised in the tissues using histochemical assays. Volatile compounds were determined with the use of solid phase microextraction (SPME) and gas chromatography-mass spectrometry (GC-MS). (3) Results: The study showed production of secretion in the petal parenchyma, whose ultrastructure has features of a secretory tissue. The lipophilic secretion was localised in the cells and intercellular spaces of the parenchyma and in the walls and surface of epidermal cells, where it accumulated after release through cuticle microchannels. Sesquiterpenes were found to constitute the main group of volatile compounds, with the highest content of β-caryophyllene (26.17%) and α-humulene (9.77%). (4) Conclusions: Given the presence of some volatile components that are often found in resins (caryophyllene, delta-cadinene) and the abundant secretion residues on the epidermal surface, we suppose that the C. cyanus secretion released by the flowers is a resinaceous mixture (oleoresin), which is frequently found in plants, as shown by literature data. This secretion may play an important role in the therapeutic effects of C. cyanus flowers. 相似文献
59.
对失谐肋环形平面结构的振动模态局部化问题进行了研究。将径向杆模拟为一端固定一端简支的超静定梁。环向连接杆模拟为无质量的线弹簧,采用Hamilton变分原理和Galerkin方法,导出了系统的运动方程表达式。分别计算出了谐调和失谐情况下的模态振型,并对计算结果进行分析讨论。 相似文献
60.
Piotr Garbaczewski 《Journal of statistical physics》2006,123(2):315-355
We analyze the functioning of Gibbs-type entropy functionals in the time domain, with emphasis on Shannon and Kullback-Leibler entropies of time-dependent continuous probability distributions. The Shannon entropy validity is extended to probability distributions inferred from L
2(R
n
) quantum wave packets. In contrast to the von Neumann entropy which simply vanishes on pure states, the differential entropy quantifies the degree of probability (de)localization and its time development. The associated dynamics of the Fisher information functional quantifies nontrivial power transfer processes in the mean, both in dissipative and quantum mechanical cases.
PACS NUMBERS: 05.45.+b, 02.50.-r, 03.65.Ta, 03.67.-a 相似文献