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981.
982.
Changes in structure and dielectric properties at elevated temperatures have been investigated on single-crystals of sodium potassium niobate, Na0.5K0.5NbO3, grown by the flux method. Single-crystal X-ray diffraction studies revealed that the crystals underwent orthorhombic-tetragonal and tetragonal-cubic phase transitions at 465 and 671 K during heating and 446 and 666 K during cooling, respectively. Both transitions were accompanied by volumetric discontinuities of collapse upon heating and expansion upon cooling, suggesting that the transitions were of the first order. The coordination numbers of an Nb showed a decreasing tendency with decreasing temperature, i.e., 6 in cubic, 5+1 in tetragonal and 4+2 in orthorhombic. An Na atom occupied a slightly different position from the K atom in 12-fold coordination, resulting in fewer coordination numbers of 8+4 in cubic and tetragonal and 7+5 in orthorhombic. The spontaneous polarisation (Ps) estimated from the atom positions and formal charges were approximately 0.29 C m−2 in orthorhombic and 0.18 C m−2 in tetragonal. The contribution of the alkaline oxide components to Ps was estimated to be approximately 15% in both ferroelectric forms. The temperature-induced transitions were also confirmed through the dielectric constant and dielectric loss at various frequencies and the differential scanning calorimetry. 相似文献
983.
This work answers an unsolved question that consists of determining the least number of water molecules necessary to separate a potassium chloride molecule. The answer based on accurate quantum chemical calculations suggests that tetramers are the smallest clusters necessary to dissociate KCl molecules. The study was made with Møller‐Plesset second‐order perturbation theory modified with the cluster theory having single, double, and perturbative triple excitations. With this extensive study, the dissociation of KCl molecule in different water clusters was evaluated. The calculated results show that four water molecules stabilize a solvent separated K+/Cl? ion‐pair in prismatic structure and with six water molecules further dissociation was observed. Attenuated total reflection infrared spectroscopy of KCl dissolved in water establishes that clusters are made of closely bound ions with a mean of five water molecules per ion‐pair [K+(H2O)5Cl?]. (Max and Chapados, Appl Spectrosc 1999, 53, 1601; Max and Chapados, J Chem Phys 2001, 115, 2664.) The calculated results tend to support that five water molecules leads toward the formation of contact ion‐pair. The structures, energies, and infrared spectra of KCl molecules in different water clusters are also discussed. © 2010 Wiley Periodicals, Inc. J Comput Chem, 2010 相似文献
984.
KOH对超临界水中褐煤连续制氢的影响 总被引:1,自引:0,他引:1
采用连续式超临界水反应装置,以20%的水煤浆为反应原料,考察了不同KOH/煤质量比、温度、压力对褐煤制氢过程的影响。实验结果表明,在水煤浆中添加KOH可以提高碳气化率及H2的体积分数和产率,在600℃、25 MPa、KOH/煤质量比为4.1%时,与未加KOH相比,气相产物收率由29.6%提高到49.5%,碳气化率由23.0%增大到31.5%;H2的产率由135.4 mL/(g daf coal)提高到239.1 mL/(g daf coal)。随着温度的升高,H2产率逐渐增大,650℃时达到287.8 mL/(g daf coal),是500℃时的5.4倍;高温、高压下,KOH对煤气化过程的催化作用更为明显。 相似文献
985.
Xiaojia Huang Ningning QiuDongxing Yuan Qingmei Lin 《Journal of chromatography. A》2010,1217(16):2667-2673
In this study, a novel mixed mode monolithic material was prepared and acted as the SBSE coating. The monolithic material was prepared by in situ copolymerization of methacrylic acid-3-sulfopropyl ester potassium salt (MASE) and divinylbenzene (DB) in the presence of a porogen solvent containing cyclohexanol, 1-dodecanol, and water with azobisisobutyronitrile as initiator. The influences of the contents of the porogen solvent and monomer in the polymerization mixture on the extraction performance were investigated thoroughly. Several characteristic techniques, such as elemental analysis, scanning electron microscopy and infrared spectroscopy were used to characterize the monolithic material. To achieve optimum extraction performance for quinolones, several parameters, including pH value, desorption solvent, ionic strength in sample matrix, extraction and desorption time were investigated. The results show that under the optimized experimental conditions, the method has good sensitivity, linearity, simplicity and low cost. The extraction performance of present method to the target compounds was compared with commercial SBSE which using polydimethylsiloxane as coating and other SBSEs which based on monolithic materials. The comparative results indicate that present SBSE can extract the analytes more effectively than other SBSEs because both ion-exchange and hydrophobic interactions contribute to the extraction of quinolones. 相似文献
986.
