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11.
合成丙交酯中微量水分分析 总被引:3,自引:0,他引:3
合成丙交酯中微量水分分析徐溢,柳胜春(重庆大学化工学院分析教研室630044)关键词丙交酯,微量水,定量分析丙交酯是人工合成骨材料聚乳酸的合成中间体,其性能决定着合成产品的品质,要获得高质量的合成材料,对中间体的分析和监测十分重要。一般要求丙交酯中间... 相似文献
12.
本文讨论了29个不对称色酸双偶氮膦酸型显色剂的分子联接性指数,并将其与结构选择性因子相结合,用于偶氮类剂结构与铈显色反应灵敏度的相关性研究,讨论了显色剂结构对显色反应灵敏度的影响。 相似文献
13.
Thermogravimetric analysis is used to determine the amounts of Mg(OH)2 and Mg(CH3COO)2in a mixture thereof. The application and suitability of different analysis methods are discussed. In the first method the
mass losses in the temperature ranges as indicated by the decomposition of the pure compounds were used. Results obtained
using these temperature ranges were unusable. The percentage mass losses due to the decomposition of Mg(OH)2 and Mg(CH3COO)2 were then determined in a second method using the minimum in the derivative mass vs. temperature curves. The results obtained
by this method compared well with the actual values for mixtures containing more than 15% magnesium acetate. The third method
employed the total experimental mass loss of both decomposition reactions. The results obtained using this method compared
well to the actual values, giving a R
2 value of more than 0.99. This method of using the total mass losses can however only be used for binary mixtures that consist
only of magnesium hydroxide and magnesium acetate.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
14.
Theodor H. G. Hehenkamp 《Mikrochimica acta》1992,107(3-6):273-277
In order to optimize the physical properties of HTSC small single crystals grown from a melt for basic studies of their physical properties the influence of the environment on their impurity content was investigated by EPMA. This requires quantitative analysis of all elements being present in the crystals. The accuracy of results was affected by problems with the choice and quality of standards, by contamination but also by malfunction of microprobe electronics. The HTSC materials were found to react with mills, milling balls, crucibles and the atmosphere. These problems are being discussed and some reactions being studied for Y1Ba2Cu3O6+x (0 < x < 1) HTSC in A12O3 and ZrO2 crucibles. The crystals grown contain reproducible amounts of impurities depending on boundary conditions and exhibit a zone structure in composition particularly for Y and Ba within their range of homogeneity. 相似文献
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A direct quantitative method is presented that is based upon the use of multiple headspace solid phase microextraction (HS-SPME) to monitor biogenic volatile organic compounds (BVOCs) released from a living leaf of Pelargonium hortorum in situ. Seventeen BVOCs were detected by GC-MS after a single SPME extraction using a CAR/DVB/PDMS fibre. An internal standard was employed to determine the absolute amounts of seven terpenoid compounds released from a P. hortorum leaf. The quantitative analysis was performed over two days, with extraction preformed for 20 min every 3 h. The amount of volatiles extracted varied with the time of day, with two maxima recorded at 14:00 (day 1) and 17:00 (day 2), corresponding to 236 and 277 ng of the seven terpenoids recorded, respectively. These results indicate that multiple HS-SPME in combination with an internal standard is a simple, quick, and quantitative technique for analysising BVOC emissions from a live plant sample. 相似文献
18.
化学计量学定量分析模型的评价及应用 总被引:3,自引:0,他引:3
本文介绍了评价化学计量学校正技术所建立的定量分析模型定量分析效果的一种实用方法,根据定量分析模型对样品待测组分的计算值x与样品待测组分的标准值y建立简单回归模型:y=a+bx通过检验回归参数a=0,b=1的假设能否在一定概率水平上被接受,评价定量分析模型对样品待测组分的预测效果。 相似文献
19.
As an extension of previous reports, the barium carbonate procedure has been optimized in detail for the preparation of apolar columns. The aim was to produce optimum overall column characteristics, and to maintain them unchanged under the prolonged influence of the highest possible temperature. The main parameters under optimization were glass variety, leaching of glass surface with aqueous HCl, and amount of barium carbonate deposited, while deactivation and coating were kept constant. The basic column characteristics were adsorption properties and thermostability of deactivation, acid/base behaviour and separation efficiency. They were determined by a new, quantitative testing procedure. Intense leaching was able to eliminate almost totally the differences between glass varieties and to create a well-defined glass surface. While untreated glass, leached glass, and barium carbonate treated glass showed specific weak points in the respective column quality, the combination of leaching and barium carbonate treatment yielded the highest and most stable quality. Some technical modifications of the preparation procedure are described, including deactivation in the gas phase, and use of pentane as a solvent for static coating. 相似文献
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