Sensitive chemically amplified electrochemical detection of ruthenium tris-(2,2′-bipyridine) on tin-doped indium oxide electrode

Optimized combination of chemical agents was selected for sensitive electrochemical detection of dissolved ruthenium tris-(2,2′-bipyridine) (Ru-bipy). The detection was based on the chemical amplification mechanism, in which the anodic current of a redox-active analyte was amplified by a sacrificial electron donor in solution. On indium-doped tin oxide (ITO) electrodes, electrochemical reaction of the analyte was reversible, but that of the electron donor was greatly suppressed. Several transition metal complexes, such as ferrocene and tris-(2,2′-bipyridine) complexes of osmium, iron and ruthenium, were evaluated as model analyte. A correlation between the amplified current and the standard potential of the complex was observed, and Ru-bipy generated the largest current. A variety of organic bases, acids and zwitterions were assessed as potential electron donor. Sodium oxalate was found to produce the largest amplification factor. With Ru-bipy as the model analyte and oxalate as the electron donor, the analyte concentration curve was linear up to 50 μM, with a lower detection limit of approximately 50 nM. Preliminary work was presented in which a Ru-bipy derivative was attached to bovine serum albumin and detected electrochemically. Although the combination of Ru-bipy, oxalate and ITO electrode has been used before for electrochemiluminescent detection of Ru-bipy and oxalate, as well as electrochemical detection of oxalate, its utility in amplified voltammetric detection of Ru-bipy as a potential electrochemical label has not been reported previously.     

两个DEA的逆问题的解法的探讨

文[1]提出了两个DEA的逆问题，并用搜索法来解．而本文根据所证的定理，对每个问题一般只要解二、三个线性规划问题就能得到答案．     

用带时序子模块的系统动力学模型预测Brent原油价格

提出在系统动力学模型中加入时序自回归AR(p)子模块，并且自动确定每个AR(p)子模块的阶数p。带时序子模块的系统动力学模型既体现了因素问的横向因果关系，又体现了每个因素的纵向关系。建立欧佩克(OPEC)石油产量、世界GDP、煤炭产量与价格、天然气、需求量、供求差额、消费系数、非欧佩克石油产量、非欧佩克供求差额，石油库存和OPEC组织的期望油价共十一个因素影响下的Brent原油价格预测模型，模型的预测结果表明：在系统动力学模型中加入时序自回归AR(p)子模块的方法是可行的、有效的，并且能提高模型的预测精度。     

基于BP网络的反馈控制器设计

针对常规反馈控制器参数在对象时变情况下难以获得最优的问题，利用BP神经网络构成系统反馈控制器，通过自适应学习速率在线调整网络权值以逼近对象的逆动态模型，并利用Lyapunov方法给出了该算法的收敛的条件。将算法应用于循环水温度控制系统表明：该控制器对模型参数不依赖，能有效地适应控制对象参数的变化，系统具有较强的鲁棒性。     

用DDM实现分布式三维虚拟环境

介绍了HLA中数据分发管理(DDM)的过滤原理;研究分析了目前几种实现DDM过滤机制的方法及其存在的问题,并提出一种简单易行的DDM实现策略,以实现三维虚拟环境的分布式,来提高它的响应速度.     

智能小区网络的系统设计

介绍了智能住宅与智能小区的概念，并针对其特点提出了智能小区网络的设计方案，着重介绍了楼宇自动化网络系统，园区一卡通网络系统。     

N-烯丙基-N''''-(对苯磺酸钠)硫脲的合成及分析应用进展

本文评述了一种新的硫脲试剂N-烯丙基-N'-(对苯磺酸钠)硫脲的合成、性质及其在定性分析、光度分析、电化学分析中的应用进展,展望了今后的研究方向.引用文献20篇.     

数字电视机顶盒综述

在介绍数字电视机项盒的定义、功能及分类的基础上，着重探讨了数字电视机顶盒的软、硬件结构以及该产品的市场前景等问题。     

集成电路设计产业产品创新趋势研究——国际片上系统（SOC）IP核发展现状及对策分析

基于国际集成电路设计产业的分析，系统阐述了国际SOCIP核的发展状况，指出SOC设计将是集成电路设计企业技术创新的发展方向。提出了一些国际SOCIP核发展的对策，包括口核标准化、SOC技术平台开发及加强与Foundry的合作。     

Rigidity and flexibility of virtual polytopes

All 3-dimensional convex polytopes are known to be rigid. Still their Minkowski differences (virtual polytopes) can be flexible with any finite freedom degree. We derive some sufficient rigidity conditions for virtual polytopes and present some examples of flexible ones. For example, Bricard's first and second flexible octahedra can be supplied by the structure of a virtual polytope.