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11.
Chi-Chang?HuEmail author Hong-Ru?Chiang Chen-Ching?Wang 《Journal of Solid State Electrochemistry》2003,7(8):477-484
The electrochemical characteristics of ruthenium oxides, formed on Ru-plated Ti electrodes in 0.5 M H2SO4 by potential cycling with different CV upper potential limits (E
SU), were systematically compared. The repeated potential cycling between 0.2 and 0.75 V activated the formation/reduction of
surface Ru oxides with hysteretic behavior. This application of repeated CVs also modified the ability of Ru deposits for
hydrogen adsorption/desorption. An irreducible Ru oxide accumulated on the electrode at potentials more positive than ca.
0.95 V, whose capacitive characteristics are applicable for electrochemical supercapacitors. This irreducible oxide was composed
of an aggregate consisting of Ru in various oxidation states, bridged oxygen, OH and water in a 3D-like structure with a relatively
ordered and compact nature, from the X-ray photoelectron spectroscopic and voltammetric results. The surface reconstruction
of the Ru deposits induced by the repeated potential cycling with E
SU≥0.75 V was clearly observed from the SEM photographs. From the X-ray diffraction patterns, all the anodically formed Ru oxides
showed an amorphous nature. 相似文献
12.
13.
袁峰 《合肥工业大学学报(自然科学版)》1998,(6)
系统地研究了新疆阿尔泰诺尔特地区阿克提什坎金-多金属矿床的微量元素组成特征,并应用Grant等位线方法讨论了热液蚀变作用过程中微量元素的行为。认为在热液蚀变作用过程中,微量元素尤其是Au、As等,活动强烈,围岩为成矿提供了部分物质来源。文章还进行了质量迁移的定量计算。 相似文献
14.
作者根据对新疆东天山典型金矿床的沉淀成矿环境、地球化学特征、稳定同位素特征等的系统分析和研究,论证了形成金矿床的硅质流体最初是一种以水为主要溶剂,以溶解态、胶体态氧化硅为主要溶质的高温高压(超临界态)溶液,其来源于地幔,是一种溶解了大量SiO2的地幔流体。而成矿元素主要来源于硅质流体上升运移过程中所经围岩,以致成矿物质来源具异源性。这对研究内生金矿床的成矿机制和成因有着十分重要的意义。 相似文献
15.
渐新统沙二段是济阳坳陷车西地区的主力油层,为了弄清其油气分布和控制因素,综合利用大量的地质和地球物理资料,首次在该段识别出漫湖洪水—风暴重力流沉积.该沉积具有明显的重力流沉积特征,砂岩的成分和结构成熟度均较低,粒度概率图多由悬浮次总体组成,沉积序列可用Bouma序列来描述.在明确了砂体的沉积层位和沉积边界的基础上,描述了漫湖洪水—风暴的沉积特征并建立了沉积模式,系统分析了这个环境下储集性砂体的分布及其油气聚集特征,为车西洼陷的进一步勘探指明了方向. 相似文献
16.
17.
某金矿床赋存于太华群龙潭沟组地层中,金矿床严格受断裂构造控制.通过对此金矿床地质特征的研究,系统总结了该矿床的控矿因素和找矿标志,并指明了矿区今后的找矿方向. 相似文献
18.
LU Anhuai GAO Xiang QIN Shan & WANG ChangqiuDepartment of Geology Peking University Beijing . China Correspondence should be addressed to Lu Anhuai 《科学通报(英文版)》2003,48(9):920-923
The Xiangtan manganese deposit (XTM) used to be considered a supergene oxide manganese ore in South China. We reported a new identification of the naturally outcropping cryptomelane by examining the physical, chemical and structural features of the XTM supergene oxide manganese ore. The MnO2 content was over 90%, K2O more than 3%, and water from 2.2%-3.1% which is similar to one in zeolite. The cell parameters of the cryptomelane were given as a0 = 0.9974 nm, b0 = 0.2863 nm, c0 = 0.9693 nm and β= 91.47°. There was a larger pseduotetragonal tunnel in the natural cryptomelane that was formed by [MnO6] octahedral double chains with aperture of 0.462×0.466 nm2, filled with K cations resulting in some Mn3+ substituting for Mn4+ to balance the negative charges of structure. The finding is important not only for prospecting manganese resources in South China, but also in application of octahedral molecular sieve of natural cryptomelane as that developed in the tetragonal molecular sieve of natural zeolite o 相似文献
19.
德兴斑岩铜矿成矿流体演化与来源的流体包裹体研究 总被引:10,自引:0,他引:10
主要研究了德兴斑岩铜矿床不同期次脉石英及花岗闪长斑岩石英斑晶中流体包覆体的特征,测定了流体包裹体的均一温度和冰点,估算了成矿流体的盐度、密度等参数.结合花岗闪长斑岩与石英脉中石英氢氧同位素数据的讨论分析,对流体的演化过程和来源进行了探讨.研究表明花岗闪长斑岩石英斑晶中的包裹体代表了岩浆流体的特征,石英脉中的包裹体记录了岩浆流体演化成成矿流体的特征。研究证实成矿流体主要由岩浆流体而来,成矿流体演化晚期有大气降水的加入。 相似文献
20.
Loess-soil sequences in southern Anhui Province: Magnetostratigraphy and paleoclimatic significance 总被引:8,自引:0,他引:8
QIAOYansong GUOZhengtang HAOQingzhen WUWenxiang JIANGWenying YUANBaoyin ZHANGZhongshi WEIJianjing ZHAOHua 《科学通报(英文版)》2003,48(19):2088-2093
Two parallel loess-soil sequences from Xuancheng and Fanchang in southern Anhui Provinces are dated using geomagnetic and luminescence methods.The Brunhes/Matuyama(B/M) reversal boundary is recognized within the lower part of the so-calles Vermiculated Red Soil (VRS) in the Xuancheng section while the entire Fanchang sequence is of Brunhes age.This indicated that the most recent VRS in southern China,a stratigraphic marker and an indication of extremely warm-humid conditions,was formed during the middle Pleistocene,chronologically correlative with the S4 and S5 soil units in northern China.Microscopic and sedimentologic in vestigations reveal that eolian deposition started in this region at about 0.85 MaBp,roughly synchronous with the well-known Mid-Pleistocene climate change of global significance.The strengthening of both summer and winter monsoon circulations and the consequent river hydrological changes at that time would have provided favorable conditions for sustained eolian deposition in the middle-lower reaches of the Yangtze River since 0.85 MaBP. 相似文献