20世纪90年代末东亚夏季降水年代际变化及其成因初探

基于1983—2011年月总降水量、环流和海温的再分析资料,给出了20世纪90年代末东亚夏季降水的年代际调整的区域特征,及其对应的大气环流内部过程和可能的海温外强迫的年代际变化.研究结果表明,在20世纪90年代末期东亚北部夏季降水比东亚南部夏季降水由湿向干的表现更为明显,东亚南部地区夏季降水则是在20世纪90年代初和21世纪初发生年代际的转折.此外,东亚地区夏季的500 h Pa高度场、850 h Pa风场、U200风场、水汽输送场和东亚太平洋遥相关型指数和东亚夏季风指数等在20世纪90年代末期也表现出明显的年代际变化特征.进而从大气内部过程的角度验证了20世纪90年代末东亚夏季降水发生的年代际调整.与此同时,北太平洋和西太平洋海表温度表现出由偏低向偏高的转变,这可能是导致20世纪90年代末期东亚夏季气候年代际变化的重要外部成因之一.     

点缺陷对硼掺杂直拉硅单晶p/p~+外延片中铜沉淀的影响

系统研究了点缺陷对晶体硅中氧沉淀生成的影响,及点缺陷和氧沉淀对重掺硼直拉硅单晶p/p⁺外延片中铜沉淀的影响.样品先在不同的气氛下进行1250℃/60 s快速热处理,随后在750℃/8 h+1050℃/16 h常规热处理过程中引入铜沾污.通过腐蚀结合光学显微镜研究发现,以O₂作为保护气氛时,p⁺衬底中的沉淀密度较小,以Ar和N₂作为保护气氛时,重掺硼p⁺衬底中生成了高密度的沉淀,且在上述所有样品的外延层中均无缺陷生成.研究认为,以O₂作为保护气时引入的自间隙硅原子（Si_I）可以抑制沉淀的形成,而以Ar和N₂作为保护气氛时引入的空位则会促进沉淀的生成,这是导致此差异的主要原因.另外,研究还发现,p/p⁺外延结构能很好地吸除硅片中的铜杂质,从而保持了外延层的洁净.     

Forecasting of precipitation occurrence in long-range trajectory climatology

Summary A procedure to include a way for forecasting the precipitation occurrence in the air mass trajectory computation for climatological studies in order to compute the wet deposition of airborne pollutants is presented. It is based on a technique proposed by Moscoet al., Riv. Meteorol. Aeronaut.,33, 229 (1973). Its performance is tested comparing the forescen occurrence of either precipitation or no precipitationversus the actual one for two stations, Parma and Vipiteno, for a period of four years. In more than 80% of the cases the forecasting was correct.     

A probability distribution for precipitation data analysis

Hydrologic design is often based on assessments of large return interval measures; it is vital to be able to conclude them as precisely as possible. Henceforth, the selection of a probability distribution is very crucial for such cases. In view of this scenario, we propose and study a pliant probability distribution for precipitation data analysis. Some mathematical and statistical properties are analyzed. In order to make stronger predictions and judge the realistic return period, we have also characterized the model via Laplace transformation. We have estimated its parameters via the maximum likelihood estimation and constructed its information matrix for developing the confidence belt of population parameters. Moreover, a real-life setup is also considered by applying the model over precipitation data of diverse regions, including Jacksonville, Florida (USA), Barkhan (Pakistan), British Columbia (Canada), and Alexandria (Egypt). This investigated study is based on various statistical parametric and nonparametric tests, which indicates that the proposed model is one of the better strategies for precipitation data analysis when compared with the famous three-parameter Kappa model.     

