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991.
基于von Karman薄板理论和Hamilton原理,运用假设时间模态法,得到了弹性地基上加热圆板非线性轴对称自由振动的常微分控制方程.考虑不可移简支边界条件,采用打靶法得到了一阶屈曲位形下的前3阶振型的数值结果.结果表明:随地基弹性系数增加,热屈曲临界温度增加;在小振幅的情形下,振型对屈曲构型的影响和地基系数对振型... 相似文献
992.
七水硫酸锌脱水机理热力学初探 总被引:1,自引:0,他引:1
通过差热/热重综合分析仪(DTA/TGA)测定ZnSO4.7H2O的失水过程,并对DTA,TG图谱进行分析。分析结果表明:在低温下(373K以下),水合盐先失液态水,由ZnSO4.7H2O分别失去1分子、5分子液态水,而生成Zn-SO4.H2O。在高温下(513~553K),ZnSO4.H2O直接失去气态水,而生成ZnSO4。并从热力学理论上对ZnSO4.7H2O的脱水过程机理进行解释。 相似文献
993.
A sequence of random variables X0,X1, … with values in {0, 1, …, n} representing a general finite-state stochastic process with absorbing state 0 is said to be directionally biased towards 0, if, for all j > 0, ϵj: = infk>0 {j − E[Xk | Xk−1 = j]} > 0. For such sequences, let t be the expected value of the time to absorption at 0. For a fixed set of biases, the least upper bound for this time can be computed with an algorithm requiring O(n2) steps. Simple upper bounds are described. In particular, t ≤ E[bx0], where bi = Σj≤i 1/¯ϵj and ¯ϵj = minl≥j {ϵl}. If all ϵj ≤ ϵj + 1 (so ¯ϵj = ϵj) and ϵn < 1, this bound for t is the best possible. For certain finite stochastic processes which we term conditionally independent of X0 = i, b(i) bounds the expected time given X0 = i. Similar results are given for lower bounds. The results of this paper were designed to be a useful tool for determining rates of convergence of stochastic optimization algorithms. © 1996 John Wiley & Sons, Inc. 相似文献
994.
Ioakim K. Spiliopoulos John A. Mikroyannidis 《Journal of polymer science. Part A, Polymer chemistry》1996,34(13):2799-2807
Various unsaturated polyamides and polyesters were prepared from the reactions of 1,4-bis(2-carboxyvinyl)benzene acid chloride with aromatic diamines and bisphenols, respectively. In addition, various unsaturated homo- and copolyesters were synthesized from 4-hydroxycinnamic acid and 4-hydroxybenzoic acid. They were heat-cured to thermally stable resins. The polymers were characterized by inherent viscosity measurements, FT-IR, x-ray, DTA, TMA, TGA, and isothermal gravimetric analysis. The water absorption as well as the solubility behavior of the polymers was also investigated. © 1996 John Wiley & Sons, Inc. 相似文献
995.
Toru Doi Akira Akimoto Akikazu Matsumoto Takayuki Otsu 《Journal of polymer science. Part A, Polymer chemistry》1996,34(3):367-373
Radical copolymerization of N-methylmaleimide (MeMI) as well as other N-alkylmaleimides (RMI) and isobutene (IB) was carried out with 2,2′-azobis(isobutyronitrile) as an initiator at 60°C. The initial rate of the copolymerization (Rp) was dependent on the monomer composition and was maximum at the 40 mol % of MeMI in the feed. A solvent effect on the Rp and the monomer reactivity ratio was observed in this copolymerization system, i.e., copolymerization in chloroform produced a higher Rp and an alternating tendency compared with those in dioxane (rMeMI = 0.14, r1B = 0 in chloroform and rMeMI = 0.47, r1B = 0 in dioxane). The alternating copolymer of RMI and IB shows a high glass transition temperature (Tg) and excellent thermal stability, e.g., the Tg and the thermal decomposition temperature (Td) were 152 and 363°C, respectively, for the alternating copolymer of MeMI and IB. Both the Tg and Td increased as the concentration of the MeMI unit in the copolymers increased. Colorless transparent sheets were obtained from press molding the alternating copolymers. They showed excellent mechanical and optical properties. © 1996 John Wiley & Sons, Inc. 相似文献
996.
