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91.
92.
IntroductionMicellarelectrokineticchromatography (MEKC)wasinventedtoextendtheutilityofcapillaryelectrophoresis(CE)andpermittedtheseparationandanalysisofneutralcompounds .ButjustlikeothermodesofCE ,MEKCarehamperedbythelowconcentrationsensitivityoftheultra … 相似文献
93.
吴镇扬 《东南大学学报(自然科学版)》1995,(Z1)
一些科学工作者对人类以及动物听觉的自由声场至耳膜的传递函数进行了测量,他们发现在宽带信号激励的情况下,不同频率分量之间的幅度差异是与声源的方向有关的,这一发现已被用于展现“真实”的三维听觉,称作虚拟听觉空间仿真。 相似文献
94.
李树勇 《四川师范大学学报(自然科学版)》1998,(1)
运用Razumikhin技巧.对两类具有变时滞的偏泛函微分方程进行了讨论.获得其平凡解一致渐近稳定的充分判别条件. 相似文献
95.
96.
TCP/IP体系结构 总被引:2,自引:0,他引:2
刘永泰 《科技情报开发与经济》1998,8(3):23-24,30
TCP/IP是Internet网络进行信息传输和网络互连所使用的协议,随着Internet的飞速发展,TCP/IP已成为事实上的国际标准和工业标准。本文对TCP/IP的网络体系结构及其协议族作了概述介绍。 相似文献
97.
98.
Underpotential deposition studies of copper on glassy carbon 总被引:1,自引:0,他引:1
Studies on the deposition and dissolution of copper from 0·5 M sulphuric acid solutions onto glassy carbon (GC) using potential
sweep techniques indicated that an additional peak occurs at higher positive potentials than the bulk stripping peak. This
peak is identified as due to the stripping of underpotential deposited (UPD) copper. Results of investigations on the effect
of sweep rate, deposition potential and time of deposition on the peak characteristics of UPD and bulk deposited copper are
also reported. 相似文献
99.
Four new stationary phases for HPLC were prepared by modifying silica gel with a trifrnctional aminoalkyl silane. A conjugated π-electron system was linked to the amino group either directly or with a carboxylic anhydride as a spacer in between. Characterization and dynamic measurements of the new stationary phases were performed by solid state NMR spectroscopy. The results of the 29si and 13C CP/MAS techniques were compared with the recently developed 1H MAS-only technique. Despite strong homonuclear dipole-dipole interactions it was possible to obtain well resolved 1H MAS spectra of those stationaru phases with a high degree of crosslinking. Limited mobility of the aromatic ligand fragments is common for all examined stationaryu phases. The chromatographic properties of the new phases were tested by their ability tio sepatate a mixture of eight PAHS. It could be shown that the π-π interaction mechanism is responsible for the separation of the eight PAHs, because the elution order of the PAHs did not changem despite the use of both a nonpolar mobile phase (n-heptane) and a polar mobile phase (methanol/ water mixture). 相似文献
100.
A new Fe(III)-imprinted amino-functionalized silica gel sorbent was prepared by a surface imprinting technique for selective solid-phase extraction (SPE) of Fe(III) prior to its determination by inductively coupled plasma atomic emission spectrometry (ICP-AES). Compared with non-imprinted polymer particles, the ion-imprinted polymers (IIPs) had higher selectivity and adsorption capacity for Fe(III). The maximum static adsorption capacity of the ion-imprinted and non-imprinted sorbent for Fe(III) was 25.21 and 5.10 mg g−1, respectively. The largest selectivity coefficient of the Fe(III)-imprinted sorbent for Fe(III) in the presence of Cr(III) was over 450. The relatively selective factor (αr) values of Fe(III)/Cr(III) were 49.9 and 42.4, which were greater than 1. The distribution ratio (D) values of Fe(III)-imprinted polymers for Fe(III) were greatly larger than that for Cr(III). The detection limit (3σ) was 0.34 μg L−1. The relative standard deviation of the method was 1.50% for eight replicate determinations. The method was validated by analyzing two certified reference materials (GBW 08301 and GBW 08303), the results obtained is in good agreement with standard values. The developed method was also successfully applied to the determination of trace iron in plants and water samples with satisfactory results. 相似文献