Analytical procedure to simultaneously measure trace amounts of trenbolone acetate and beta-trenbolone residues in porcine muscle using HPLC-UVD and MS

The current study was undertaken to validate the performance for the determination of both TBA and beta-trenbolone (beta-TB) residues in porcine muscle at concentrations required to monitor compliance with the maximum residue limit (MRL). The method involves a one phase liquid-liquid extraction, cleanup with low-temperature fat precipitation, separation of the respective compounds by HPLC on a Capcell pak C(18) column, use of a methanol-water isocratic system as an eluent, and measurement by UV absorbance detection at 340 nm. Both compounds were confirmed using LC-MS/MS with electrospray interface (ESI) and a triple quadrupole (QqQ) analyzer. The method was found to be precise and accurate, with a linearity range of 1-10 microg/kg (r(2) >0.973). The intra- and interday precision showed good reproducibility with RSDs < or =13.25%. The LODs were 0.12 and 0.22 microg/kg, and the LOQs were 0.37 and 0.66 microg/kg, for TBA and beta-TB, respectively. The applicability of the method was demonstrated by analyzing real samples collected from major cities in the Republic of Korea. No residues of the selected compounds were detected in any of the samples. The advantages of our method are that it is: selective, sensitive, requires a short time for analysis (13 min), and performs simple sample extraction and clean-up procedure with low-temperature fat precipitation as compared to the previously published methods.     

钒的一个特别灵敏指示反应

本文研究了钒（V）在乙酸介质中催化溴酸钾氧化钙试剂羧酸钠盐的褪色反应。本方法的灵敏度为2.5×101?g/ml,与同类方法相比为最高,测定范围为0～4ngV/25ml。本法已用于水样中超痕量钒测定。     

导数原子吸收光谱法直接测定水中痕量元素

提出了导数原子吸收光谱法直接测定水中痕量元素的方法,它是基于测定导数原子吸收值,即吸光度随时间的变化率来提高原子吸收分析灵敏度的一种新技术。方法具有简单快速,灵敏度高,检出限低的优点,可直接用于水质的常规分析。     

PAN分光光度法测定全珍珠水解液中微量铜

探讨了用Cu-1-(2-吡啶偶氮)-2-萘酚分光光度法测定珍珠水解液中微量铜的最佳条件.在HCl-KCl溶液介质中,十二烷基苯磺酸钠存在下,其表观摩尔吸光系数为1.42×104L·mol-1·cm-1,Gu2+含量在0-100μg/50m1范围服从比尔定律,检测限为0.5μg/dms.应用于珍珠水解液制备的工艺优化中指标控制,效果良好.     

放大反应-氯化钠增敏光度法测定食品中的微量碘

样品中的有机碘高温灰化后,在酸性条件下,经饱和溴水将I^-氧化为IO3^-.在0．06％的磷酸酸度条件下,以KI还原KIO3,使样品中的碘放大六倍。系统优化选择了定波长、磷酸酸度、氯化钠质量浓度、淀粉用量、碘化钾用量等。在选定的最佳实验条件下,碘质量浓度在0～3．2μg／mL范围旱良好线性关系,相关系数为0．9995;方法榆出限为0．028μg／mL,回收率为96．27％～106．43％。     

固定资产减值会计之探讨

本文从《企业会计制度》和《企业会计准则——固定资产》出发，结合国际惯例，就固定资产减值会计的某些核心问题提出个人的观点和建议。     

Molecular iodine-catalyzed one-pot synthesis of 4-substituted-1,4-dihydropyridine derivatives via Hantzsch reaction

A simple, inexpensive and efficient one-pot synthesis of 1,4-dihydropyridine derivatives at room temperature using catalytic amount of iodine were reported with excellent product yields. An easy access to various substituted 1,4-dihydropyridine derivatives quantitatively using commercially available iodine as a catalyst.     

贝叶斯模型平均及其在北京降雨预报中的一个应用

贝叶斯模型平均(Bayesian Model Averaging:BMA)是动态建模中融合集合预报信息的一种重要统计后处理方法.本文首先系统论述了BMA的建模分析过程,包括模型架构、参数估计方法、训练期的选择准则以及典型预报分布的抽样原理.然后,结合北京市2011年5—8月份逐日累积降雨量实例,我们详细描述了BMA的实现过程.实例分析结果表明,BMA统计后处理,无论是精度还是校准度,相对于原始集合预报都有优势.     

苏北运河沿线航运市场需求分析预测

采用增长率法对苏北运河10个主要船闸总货物通过量进行预测，运用回归分析法预测典型船闸的货物通过量，对苏北运河沿线航运市场需求潜力进行预测并分析了各船闸的极限货物通过能力．     

保险费收取次数为Poisson过程的破产概率

经典的破产模型都是假定保险公司按照意境全时间常数速率收取保险费。在考虑保险费收入是一个Ｐｏｓｉｉｏｎ过程的基础上，讨论了盈余过程｛Ｒ（ｔ）ｔ≥０｝的性质，利用这些性质，给出了关于破产概率的一个定理，得到了与经典破产模型相同的不等式。