Ein Beitrag über Ba3Pt4HgO11: Das erste Erdkalimetall-Oxoplatinat(II,V)/Oxomercurat

A Contribution on Ba₃Pt₄HgO₁₁: The First Alkaline-Earth Oxoplatinate(II,V)/Oxomercurate Single crystals of Ba₃Pt₄HgO₁₁ were prepared by oxygen high pressure technique (4 200–3 600 bar) and investigated by X-ray methods. It crystallizes with hexagonal symmetry, space group D? P6 2c, a = 6.021, c = 17.374 Å, Z = 2. Ba₃Pt₄HgO₁₁ represents a new structure type, showing structural relationships to Ba₂Hg₃Pd₇O₁₄ and to the precious metal 6L-perovskites. The Hg²⁺ ions show dumb-bell like coordination, Pt²⁺ a square-planar surrounding and Pt⁵⁺ face shared double octahedra.     

CdHgO2: Ein Oxomercurat mit Verwandtschaft zur Crednerit-Struktur

CdHgO₂: An Oxomercurate related to the Crednerite Structure Single crystals of CdHgO₂ were prepared by oxygen high pressure technique (600°C, 3900 bar) and investigated by X-ray technique. It crystallizes with monoclinic symmetry, space group C–C2/m; a = 5.933, b = 3.452, c = 5.875 Å, β = 91.26°; Z = 2. The Hg²⁺ ions show dumb-bell like coordination, Cd²⁺ an octahedral one. CdHgO₂ shows strong relationship to the Crednerite structure. The orientation of the O? Hg? O dump-bells to the CdO₆ octahedra layers is discussed with respect to related oxomercurates.     

等离子体窗密封性能实验研究

等离子体窗具有高真空密封性和良好的束流通过性,在电子束焊接、加速器等领域有很大的应用前景. 针对传统等离子体窗应用孔径小的问题,本文在优化的三阴极源基础上研究了通道直径为7 mm和8 mm等离子体窗的密封特性,以及Ar、He、H2三种等离子窗压降系数随输入电流和气流量的变化关系. 结果显示,在输入电流120~210 A、气流量1000~5000 sccm范围内,Ar等离子体窗的压降系数随输入电流、气流量的增加呈先上升后下降的变化趋势,He、H2等离子体窗的压降系数随输入电流的增加逐渐上升,但随着气流量的增加,He等离子体窗的压降系数先上升后下降,H2等离子体窗的压降系数逐渐下降. 本实验获得的等离子体窗最大压降系数为2550,可隔绝的最大高压为1 atm,与已报道文献相比具备较好的竞争优势,展现了良好的密封性,在未来加速器等领域有很大的应用潜力.     

Stability of the Sarcin/Ricin domain of 28S RNA in rat ribosome under hydrostatic pressure

Under 2 100 bar of hydrostatic pressure, KNA N-glycosidase can still cleave the N-C bond of adenosine at position 4324 in R/S domain of 28S RNA in rat ribosome, demonstrating that high pressure has no effect on the tertiary structure of S/R domain.     

双剪强度理论在水工压力隧洞弹塑性应力分析中的应用

水工压力隧洞的弹塑性分析,工程上一直采用Ｍｏｈｒ－Ｃｏｕｌｏｍｂ强度准则进行求解。但由于该理论和试验结果常常不符,故产生误差。本文应用俞茂宏教授提出的双剪强度理论对水工压力隧洞进行弹塑性分析,解决了上述问题。     

影响油气运移的应力场地温场渗流场耦合的双重介质模型

地应力场、地温场和渗流场是影响油气运移的主要因素。以此为基础,研究了含油气盆地双重介质体系内流体与岩体相互的力学作用关系,提出了双重介质体系内渗流场、岩体地应力场和地温场耦合的非线性动力学模型。     

间歇式压滤机的优化研究

在计入洗涤时间这一重要因素的前提下,以间歇式压滤机的生产能力最大为优化目标函数,得出其最佳操作时间,经实例验证,优化效益显著．     

压电陶瓷—明胶复合材料的功能效应与实验分析

分析了锆钛酸铝压电陶瓷－明胶复合材料中的功能效应,并对该功能效应的整个响应过程进行了研究,研究结果表明,在压电陶瓷－明胶复合材料中,明胶渗透压的改变是影响压电陶瓷电信号输出发生变化的主要因素,通过乘积效应原理的应用,对复合材料随外界条件的改变而产生的电信号的输出进行了实验研究和理论推导,分析结果与实验符合较好。     

埋藏式钢管的抗外压稳定研究

应用壳体稳定理论结合某一工程实例研究了圆形加劲环式钢管和锚筋式钢管的抗外压稳定问题。首先分析了非对称外压对失稳荷载的影响;其次根据壳体稳定分析结果对锚筋式和加劲环式钢管的失稳形态和影响因素进行了分析,并对现有计算公式进行了评述。结果表明,对锚筋式和加筋环式钢管采用本文提出的按壳体稳定理论建立的有限元计算公式是可靠合理的。     

A predictive model for impact response of viscoelastic polymers in drop tests

We show for the first time that a classical Hookean viscoelastic constitutive law for rubbery materials can predict the impact forces and deflections measured with a commercial drop tester when a mass, or tup with a flat impacting surface is dropped onto a flat pad of commercial impact-absorbing rubber. The viscoelastic properties of the rubber, namely the relaxation times and strengths, are obtained by a standard rheological linear-oscillatory test, and the equation of momentum transfer is then solved, using these measured parameters, assuming a uniaxial deflection of the pad during the impact. Good agreement between measured and predicted forces and deflections is obtained for a series of various drop heights, tup masses, impact areas, and pad thicknesses, as long as the deflection of the pad relative to its thickness is small or modest (<50% or so), and as long as the area of the pad is less than or equal to that of the tup. When the pad area is greater than the tup, forces are higher than predicted, unless an empirical factor is introduced to account for the nonuniaxial stretching of the ring of material that extends outside of the impact area. These results imply that the impact-absorbing properties of a rubbery polymeric material can be assessed by simply examining the material's linear viscoelastic spectrum.