997.
Masayuki Oba 《Journal of polymer science. Part A, Polymer chemistry》1996,34(4):651-658
The effect of new additives on the thermal conversion of a range of polyamic acids to polyimides at temperatures lower than 100°C was investigated using infrared spectroscopy. Additives such as m-hydroxybenzoic acid, p-hydroxyphenylacetic acid, and p-hydroxybenzenesulfonic acid were found to be highly effective as curing catalysts or accelerators. The degree of imidization of polyamic acids in the presence of additives increased with an increase in the reaction temperature, and complete imidization was achieved at 140–200°C. The reaction was characterized by a rapid rate that slowed with time. © 1996 John Wiley & Sons, Inc. 相似文献
998.
John A. Mikroyannidis 《Journal of polymer science. Part A, Polymer chemistry》1996,34(16):3389-3397
New aromatic polyamide and polyimides were prepared from di(aminophenyl)acetylenediurea. In addition, model compounds were synthesized and their IR spectra were in agreement with those of the corresponding polymers. The polymers were amorphous and readily soluble in polar aprotic solvents (DMF, NMP, DMSO) and certain acids (H2SO4, CCl3COOH). The hydrophilicity of polyamide was estimated by measuring the isothermal water absorption. The polyamide softened at 260°C but no softening was observed for polyimides. The glass transition temperatures of polymers were determined by the TMA method and they were in the range of 235–310°C. The polymers were stable up to 359–404°C in N2 or air and afforded char yields of 53–65% at 800°C in N2. © 1996 John Wiley & Sons, Inc. 相似文献
999.
L. Rodier-Renaud S. L. Randzio J.-P. E. Grolier J. R. Quint J. Jarrin 《Journal of Polymer Science.Polymer Physics》1996,34(7):1229-1242
A pressure-controlled scanning calorimeter (PCSC) has been applied for measuring the isobaric volume thermal expansivities (αp) of crystalline polymers as a function of pressure up to 300 MPa at various temperatures. The measurements have been performed for several well-defined polyethylenes with various degrees of crystallinity at 302.6, 333.0, 362.6, and 393.0 K. The results are reported as values of coefficients in a correlation equation, which facilitates the use of reported data over large ranges of temperature and pressure. The general pressure-temperature behavior of αp for all polyethylenes under study is such that αp increases with temperature and decreases with pressure. The increase with temperature is smaller at high pressures and the isotherms of αp have a tendency to converge at high pressures; αp decreases linearly with the crystallinity of the polyethylene over the whole range of pressure and temperature under investigation. From the linear approximation of experimental data for polyethylenes with various crystallinities the estimated αp for both crystal and amorphous phases of polyethylenes have been determined as a function of pressure up to 300 MPa at 302.6, 333.0, and 362.5 K. The obtained results have been compared with available literature crystallographic data and with the values derived from the Pastine theoretical equation of state for both crystalline and amorphous phases. © 1996 John Wiley & Sons, Inc. 相似文献
1000.
Francesco A. Bottino Giovanna Di Pasquale Nicoletta Leonardi Antonino Pollicino 《Journal of polymer science. Part A, Polymer chemistry》1996,34(7):1305-1310
High molecular-weight aromatic polyamides were obtained from 1,5- and 2,6-bis-(4′-carboxy-4-phenylenoxy-sulfonyl)naphthalene by direct polycondensation reaction in N-methyl-2-pyrrolidone with various aromatic diamines, using triphenyl phosphite and pyridine as condensing agents. The polymers were characterized by elemental analysis, thermogravimetric analysis, differential scanning calorimetry, and infrared analysis. The polyamides, obtained in quantitative yield, possessed inherent viscosities in the range 0.42–1.70 dL/g, glass transition temperatures between 245–310°C, and 10% weight loss temperatures in nitrogen and air above 435 and 424°C, respectively. Most of the polymers were soluble in aprotic solvents. The effect of the structure on properties, such as solubility, Tg, and thermal behavior, were also studied. © 1996 John Wiley & Sons, Inc. 相似文献