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141.
层流液柱吸收法测定气体在液相中的扩散系数 总被引:2,自引:0,他引:2
采用射流吸收的简捷方法,通过测定由Shouthwell型孔板所产生的截面速度均匀的层流喷射液柱所吸收的气体量,由渗透理论所导出的模型,可计算出一定温度、压力下的微溶气体在液相中的分子扩散系数D。在温度为30~45℃的范围,测试结果与文献值吻合良好. 相似文献
142.
具有非局部边界条件的奇摄动反应扩散问题 总被引:2,自引:0,他引:2
本文研究了一类具有非局部边界条件的奇摄动反应扩散初始边值问题.在适当的条件下,利用比较定理讨论了问题解的渐近性态. 相似文献
143.
The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and 13C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (Tg) for the in situ blends, contrary to an increase of Tg with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007 相似文献
144.
We consider a spatially distributed hybrid system consisting of a convection/reaction system in which the reaction switches discontinuously in time between modes, independently at each spatial point on reaching “switching thresholds”. The model involves a novel formulation for evolution of the free boundary between the modal regions. 相似文献
145.
G. N. Merrill 《Journal of Physical Organic Chemistry》2007,20(1):19-29
Ab initio molecular orbital calculations were carried out on epibromohydrin (EBH) and epichlorohydrin (ECH) in an attempt to elucidate their reactivity with respect to a hard nucleophile, hydroxide. These systems were modeled in both the gas phase and a polar solvent under basic conditions. In the gas phase, it was determined that a direct displacement mechanism (nucleophilic attack at the C1 position) was operative for EBH, while an indirect pathway (nucleophilic attack at the C3 position and subsequent intramolecular displacement) was followed for ECH. In an acetone solution, only the indirect displacement mechanism was found to occur. An electrostatic argument is advanced to account for this behavior in polar solution. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
146.
147.
Vicenç Branchadell Roser Pleixats Claude Commandeur Max Malacria 《Journal of organometallic chemistry》2003,687(2):337-345
Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom. 相似文献
148.
This paper deals with a model of time-dependent double diffusive convection in Darcy flow. In particular it is concerned with the spatial decay of solutions when the flow is confined to a semi-infinite cylinder. Decay bounds for an energy expression are derived. 相似文献
149.
150.
We consider systems of two pure one-dimensional diffusion equations that have considerable interest in Soil Science and Mathematical Biology. We construct non-local symmetries for these systems. These are determined by expressing the equations in a partially and wholly conserved form, and then by performing a potential symmetry analysis on those systems that can be linearised. We give several examples of such systems, and in a specific case we show how linearising and hodograph-type mappings can lead to new solutions of the diffusion system. 相似文献