在氢氧化钠介质中,芦丁对高碘酸钾氧化偶氮胂Ⅲ褪色反应有明显的催化作用,据此建立了测定芦丁含量的催化动力学光度法.最大吸收波长为590nm,该方法的线性范围为0.03~1.0mg/L.对实验数据进行回归处理的线性方程为ΔΑ=0.4485c(芦丁)+0.0011,相关系数为r=0.9985,检出限为0.0167mg/L.该方法简便,快速,灵敏度高,用于实际样品的测定,结果令人满意. 相似文献
987.
988.
Yun Hwan Kang In Jun Yang Kathleen G. Morgan Heung Mook Shin 《Experimental & molecular medicine》2012,44(12):749-755
Cinnamyl alcohol (CAL) is known as an antipyretic, and a recent study showed its vasodilatory activity without explaining the mechanism. Here we demonstrate the vasodilatory effect and the mechanism of action of CAL in rat thoracic aorta. The change of tension in aortic strips treated with CAL was measured in an organ bath system. In addition, vascular strips or human umbilical vein endothelial cells (HUVECs) were used for biochemical experiments such as Western blot and nitrite and cyclic guanosine monophosphate (cGMP) measurements. CAL attenuated the vasoconstriction of phenylephrine (PE, 1 µM)-precontracted aortic strips in an endothelium-dependent manner. CAL-induced vasorelaxation was inhibited by pretreatment with NG-nitro-L-arginine methyl ester (L-NAME; 10-4 M), methylene blue (MB; 10-5 M) and 1 H-[1,2,4]-oxadiazolole-[4,3-a] quinoxalin-10one, (ODQ; 10-6 or 10-7 M) in the endothelium-intact aortic strips. Atrial natriuretic peptide (ANP; 10-8 or 10-9 M) did not affect the vasodilatory effect of CAL. The phosphorylation of endothelial nitric oxide synthase (eNOS) and generation of nitric oxide (NO) were stimulated by CAL treatment in HUVECs and inhibited by treatment with L-NAME. In addition, cGMP and PKG1 activation in aortic strips treated with CAL were also significantly inhibited by L-NAME. Furthermore, CAL relaxed Rho-kinase activator calpeptin-precontracted aortic strips, and the vasodilatory effect of CAL was inhibited by the ATP-sensitive K+ channel inhibitor glibenclamide (Gli; 10-5 M) and the voltage-dependent K+ channel inhibitor 4-aminopyridine (4-AP; 2 × 10-4 M). These results suggest that CAL induces vasorelaxation by activating K+ channels via the NO-cGMP-PKG pathway and the inhibition of Rho-kinase. 相似文献
989.
1560nm激光经PPLN和PPKTP晶体准相位匹配倍频研究 总被引:2,自引:1,他引:1
将1560nm光栅反馈复合腔半导体激光器产生的连续激光注入掺铒光纤放大器,放大至约5 W,分别采用周期极化铌酸锂(PPLN)和周期极化磷酸氧钛钾(PPKTP)晶体单次穿过进行准相位匹配倍频,对应获得约336mW和210mW的780nm激光输出,倍频效率约为7%和4.4%。通过监视倍频光纵模,显示其具有良好的单频输出特性。此外,还扫描测得了Rb原子D2线的吸收光谱,表明780nm激光的频率调谐范围大于10GHz。采用无调制偏振光谱技术将1560nm半导体激光器频率锁定至87 Rb 5S1/2(Fg=2)-5P3/2(Fe=3)超精细跃迁线上。相对于自由运转450s内1560nm激光频率起伏约4MHz,锁定后可将残余频率起伏压低至1.5MHz左右。 相似文献
990.
以Luo-Rudy相I心脏模型为基础,研究心脏中螺旋波和时空混沌的控制,提出了两种控制方法: (Ⅰ)通过交替改变细胞外钾离子浓度来产生平面波,再利用弱外电场辅助平面波抑制螺旋波和时空混沌; (Ⅱ)先提高细胞外钾离子浓度,然后利用外电场激发波的方式产生平面波,再用平面波去抑制螺旋波和时空混沌. 研究结果表明,只要适当选择控制参数,这两种方法都能够有效抑制螺旋波和时空混沌. 当心肌出现局部缺血时,在心肌缺血处就会出现高的细胞外钾离子浓度,在这种情况下, 可以采用电场发射波的方法来抑制心脏中的螺旋波和时空混沌.对这些控制方法的优点和控制机制做了解释. 相似文献