Xyloccensin L, a novel limonoid from Xylocarpus granatum

The isolation and structure elucidation of xyloccensin L from the stem bark of Xylocarpus granatum is described. Xyloccensin L is a highly oxidized heptacyclic A, B, D-seco limonoid with an α-8, 30-epoxy ring and a rare 1, 29 oxygen bridge.     

硼烷缺电子多中心桥键的H-F力研究

Hellmann-Feynman静电力表现了分子中电荷分布及对各原子核的作用。H-F力的方向性可描述电子电荷的数量和位置,具有定量、形象和直观的特点,已在弯键的研究中显示出来。这一方法尚可用于多中心缺电子桥键的研究。 1 理论与方法 按LCAO-MO理论对H-F力进行分解,除有重叠力、极化力和屏蔽力外,还有一     

Electronic communication through the ureylene bridge: spectroscopy, structure and electrochemistry of dimethyl 1,1-ureylenedi(1-ferrocenecarboxylate)

Dimethyl 1^′,1^′-ureylenedi(1-ferrocenecarboxylate) (1) formed during the synthesis of 1-amino, 1^′-ferrocenecarboxylic acid shows virtual molecular centrosymmetry. Electronic coupling between the two Fc groups through the ureylene bridge results in both Fc groups being individually oxidizable (ΔE_1/2?0.14 V). The possible existence of intermolecular electronic communication has discussed. The oxidation was followed by spectroelectrochemistry. The separation between the two halfwave potentials ΔE_1/2=137±5 mV and the comproportionation constant K_c=207.     

A,C-Bridged Calix[6]arene： Relationship between the Length of Bridge and Conformation

Three new A,C-diamide bridged p-tert-butylcalix[6]arenes were synthesized from p-tert-butylcalix[6]arenes by bridging ClCH2CONH(CH2)nNHCOCH2Cl(n=3,4,6) in acetonitrile using K2CO3 as a base in 17%-25% yields.It was found that the bridged calix[6]arenes with shorter bridges (n=2,3,4 in N′,N′-bischloroacetodiamines) adopt cone conformation, but the last one (n=6) adopts alternate conformation, i.e., accompanying the lengthening of bridge, the conformation of A,C-bridged calix[6]arenes changes from cone to alternate.     

Limit theorems for trimmed sums

This paper studies the heavily trimmed sums (*) _{[ns] + 1} ^[nt] X _j ⁽ⁿ⁾ , where {X _j ⁽ⁿ⁾ } _{j = 1} ⁿ are the order statistics from independent random variables {X ₁,...,X _n } having a common distributionF. The main theorem gives the limiting process of (*) as a process oft. More smoothly trimmed sums like _{j = 1} ^[nt] J(j/n)X _j ⁽ⁿ⁾ are also discussed.     

Investigation of the metal binding site in methionine aminopeptidase by density functional theory

All methionine aminopeptidases exhibit the same conserved metal binding site. The structure of this site with either Co²⁺ions or Zn²⁺ions was investigated using density functional theory. The calculations showed that the structure of the site was not influenced by the identity of the metal ions. This was the case for both of the systems studied; one based on the X-ray structure of the human methionine aminopeptidase type 2 (hMetAP-2) and the other based on the X-ray structure of the E. colimethionine aminopeptidase type 1 (eMetAP-1). Another important structural issue is the identity of the bridging oxygen, which is part of either a water molecule or a hydroxide ion. Within the site of hMetAP-2 the results strongly indicate that a hydroxide ion bridges the metal ions. By contrast, the nature of the oxygen bridging the metal ions within the metal binding site of eMetAP-1 cannot be determined based on the results here, due to the similar structural results obtained with a bridging water molecule and a bridging hydroxide ion.     

青藏铁路清水河段多年冻土区站场路基的试验研究

通过对青藏铁路清水河段站场路基的初步试验,获取了地温变形数据,探讨站场路基的冻结和融化过程的规律.实验表明:站场路基下冻土人为上限发生了上移,多年冻土得到了保护,为类似路段多年冻土工程提供借鉴.     

用频域法识别桥梁的模态参数

根据大型土木结构环境振动的特点,利用频域法对桥梁的模态参数进行识别,详细阐述了峰值检测法和复模态指示函数法识别桥梁模态参数的理论依据和实现方法,对比了两种方法各自的特点.利用香港汀九大桥的实测数据,辨识出了桥梁的模态参数,最后的辨识结果表明该方法在具体的工程应用中的有效性.     

既有铆接铁路钢桥剩余寿命的评估

为确保既有铆接铁路钢桥使用安全，探讨了评估既有铆接铁路钢桥疲劳剩余寿命的方法。以京九线赣江桥为例，介绍了基于断裂力学的既有铆接铁路钢桥剩余寿命评估的原理与方法。基于断裂力学的评估过程主要包括如下4个步骤：识别临界构件、计算临界裂纹尺寸、疲劳裂纹扩展模拟、确定探测间隔。根据赣江桥剩余寿命评估结果：若按保证桥梁的正常使用功能，超声波探测间隔为1a；若按保证主桁结构承载安全，则探测间隔为3a。     

在役桥梁结构延性系数的动力评价方法

以桥墩的基本振型函数为基础,推导出基于试验动力参数的在役桥梁结构延性系数的计算公式,并给出了结构非弹性地震力的求解方法。对室内钢模型桥利用冲击力锤法进行了模态试验和静力对比试验,实测参数与理论值相差仅2%,在此基础上利用给出的公式可以求得桥墩的变形增加系数为2.78。结果表明,在场地土条件未知的情况下,利用动力试验法对在役桥梁结构延性系数进行评价是可行的。