全文获取类型
收费全文 | 15533篇 |
免费 | 3467篇 |
国内免费 | 1660篇 |
专业分类
化学 | 4179篇 |
晶体学 | 71篇 |
力学 | 228篇 |
综合类 | 107篇 |
数学 | 1318篇 |
物理学 | 11188篇 |
综合类 | 3569篇 |
出版年
2024年 | 68篇 |
2023年 | 225篇 |
2022年 | 651篇 |
2021年 | 609篇 |
2020年 | 568篇 |
2019年 | 497篇 |
2018年 | 446篇 |
2017年 | 463篇 |
2016年 | 625篇 |
2015年 | 598篇 |
2014年 | 888篇 |
2013年 | 1115篇 |
2012年 | 965篇 |
2011年 | 1120篇 |
2010年 | 863篇 |
2009年 | 909篇 |
2008年 | 1117篇 |
2007年 | 1140篇 |
2006年 | 1083篇 |
2005年 | 958篇 |
2004年 | 829篇 |
2003年 | 726篇 |
2002年 | 708篇 |
2001年 | 508篇 |
2000年 | 539篇 |
1999年 | 372篇 |
1998年 | 405篇 |
1997年 | 312篇 |
1996年 | 213篇 |
1995年 | 181篇 |
1994年 | 155篇 |
1993年 | 153篇 |
1992年 | 131篇 |
1991年 | 76篇 |
1990年 | 102篇 |
1989年 | 83篇 |
1988年 | 51篇 |
1987年 | 45篇 |
1986年 | 42篇 |
1985年 | 28篇 |
1984年 | 23篇 |
1983年 | 8篇 |
1982年 | 12篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1978年 | 11篇 |
1976年 | 5篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1972年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
51.
用经典力学和双波量子力学计算了氢原子的固有电偶极矩。双波量子理论算得的结果在经典极限下与经典力学的结果一致。普通量子力学对氢原子Stark效应中表现出来的电偶极矩难以做出很好的解释,因为一个波函数描述的是系综而不是单个粒子。经典力学和双波量子力学可描述单个粒子的行为,对永久电偶极矩的计算和解释显得自然而合理。 相似文献
52.
Andrzej Kaim 《Journal of polymer science. Part A, Polymer chemistry》2007,45(2):232-241
The competitiveness of the combination and disproportionation reactions between a 1‐phenylpropyl radical, standing for a growing polystyryl macroradical, and a 2,2,6,6‐tetramethyl‐1‐piperidinyloxy (TEMPO) radical in the nitroxide‐mediated free‐radical polymerization of styrene was quantitatively evaluated by the study of the transition geometry and the potential energy profiles for the competing reactions with the use of quantum‐mechanical calculations at the density functional theory (DFT) UB3‐LYP/6‐311+G(3df, 2p)//(unrestricted) Austin Model 1 level of theory. The search for transition geometries resulted in six and two transition structures for the radical combination and disproportionation reactions, respectively. The former transition structures, mainly differing in the out‐of‐plane angle of the N? O bond in the transition structure TEMPO molecule, were correlated with the activation energy, which was determined to be in the range of 8.4–19.4 kcal mol?1 from a single‐point calculation at the DFT UB3‐LYP/6‐311+G(3df, 2p)//unrestricted Austin Model 1 level. The calculated activation energy for the disproportionation reaction was less favorable by a value of more than 30 kcal mol?1 in comparison with that for the combination reaction. The approximate barrier difference for the TEMPO addition and disproportionation reaction was slightly smaller for the styrene polymerization system than for the acrylonitrile polymerization system, thus indicating that a β‐proton abstraction through a TEMPO radical from the polymer backbone could diminish control over the radical polymerization of styrene with the nitroxide even more than in the latter system. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 232–241, 2007 相似文献
53.
