全文获取类型
收费全文 | 12921篇 |
免费 | 1333篇 |
国内免费 | 660篇 |
专业分类
化学 | 2448篇 |
晶体学 | 84篇 |
力学 | 1467篇 |
综合类 | 53篇 |
数学 | 239篇 |
物理学 | 3737篇 |
综合类 | 6886篇 |
出版年
2024年 | 38篇 |
2023年 | 119篇 |
2022年 | 240篇 |
2021年 | 260篇 |
2020年 | 308篇 |
2019年 | 290篇 |
2018年 | 240篇 |
2017年 | 378篇 |
2016年 | 416篇 |
2015年 | 536篇 |
2014年 | 634篇 |
2013年 | 1238篇 |
2012年 | 737篇 |
2011年 | 784篇 |
2010年 | 558篇 |
2009年 | 616篇 |
2008年 | 574篇 |
2007年 | 732篇 |
2006年 | 643篇 |
2005年 | 607篇 |
2004年 | 588篇 |
2003年 | 501篇 |
2002年 | 449篇 |
2001年 | 424篇 |
2000年 | 329篇 |
1999年 | 342篇 |
1998年 | 306篇 |
1997年 | 249篇 |
1996年 | 209篇 |
1995年 | 239篇 |
1994年 | 194篇 |
1993年 | 207篇 |
1992年 | 158篇 |
1991年 | 127篇 |
1990年 | 129篇 |
1989年 | 121篇 |
1988年 | 132篇 |
1987年 | 66篇 |
1986年 | 52篇 |
1985年 | 32篇 |
1984年 | 23篇 |
1983年 | 4篇 |
1982年 | 16篇 |
1981年 | 18篇 |
1980年 | 5篇 |
1979年 | 17篇 |
1976年 | 4篇 |
1973年 | 4篇 |
1972年 | 5篇 |
1955年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
992.
Analysis of 11 polybrominated diphenyl ethers (PBDEs), tetrabromobisphenol A bis 2,3-dibromopropylether (TBBPA-bis), tetrachlorobisphenol A (TCBPA), tetrabromobisphenol A (TBBPA) and hexabromocyclododecanes (HBCDs) was optimized by ultrahigh pressure liquid chromatography/tandem mass spectrometry (UPLC–MS/MS) operating in negative ion (NI) mode. Electrospray ionization (ESI), atmospheric pressure photoionization (APPI) and atmospheric pressure chemical ionization (APCI) sources were tested and for PBDEs APCI gave higher sensitivity than APPI while for TBBPA-bis APCI and APPI showed similar performance. ESI was the best option for TCBPA, TBBPA and HBCDs. Detection limits were between 20 and 59 fg for the compounds analyzed by ESI, 0.10 and 0.72 pg for PBDEs and 6 pg for TBBPA-bis. The matrix effect of sewage sludge extract was also tested showing negligible ion suppression for APCI and an increase of the background level of all investigated pollutants leading to a worsening of the limits of quantification by a factor between 1.2 and 3.3. The UPLC-APCI/MS/MS method for PBDEs, after pressurized liquid extraction (PLE), was validated by comparison with the concentration values from the NIST 1944 standard reference material. The advantages of the methods include low detection limits, PBDE congeners specificity using selected multiple reaction monitoring (MRM) transitions, and the absence of thermal degradation of higher PBDE congeners, especially BDE-209. The methods were applied for the determination of the above reported flame retardants in sewage sludge in order to get more information about the degradation on PBDEs (in particular BDE-209) during municipal wastewater treatments. 相似文献
993.
页岩气双二维水平井极限延伸能力研究 总被引:1,自引:1,他引:0
页岩气藏的开发多采用水平井,水平段的延伸能力直接影响到页岩气藏的综合开发效益。双二维水平井具有施工难度小、邻井碰撞风险低、作业费用低等优点。根据长宁页岩气的钻井实际情况,分析了钻机承载能力、钻柱安全系数、地层承压能力及额定泵压等因素对水平井延伸能力的影响,推导了相应计算模型。以长宁已钻页岩气井为基础,计算了不同影响因素随水平段长度的变化。研究表明,双二维水平井的延伸能力主要受地层承压能力和额定泵压影响,钻井施工中应选择合理的钻井液密度和排量,降低水平段岩屑床高度,采取适当的堵漏措施,选择高额定泵压的钻井泵。 相似文献
994.
采用固态高温烧结反应方法,成功合成出了陨硅镍铁石样品(Fe0.03Ni0.97)8(Si0.79P0.21)3。X射线衍射结果表明,合成样品的结构为R3'c,对应的晶胞参数为a=b=0.663 8(1) nm,c=3.789 2(2) nm,V=1.446 15(6) nm3。在室温下,对样品进行原位高压X射线衍射研究,实验最高压力达到21.3 GPa,随着压力的升高,晶胞体积逐渐减小,但并没有观察到结构相变。利用Birch-Murnaghan状态方程对体积与压力的关系进行拟合,获得常温常压下的体积V0=1.441 4(24) nm3,体积模量K0=220(7) GPa。晶轴与压力的关系利用Murnaghan状态方程拟合,获得a轴和c轴的模量分别为Ka=257(9)和Kc=165(4),c轴较a轴容易压缩。 相似文献
995.
