Determination of dispersive and nondispersive components of the surface free energy of glass fibers

The dispersive component _s ^d of the surface free energy of glass fibers and its interaction energy with alkanes, benzene, 1-nitropropane, ethyleneglycol, glycerol, formamide, and water were quantitatively determined by the tensiometric method within two liquids. The values of nondispersive interaction energy I _SL ^p were found to be a linear function of the square root of the nondispersive component of the surface free energy of liquids. This suggests that the nondispersive interaction energy may be represented by the geometric mean of the nondispersive component of the surface free energy of a solid and a liquid. The slope gave the nondispersive component _s ^p of the surface free energy. The _s ^p values are 33 and 14 mJ/m² for the untreated and aminosilane-treated fibers, respectively, suggesting that organophilic character has developed on the surface after aminosilane treatment. The _s ^p value was almost similar after the treatment, probably because of the polar characteristics of amino groups.     

A sequence and structural study of transmembrane helices

A comparison is made between the distribution of residue preferences, three dimensional nearest neighbour contacts, preferred rotamers, helix-helix crossover angles and peptide bond angles in three sets of proteins: a non-redundant set of accurately determined globular protein structures, a set of four-helix bundle structures and a set of membrane protein structures. Residue preferences for the latter two sets may reflect overall helix stabilising propensities but may also highlight differences arising out of the contrasting nature of the solvent environments in these two cases. The results bear out the expectation that there may be differences between residue type preferences in membrane proteins and in water soluble globular proteins. For example, the -branched residue types valine and isoleucine are considerably more frequently encountered in membrane helices. Likewise, glycine and proline, residue types normally associated with `helix-breaking' propensity are found to be relatively more common in membrane helices. Three dimensional nearest neighbour contacts along the helix, preferred rotamers, and peptide bond angles are very similar in the three sets of proteins as far as can be ascertained within the limits of the relatively low resolution of the membrane proteins dataset. Crossing angles for helices in the membrane protein set resemble the four helix bundle set more than the general non-redundant set, but in contrast to both sets they have smaller crossing angles consistent with the dual requirements for the helices to form a compact structure while having to span the membrane. In addition to the pairwise packing of helices we investigate their global packing and consider the question of helix supercoiling in helix bundle proteins.     

Theoretical study on the structure and property relationship of the cationic conjugated polyelectrolytes

A theoretical study using density functional theory was performed to understand the structure/property relationship of the cationic conjugated polyelectrolytes, poly[9,9-bis-(6′-N,N,N-trimethylammonium) hexyl] fluorene-alt-4,7-(2,1,3-benzothiadiazole)] (PFBT-X, where X = Br). The torsion angle between the fluorene and benzothiadiazole units in the PFBT monomer was found to substantially affect the structural and electronic properties of the cationic PFBT monomer. The changes of geometrical parameter, HOMO and LUMO energy levels, and band gap, as well as the absorption maximum are discussed in terms of the torsion in the PFBT monomer structure. For comparison, its neutral analogue, the monomer of poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) (F8BT) was also studied. The length of conjugation backbone was also examined.     

苯、甲苯、一氯代苯对含水卵磷脂液晶结构影响的SAXS研究

苯及其衍生物甲苯,一氯代苯都是重要的有机试剂和化工原料,也是对人体有害的有机物。为了了解这些有机试剂对处于生物液晶态的生物膜毒害的机理,我们以含水卵磷脂组成的液晶体系作为人工模型用小角X射线散射(SAXS)方法探讨这些有机试剂对它们结构的影响。关于苯或其它非极性有机介质与含水卵磷脂形成液晶体系及其结构模型前人有一些报导。     

计算旋转螺旋面三维边界层的一种积分方法

本文将计算二维层流边界层的Thwaites方法和计算二维湍流边界层的Truckenbrodt方法推广,用以求解旋转系统的“准三维”边界层方程,得到了计算旋转螺旋面上三维边界层的一种可迭代求解的积分方法.应用此方法进行了两例计算.计算结果与理论精确解或实验测量的对比表明,本文方法是有效的.     

Upper bound of Kähler angles on the β-symplectic critical surfaces

Let (M,g) be a Kähler surface and \mathrm{\Sigma } be a \beta-symplectic critical surface in M. If L_q\left(\mathrm{\Sigma }\right) is bounded for some q>3, then we give a uniform upper bound for the Kähler angle on \mathrm{\Sigma }. This bound only depends on M,q,\beta and the L_q functional of \mathrm{\Sigma }. For q>4, this estimate is known and we extend the scope of q.     

凸轮实测中角度基准偏移误差的消除方法

引起凸轮测量误差的主要原因之一是实测时的角度基准与理论设计时的角度基准不一致,本文利用凸轮的一次离散实测数据,采用分段抛物线拟合函数,以角度搜索法插值得到不同角度基准下的多组测量数据．从各组测量数据与设计数据的各个最大偏差值中,找到最小值,它所对应的角度基准即为该凸轮的准确的角度基准．通过编程并在实测凸轮中验证了此方法的可靠性．     

线阵CCD在折射率测量中的应用

提出利用线阵CCD传感器作为反射光或折射光的光强分布接收装置的折射率测量方法,研究了如何根据光强的空间分布曲线确定布儒斯特角或临界全反射角的定标方案,讨论了测量结果可能达到的精确度。     

投影角与两直线空间夹角关系的判定定理

空间两直线所成的角度,投影时并非不变量,其投影角可大于、小于或等于其空间夹角．本文通过空间分析和解析计算推证出构成空间角度的两直线当中有一条直线与投影面平行时,其投影角的判定定理组．     

Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization

Block copolymers based on poly(pentafluorostyrene), PFS, in various numbers and of different lengths, and polystyrene are prepared by atom transfer radical polymerization (ATRP). Di- and triblock copolymers with varying amounts of PFS were synthesized employing either 1-phenylethylbromide or 1,4-dibromoxylene as initiators for ATRP. Diverse bromo(ester) (macro)initiators were also devised and involved in the formulation of fluorinated pentablock as well as amphiphilic triblock copolymers with a central polyether segment. Amphiphilic star-shaped fluoropolymers, hydrophobic fluorinated nanoparticles, or segmented fluorinated star-shaped block copolymers are further designed by use of different multifunctional initiators. The composition of the novel materials with PFS is determined by combination of SEC and ¹H NMR. Glass transition temperatures and thermal stabilities of the hydrophobic star-shaped PFSs on a six arm dipentaerythritol core are investigated in a wide range of molecular masses and further discussed.