Fabio Scardigli 《Foundations of Physics》2007,37(8):1278-1295
The Titius–Bode law for planetary distances is reviewed. A model describing the basic features of this rule in the “quantum-like”
language of a wave equation is proposed. Some considerations about the ’t Hooft idea on the quantum behavior of deterministic
systems with dissipation are discussed. 相似文献
54.
Reduction of tetranuclear heterometallic complex Mo2Mg2 was simulated using the B3LYP and PBE density functional methods. The results of geometry calculations of the initial complex
[MoVIO2Mg(MeOH)2(OMe)4]2 and a partially reduced MoV complex are in good agreement with experimental data. The reduced MoIII complex is characterized by a decrease in the binding energy of aqua ligands. Structural rearrangement of the complex with
release of a coordination position at the Mo atoms requires small energy expenditure. One can assume that the reduction of
the polynuclear complex causes overcrowding of its coordination sphere, which favors formation of dinitrogen complexes.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 441–457, March, 2008. 相似文献
55.
In this paper, a projection method is presented for solving the flow problems in domains with moving boundaries. In order to track the movement of the domain boundaries, arbitrary‐Lagrangian–Eulerian (ALE) co‐ordinates are used. The unsteady incompressible Navier–Stokes equations on the ALE co‐ordinates are solved by using a projection method developed in this paper. This projection method is based on the Bell's Godunov‐projection method. However, substantial changes are made so that this algorithm is capable of solving the ALE form of incompressible Navier–Stokes equations. Multi‐block structured grids are used to discretize the flow domains. The grid velocity is not explicitly computed; instead the volume change is used to account for the effect of grid movement. A new method is also proposed to compute the freestream capturing metrics so that the geometric conservation law (GCL) can be satisfied exactly in this algorithm. This projection method is also parallelized so that the state of the art high performance computers can be used to match the computation cost associated with the moving grid calculations. Several test cases are solved to verify the performance of this moving‐grid projection method. Copyright © 2004 John Wiley Sons, Ltd. 相似文献
56.
The symplectic, optical, and photon-number tomographic symbols of binomial states of the radiation field are studied. Explicit relations for all tomograms of the binomial states are obtained. Two measures for nonclassical properties of these states are discussed. 相似文献
57.
58.
We apply a method analogous to the eikonal approximation to the Maxwell wave equations in an inhomogeneous anisotropic medium and geodesic motion in a three dimensional Riemannian manifold, using a method which identifies the symplectic structure of the corresponding mechanics, to the five dimensional generalization of Maxwell theory required by the gauge invariance of Stueckelberg's covariant classical and quantum dynamics. In this way, we demonstrate, in the eikonal approximation, the existence of geodesic motion for the flow of mass in a four dimensional pseudo-Riemannian manifold. These results provide a foundation for the geometrical optics of the five dimensional radiation theory and establish a model in which there is mass flow along geodesics. We then discuss the interesting case of relativistic quantum theory in an anisotropic medium as well. In this case the eikonal approximation to the relativistic quantum mechanical current coincides with the geodesic flow governed by the pseudo-Riemannian metric obtained from the eikonal approximation to solutions of the Stueckelberg–Schrödinger equation. The locally symplectic structure which emerges is that of a generally covariant form of Stueckelberg's mechanics on this manifold. 相似文献
59.
Nimrod Moiseyev Romanas Narevich 《International Journal of Theoretical Physics》2003,42(10):2131-2143
Resonances are defined as the poles of the scattering matrix. The poles are associated with the complex eigenvalues of the Hamiltonian which are embedded in the lower half of the complex plane. The asymptotes of the corresponding eigenfunctions are exponentially diverged. Therefore, the resonance eigenfunctions are not embedded in the Hermitian domain of the Hamiltonian. The time asymmetric problem is discussed for these types of non-Hermitian Hamiltonians and several solutions of this problem are proposed. 相似文献
60.
A specific quantum Lax operator, forming a quantum U
q
(sl
n) chain, is suggested. The intertwining R
L
L relation is proved. The invariant local 2+1-dimensional reformulation of the auxiliary linear problem for the L-operator is discussed. 相似文献