A highly distorted hexacoordinated silver(I) complex: synthesis,crystal structure,and DFT studies

A new highly distorted hexacoordinated silver(I) complex [AgL₂NO₃] with 2-(bis(methylthio)methylene)-1-phenylbutane-1,3-dione (L) as ligand is synthesized and characterized using elemental analysis, FTIR, NMR, and X-ray single-crystal structure analysis. The ligand (L) and the nitrate group act as bidentate ligands. The geometry around the silver ion has an intermediate configuration between a trigonal prism (TP) and an octahedron (OCT). Continuous shape measure (CShM) analysis indicated a closer configuration to TP than OCT. Experimentally and theoretically, the Ag–S bonds are shorter than any of the Ag–O bonds, indicating a stronger interaction between Ag⁺ (soft metal) and S-atom as a softer site than oxygen. Natural bond orbital (NBO) analyses showed higher interaction energies between the S-atom lone pairs and the Ag–antibonding NBO (8.61–31.39 kcal/mol) than LP(O)→Ag (3.48–11.46 kcal/mol). The acceptor antibonding NBO of the Ag atom has mainly s-orbital character. The Ag atom has a natural charge of +0.7579 e at the experimental structure, suggesting that negative charge was transferred from the ligand (0.0666 e) and nitrate (0.1090 e) to the Ag ion. Using Hirshfeld surface analysis, the important intermolecular interactions between molecular units within the crystal lattice of the ligand and its Ag-complex were analyzed and compared.     

菲涅耳双棱镜干涉实验中虚光源位置的讨论

讨论了菲涅耳双棱镜实验中虚光源的位置,计算了两虚光源间的距离,并进行了实验测量,理论分析与实验相一致.     

矢量分析在反射和折射中的应用

利用反射定律和折射定律的矢量公式计算出平面转镜和道威棱镜的转像规律.     

采用双石英棱镜对的掺钛蓝宝石自锁模激光器

给出了双棱镜对二、三阶色散的解析式。报道了采用双石英棱镜对的掺钛蓝宝石自锁模激光器的实验结果，获得与理论分析一致的结论。     

三轴稳像棱镜组的三种运动方式

三轴稳像棱镜组是具有三自由度全视场稳定作用,同时还可起扫描、正像作用的多功能棱镜组。本文对该棱镜组的三种运动方式进行了讨论,并运用反射棱镜的基本稳像原理,推导出了三种运动方式的稳像公式和稳像工作公式。     

光学补偿LD侧向非均匀泵浦全固化激光器

采用定向棱镜谐振腔、半圆柱面LD阵列交错侧向泵浦两根串接NdYAG激光棒、热传导冷却结构,研制出了一台工程实用的全固化激光器.定向棱镜腔内振荡光线平行于光轴的对称位置交换穿行,匀化了增益,降低了模序数;同时,定向棱镜准相位共轭特性和自准直作用在一定程度上修正波前畸变、热光楔以及热致双折射,保证了大的动态范围内热稳定性,改善了光束质量.激光器采用Cr4+YAG被动调Q,在室温条件下,工作电流为53 A、频率10 Hz时,1.06 μm单脉冲激光能量高于150 mJ、脉宽9 ns、输出稳定度±3%、束散度2.5 mrad且光轴指向稳定,远场分布近似相干平顶高斯光束.     

单层介质膜保偏全反射直角三棱镜镀膜材料的选择及其微分相位特性研究

入射角、基底玻璃折射率、膜介质折射率、膜厚等因素会影响单层介质膜保偏全反射直角三棱镜的保偏特性，且各因素的影响程度并不相同。本文分析了上述各因素的微小变化对保偏特性的影响，并提出了选择膜介质的方法     

旋转光楔多重全息术

本文提出一种新颖的多重全息术,它是利用旋转光楔调制平面参考波的传播方向,实现编码参考光记录获得多重全息图.该全息图经球面波再现,获得位于同一平面内的再现多重象.文中给出了这种方法的理论分析和实验结果,两者是吻合的.     

Variable Wavelengths Fiber Bragg Gratings Written with A Phase Mask and Four Prisms

Using only one diffractive element, the Talbot interferometer provides a robust and inherently stable method for reproducing fiber Bragg gratings with variable wavelengths, and reduces the complexity of the fiber grating fabrication system. However, the usable length of the grating is limited by the practical length of the mirrors. This paper presents a phase mask with two fixed prisms and two rotational prisms to inscribe fiber Bragg gratings with variable Bragg wavelengths. In this system, the fiber Bragg grating is inscribed by UV interference stripes of 193 nm derived from two rotational prisms and two fixed prisms, where phase mask is used as a beam splitter of ±1 order diffraction light. It is noteworthy that the tunable phase mask interferometer decreases the demand of the length of prism evidently.     

双重网络嵌入对公司IPO后市场表现的影响研究

将社会网络嵌入理论从单一网络拓展至双重网络,分析上市公司同时嵌入风险投资网络和承销商网络对公司IPO上市后市场表现的影响。利用2004～2017年有风险投资支持的IPO公司数据,实证检验结果表明：(1)单独嵌入风险投资网络中心位置、单独嵌入承销商网络中心位置,均会提高公司IPO后市场表现;(2)同时嵌入风险投资网络中心位置和承销商网络中心位置,对公司IPO后短期市场表现的正向影响会相互替代;(3)同时嵌入风险投资网络中心位置和承销商网络中心位置,对公司IPO后长期市场表现的正向影响会互相补充。