利用分离式霍普金森压杆(Split Hopkinson Pressure Bar,SHPB)技术,研究了土体在不同应变率条件下的冲击动态力学性能,发现土体有明显的应变率效应,与静载相比,冲击载荷下土的动强度和动模量均有很大的提高。根据实验曲线的特征,以一根线性弹簧和两个不同松弛时间的Maxwell体并联的粘弹性模型来表达土体的损伤型粘弹性本构模型,两个Maxwell体分别表示土体的低应变率响应和高应变率响应,模型的数值拟合曲线与实测动态本构曲线具有较好的一致性。拟合参数表明,土体对低应变率的响应与混凝土相同,对高应变率的敏感性远远高于混凝土。 相似文献
996.
利用积分球绝对测量法,对在20 Pa真空缺氧、1 000 Pa空气,105 Pa空气及1 000 Pa氧气环境下,1 064 nm波长连续激光辐照30CrMnSiA碳钢材料过程中的反射光信号进行了测量,得到了30CrMnSiA碳钢在4种辐照环境下的反射率和温度变化曲线。结果表明:在空气组分辐照环境的低压到105 Pa范围内,材料初始反射率随压力增大而增大;在缺氧和富氧环境的激光辐照过程中,缺氧环境下材料反射率变化缓慢,且变化拐点温度高于富氧环境,富氧环境下材料被加热后的快速氧化反应有利于材料对激光能量的吸收;不同辐照环境(缺氧和富氧)相同材料温度条件下,材料反射率并不相同。 相似文献
997.
针对传统坐姿识别系统中传感器数量多和系统较复杂导致成本过高等问题,设计一种基于少量体压传感器和支持向量机(SVM)算法的坐姿识别方法.首先,设计一种由少量薄膜压力传感器构成的体压传感阵列,将其置于坐垫内部;然后,利用该传感阵列采集不同坐姿的体压数据,并绘制相应的体压分布等高线图;最后,以体压数据作为特征向量,结合支持向量机算法建模,以实现坐姿分类自动识别.测试结果表明:少量体压传感器也能获取不同坐姿的体压分布特征;SVM坐姿分类模型在熟悉样本下的坐姿识别准确率达98.3%,在陌生样本下的坐姿识别准确率达92.5%. 相似文献
998.
Growth of gem-grade nitrogen-doped diamond crystals heavily doped with the addition of Ba(N3)2
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Additive Ba(N 3) 2 as a source of nitrogen is heavily doped into the graphite-Fe-based alloy system to grow nitrogendoped diamond crystals under a relatively high pressure (about 6.0 GPa) by employing the temperature gradient method.Gem-grade diamond crystal with a size of around 5 mm and a nitrogen concentration of about 1173 ppm is successfully synthesised for the first time under high pressure and high temperature in a China-type cubic anvil highpressure apparatus.The growth habit of diamond crystal under the environment with high degree of nitrogen doping is investigated.It is found that the morphologies of heavily nitrogen-doped diamond crystals are all of octahedral shape dominated by {111} facets.The effects of temperature and duration on nitrogen concentration and form are explored by infrared absorption spectra.The results indicate that nitrogen impurity is present in diamond predominantly in the dispersed form accompanied by aggregated form,and the aggregated nitrogen concentration in diamond increases with temperature and duration.In addition,it is indicated that nitrogen donors are more easily incorporated into growing crystals at higher temperature.Strains in nitrogen-doped diamond crystal are characterized by micro-Raman spectroscopy.Measurement results demonstrate that the undoped diamond crystals exhibit the compressive stress,whereas diamond crystals heavily doped with the addition of Ba(N 3) 2 display the tensile stress. 相似文献
999.
BC5 is a newly synthesized superhard material. We present a systematic investigation of optical properties of BC5 in P3m1 and I-4m2 phases at ambient and high pressure in the framework of density functional theory with the generalized gradient approximation (GGA) in this paper. Optical properties such as dielectric function, refractive index, absorption, reflectivity and electron energy-loss spectrum are obtained successfully. The feature in the spectra of the optical parameters is discussed. Through calculation, we find BC5 is optically anisotropic. Moreover, the dielectric function exhibits a large change at 70 GPa pressure for P3m1 BC5 phase, but I-4m2 phase not, indicating the stable electronic structure that the I-4m2 phase possesses. 相似文献
1000.
E. TangarifeC.A. Duque 《Physica B: Condensed Matter》2011,406(4):952-956
This work is concerned with the theoretical study of the combined effects of applied electric field and hydrostatic pressure on the binding energy and impurity polarizability of a donor impurity in laterally coupled double InAs/GaAs quantum-well wires. Calculations have been made in the effective mass and parabolic band approximations and using a variational method. The results are reported for different configurations of wire and barriers widths, impurity position, and electric field and hydrostatic pressure strengths. Our results show that for symmetrical structures the binding energy is an even function of the impurity position along the growth direction of the structure. Also, we found that for hydrostatic pressure strength up to 38 kbar, the binding energy increases linearly with hydrostatic pressure, while for larger values of hydrostatic pressure the binding energy has a non-linear behavior. Finally, we found that the hydrostatic pressure can increase the coupling between the two parallel quantum-well wires. 相似文献