Stable isotope composition of the meteoric precipitation in Croatia

The precipitation is the input into the water system. Its stable isotope composition has to be known for the proper use and management of water resources. Croatia is not well represented in the Global Network of Isotopes in Precipitation (GNIP) database, and the geomorphology of the country causes specific local conditions. Therefore, at the Stable Isotope Laboratory (SILab), Rijeka, we monitor the stable isotope composition (δ¹⁸O, δ²H) of precipitation. Since δ¹⁸O and δ²H are well correlated, we concentrate the discussion on the δ¹⁸O distribution. Together with GNIP, our database contains 40 stations in Croatia and in the neighbouring countries. Their different latitudes, longitudes and altitudes give information of great detail, including the influence of the topographic structure on the precipitation in the south-eastern part of Europe, as well as the complex interplay of the different climate conditions in the area. Within a few hundred kilometres, the stable isotope values display a significant change from the maritime character in the south (mean δ¹⁸O around?6 to?8%‰) to the continental behaviour in the north (mean δ¹⁸O around?8 to?11%‰). Depending on the location, the mean δ¹⁸O values vary with altitude at a rate of approximately?0.2%‰/100 m and?0.4%‰/100 m, respectively. Also the deuterium excess has been found to depend on location and altitude. The data are being used to construct a δ¹⁸O map for the entire area.     

Vacancy–solute interactions during ageing of a cold-worked Mg–RE-based alloy

The vacancy–solute interactions during artificial ageing at 250^○C of cold worked samples of a commercial magnesium alloy WE54 (Mg–RE based) were studied by coincidence Doppler broadening of positron annihilation radiation and positron annihilation lifetime spectroscopy. The results show that, in the as-cold-worked state, the vacancies are associated with dislocations that are generated by the cold work and that, after artificial ageing at 250^○C, the vacancies are associated with solute elements and help the formation of precipitate precursors. This mechanism accelerates the formation of hardening precipitates without any apparent changes in the precipitation sequence and in the products of the decomposition of the supersaturated solid solution. The present study demonstrates that the stronger hardening response achieved in the cold-worked samples originates from the presence of a higher concentration of vacancies that is introduced by the cold work and is retained in the first few minutes of ageing.     

Optical studies of samarium-doped fluoride nanoparticles

Samarium-doped calcium fluoride (CaF₂) nanoparticles were synthesized by the co-precipitation method and characterized by powder X-ray diffraction (PXRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), optical absorption and photoluminescence (PL) techniques. The PXRD patterns confirmed the cubic crystallinity of the synthesized nanoparticles. The average particle size estimated using Scherer's formula was ～20?nm. The purity of the synthesized nanoparticles was confirmed by the FTIR spectrum. The morphological features studied using SEM revealed that the nanoparticles were agglomerated and porous. The optical absorption spectrum showed a strong and prominent absorption peak at ～264?nm and a weak one at ～212?nm. The PL spectrum showed broad and prominent emissions with peaks at ～387 and 532?nm along with weak emissions at 573 and 605?nm.     

东天山的一次暴雨洪水中心最大雨量的估算

本文通过对新疆天山东部地区一次罕见的大暴雨洪水的特征分析，应用水箱模型法和最大熵原理等方法推算出本次大暴雨的中心最大雨量和流域面平均降水量．     

不规则格点上的车贝雪夫多项式在长江中下游降水分布预报中的应用

本文将任意不规则格点上的车贝雪夫多项式应用于长江中下游降水分布的预报.这一方法能适应资料分布的复杂变化,因而有更大的实用价值     

反萃沉淀法制备纳米氧化锌及其光催化动力学

以二(2-乙基己基)磷酸(HDEHP)为萃取剂,CCl4为稀释剂,H2C2O4-CH3CH2OH-H2O溶液为反萃沉淀剂,采用反萃沉淀法制备前躯体二水合草酸锌,经450 ℃煅烧制备了纳米级氧化锌粉体,用TEM,SEM,TG,XRD和FT-IR等测试手段对材料进行表征.结果表明:部分氧化锌为六角形的多微孔材料,平均粒径约为32 nm.基于Langmuir模型和Photo-Layer模型对氧化锌降解亚甲基蓝的动力学行为进行研究.结果表明:光催化氧化过程的控制步骤为化学反应动力学控制机制,反应动力学符合拟一级动力学;利用Photo-Layer模型可估算出不同反应条件下光反应层中的·OH浓度.