Thiol–norbornene materials: Approaches to develop high Tg thiol–ene polymers

The ability to prepare high T_g low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (T_g) for several thiol–norbornene materials. Results indicate that T_gs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high T_g materials. In particular, as much as a 70 °C increase in T_g was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007     

棉纤维与精梳纱之间性能关系的探讨

为了确定棉纤维性能对精梳纱性能的影响，分别从梳棉前的纤维中和同一纺纱工艺流程的粗纱中选同样９种不同的纤维作为试样进行实验。根据实验数据．得到了纤维性能与纱线性能之间关系的回归方程式，为从纤维直接预测纱线性能提供了一条快速、简捷的方法和途径。     

都匀阶地土的承载特性研究

分析了阶地的形成与土层序列阶地土的判属以及持力层和承载。     

农村土地产权制度与土地综合生产能力的经济学分析

现存农村土地制度存在的主要问题是:土地的产权关系不明晰,土地使用权的不稳定,降低了农民对土地的利用效率;农民进行土地改良的投资十分有限,大大降低了土地综合生产能力.本文从产权经济学的角度分析农村土地产权制度与土地综合生产能力的关系.     

线性系统和迭加原理

以系统的观点给出电路分析中的一个重要定理——迭加定理，并对迭加定理的证明。迭加定理与线性系统的关系．迭加定理的齐次性和可加性，作了较详细的论证。     

修正的Navier—Stokes方程的再生性质和周期解

本文证明了由提出的修正的Navier-Stokes方程在小外力的条件下对t_1∈(0,T]存在唯一的初始速度分布使得相应的初边值问题的广义解具再生性质:(t_1)=(0)=.从而当外力还是时间t的周期函数时,是周期解.进而证明此周期解以指数方式吸引相应于同一外力但初值可任意的其它解.上述结论的证明基于对广义解v的导数v在空间L~∞(0,T;L~2(Ω))中估计.     

城市房屋拆迁中产权问题的思考

本文针对目前我国城市房屋拆迁问题，通过对城市房屋拆迁过程涉及的权利内容进行了总结，并在此基础上，着重分析了城市房屋拆迁过程中权利保护的有关问题，提出了在城市房屋拆迁过程中，房屋产权要高于拆迁权的思想基础，期望通过本文分析达到抛砖引玉的作用，为今后加强对城市房屋拆迁管理，进一步完善我国城市房屋拆迁制度提供一个更为深入的研究路线。     

关于高等教育产业化若干争议的辨析

高等教育产业化问题引起了较大的争议。对争议中的高等教育市场化、．企业化的若干问题，作了针对性的辨析。     

Effect of reaction conditions on the molecular weight and polydispersity of linear poly(arylene ether phosphine oxide)s prepared from an AB monomer

A thorough study of the polymerization behavior of 4‐fluoro‐4′‐hydroxytriphenyl‐phosphine oxide, 2 , under nucleophilic aromatic substitution reactions has been carried out. The synthesis of 2 was achieved in excellent yields by the reaction of bis(4‐fluorophenyl)phenylphosphine oxide, 1 , with one equivalent of potassium hydroxide in DMSO/water. The structure and purity of 2 were confirmed via ¹H, ¹³C, and ³¹P NMR spectroscopy along with elemental analysis. Polymerization reactions of 2 in NMP or DMSO at 180 °C provided the corresponding linear poly(arylene ether phosphine oxide)s, PAEPOs, with number average molecular weights, M_n, ranging from 11,700 to 36,500 Da. All of the polymer samples were completely soluble in chloroform, tetrahydrofuran, DMSO, NMP, and DMAc. The polymerization reactions were accompanied by a competing intramolecular process that resulted in the formation of cyclic oligomeric species that were removed via a final precipitation from methanol. Analysis using ³¹P NMR spectroscopy and size exclusion chromatography (SEC) confirmed that the majority of the lower molecular weight cyclic species were removed via this process. The polymer samples formed tough films when chloroform solutions were slowly evaporated on a glass slide. The PAEPO samples prepared in this study exhibited excellent thermal stability with T_d (5%) values between 503 and 542 in air while the glass transition temperatures ranged from 223 to 237 °C. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2099–2106, 2006     

Preparation and properties of isobutylene–isoprene rubber–clay nanocomposites

Isobutylene isoprene rubber (IIR)‐clay nanocomposites have been prepared successfully by melt intercalation with maleic anhydride‐grafted IIR (Ma‐g‐IIR) and organophilic clay. In IIR‐clay nanocomposites, the silicate layers of the clay were exfoliated and dispersed into the monolayer. The nanocomposites exhibited greater gas barrier properties compared with those of Ma‐g‐IIR. When 15 phr clay was added, gas barrier properties were 2.5 times greater than those of Ma‐g‐IIR. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1182–1188, 2006