Analysis of the pungent principles of ginger and grains of paradise by high-performance liquid chromatography using electrochemical detection

Summary The pungent principles of ginger and grains of paradise are examined using a reversed-phase HPLC column. An electrochemical detector is used to selectively detect the phenolic gingerols and shogaols. The retention indices of the compounds are compared using methanowater and acetonitrile-water as eluents.Presented at the 14th International Symposium on Chromatography London, September, 1982     

Chemical reaction dynamics of PeCB and TCDD decomposition: A tight‐binding quantum chemical molecular dynamics study with first‐principles parameterization

The decomposition reaction dynamics of 2,3,4,4′,5‐penta‐chlorinated biphenyl (2,3,4,4′,5‐PeCB), 3,3′,4,4′,5‐penta‐chlorinated biphenyl (3,3′,4,4′,5‐PeCB), and 2,3,7,8‐tetra‐chlorinated dibenzo‐p‐dioxin (2,3,7,8‐TCDD) was clarified for the first time at atomic and electronic levels, using our novel tight‐binding quantum chemical molecular dynamics method with first‐principles parameterization. The calculation speed of our new method is over 5000 times faster than that of the conventional first‐principles molecular dynamics method. We confirmed that the structure, energy, and electronic states of the above molecules calculated by our new method are quantitatively consistent with those by first‐principles calculations. After the confirmation of our methodology, we investigated the decomposition reaction dynamics of the above molecules and the calculated dynamic behaviors indicate that the oxidation of the 2,3,4,4′,5‐PeCB, 3,3′,4,4′,5‐PeCB, and 2,3,7,8‐TCDD proceeds through an epoxide intermediate, which is in good agreement with the previous experimental reports and consistent with our static density functional theory calculations. These results proved that our new tight‐binding quantum chemical molecular dynamics method with first‐principles parameterization is an effective tool to clarify the chemical reaction dynamics at reaction temperatures. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2005     

Comparative analysis of the underground parts ofGentiana species by HPLC with diode-array and mass spectrometric detection

Summary The aim of this work was to compare the chemical composition of the underground parts (roots and rhizomes) ofGentiana cruciata L.,Gentiana pneumonanthe L., andGentiana asclepiadea L.— the three gentians native to Hungary—with that of the widely used stomachicGentiana lutea L., to determine which of the three Hungarian species could be used as a substitute forGentiana lutea in pharmaceutical preparations. The four gentians were compared by means of RPHPLC with diode-array detection (DAD) and electrospray ionization-mass spectrometric detection (ESI-MSD). The quantities of the lead compounds, the secoiridoid-glycosides, in 220 samples of the underground parts of gentians originating from several locations in Hungary, were determined by a more economical RPHPLC-DAD method. The occurrence of the characteristic compounds investigated—bitter principles and xanthones—in the underground parts of the speciesGentiana asclepiadea L. suggest it might be a potential replacement forGentiana lutea L. in pharmaceutical products. Presented at Balaton Symposium '01 on High-Performance Separation Methods, Siófok, Hungary, September 2–4, 2001     

"微机原理"与"汇编语言"两课整合的教学

《微型计算机原理及应用》与《汇编语言程序设计》是计算机应用专业的两门较重要的基础课程,也是教学难度和学习难度较大的两门课程,文章阐述了如何将这两门课程进行整合的教学改革和实践。     

关于完善会计专业判断的思考

专业判断是会计固有的职责,具有不可替创向应是培养会计人员的判断能力,使其熟练掌握会计专业判断的原则和方法,并通过构筑和完善专业判断的支撑环境,实现专业判断的合理化,加快国际化进程.     

跨文化言语交际中的语用策略

跨文化交际系指不同文化背景的人们之间进行的言语或非言语交际行为,它在国际和民族间的交流、交往和合作中起着举足轻重的作用.鉴于文化上的差异,在交际行为中产生语用失误并造成交际障碍和失败的情况时有发生,语用策略的选择势在必行.本文从言语交际的礼貌得体本质、语用策略选择的"面子"理据和语用策略选择的文化属性特征三个方面对跨文化言语交际中的语用策略做出了阐述.     

对我国生态环境保护的思考

论述了我国森林生态、农业生态、草地生态、水生态、矿产资源开发、生物多样性等方 面的生态环境保护的思路,讨论了生态环境保护的基本原则.     

英语词汇教学新探

现代英语词汇教学应遵循五个基本原则，即系统原则，交际原则，化原则，认知原则和情感原则，教师在词汇教学的各个阶段可有效帮助学生习得词汇，最终使学生在获得词汇知识的同时，又获得词汇能力。     

论研究生教育收费的可行性、原则及配套措施

目前，对高层次人才的持续需求为研究生教育收费提供了外在的动力；人们对非义务教育“谁受益，谁出钱”的教育投资观已经有所认识，为研究生教育收费提供了内在的社会思想基础；城乡居民收入的增长为实现研究生教育收费提供了一定的经济基础；可以采取配套措施来消除收费可能给经济困难学生带来的压力，因此，实行研究生教育收费正当其时。但在制定研究生教育收费政策时应坚持扩大宣传和循序渐进、成本多元有限分担、保证国家及社会人才需要、按地域校别专业差别收费、充分考虑到社会承受力、强化监督与权力下放等原则。对研究生教育实行收费的同时，应同时对现行的研究生奖学金、贷学金、困难补助金等相关政策进行配套改革。     

“学校课程”的建构

澄清作为三级课程体制结构中的"学校课程"概念,分析"学校课程"的缘由和要义,参照泰勒提出的课程与指导原理,结合中国课程实际情况,初步梳理学校自主设计课程的思路、程序和相应的教师专业化、课程管理的要求。