Matrix effects in the determination of butyltin compounds in environmental samples by GC AA after hydride generation

Experiments for the determination of mono-, di and tri-butyltin (MBT, DBT and TBT) by hydride generation/gas chromatography/atomic absorption spectrometry in various matrices (sediment, suspended matter, mussel, algae and water) have revealed that poor butyltin recoveries are obtained in sediments displaying high sulphur and hydrocarbon contents; very poor recoveries were also observed for TBT in sediments with high chlorophyll pigment contents as well as in algal samples. It was however not clear whether the hydride generatin was inhibited by these infering compounds, as was previously assumed in the case of hydrocarbons, or whether interferences affected the atomization rate. Further studies were performed to solve this problem in order to validate this method in the case of analyses of, for example, oil-contaminated sediment and algae. This paper presents the results obtained. It is concluded here that the poor recoveries were due to an inhibition of hydride generation rather than to interference at the atomization stage.     

普遍的洛伦兹变换式的两种推导方法

给出了由特殊洛伦兹变换式到一般洛伦益变换式的两种推导方法．     

区间动力系统稳定性分析的最新进展

综述了区间力系统稳定性,广义区间动力系统正则、无脉冲膜、稳定性方面的近期结果,并对其中一些结论所使用的工具及方法进行了总结.     

含第三对称平均值比的一个不等式及其应用

借助于数学归纳法建立了含第三对称平均值比的一个不等式 ,并将此结果用于正定矩阵 ,获得了一个有趣的结果 .     

四元数矩阵的伴随性质

利用代数的方法，研究了四元数矩阵的伴随性质，得出了一系列有意义的新结果．     

关于矩阵方程AXB=CYD

应用矩阵的初等变换技巧，给出了任意域上矩阵方程AXB=CYD的通用表达式及解法。     

大型喷浆机器人的灵巧度分析

灵巧度是衡量机器人运动失真程度的重要参数。对机器人灵巧度评价指标进行了对比研究 ,结合大型喷浆机器人自由度较多的特点 ,用雅可比矩阵的条件数对喷浆机器人的灵巧度进行了分析。结果表明 ,大型喷浆机器人在不同形位下的条件数都很小 ,具有较好的运动灵巧度。     

Morphology of Nylon-6 blends with styrenic polymers

The morphology of blends of styrenic polymers in a matrix of 75% Nylon-6 prepared in a Brabender Plasti-Corder was examined by scanning electron microscopy. Styrene/acrylonitrile copolymers (SAN) form smaller particles as the AN level increases owing to the corresponding decrease in the SAN–polyamide interfacial tension. Various styrenic polymers containing functional groups, maleic anhydride or oxazoline type, that can react with Nylon-6 during melt processing were added to the SAN phase which also led to a decrease in the particle size owing to the graft copolymer formed in situ. The effects of functional group type, amount of functional groups per chain, amount of functional polymer added, and the miscibility of the styrene/maleic anhydride (SMA) and SAN copolymers on the morphology of the styrenic phase in the Nylon-6 matrix are described. © 1992 John Wiley & Sons, Inc.     

N阶幻体及其初等性质

幻方和幻立方是组合数学中古老问题,它们体现了数字间关系的优美性与和谐性.本文基于幻方和幻立方的理论引入了幻体,给出了其存在性定理的证明,并进一步讨论了幻体的初等性质.