长程电子关联对有限长聚乙炔链中极化子态的影响

本文采用扩展Hubbard模型, 加上长程关联哈密顿量,在自然边界条件下用自洽场方法研究了有限长反式聚乙炔链中极化子的问题。计算了长程电子关联对极化子的影响并计算了极化子的长程关联能。计算发现长程电子关联使极化子的位形变宽变浅(局域性减弱),在极化子区域,长程电子关联能比平均长程电子关联能要大。当链长增加到100格点以上时,电子极化子和空穴极化子的平均关联能趋于-0.1663eV,而在极化子区域,电子极化子和空穴极化子的平均关联能趋于-0.1868eV。     

极性晶体膜中束缚磁极化子的声子平均数与回旋共振频率的关系

采用改进的线性组合算符法和幺正变换方法,研究极性晶体膜中束缚磁极化子的声子平均数与回旋共振频率 的变化关系。得出束缚磁极化子的声子平均数由两部分组成：第一部分是由于电子—体LO声子相互作用所引起的;第二部分则是电子－SO声子相互作用引起的。而且当 时,声子平均数随着回旋共振频率 的增加而迅速增加,这主要是由于磁场的加入使电子声子的相互作用增强而引起的。     

球壳量子点中极化子和量子比特的声子效应

采用求解能量本征方程、LLP幺正变换、变分相结合的方法研究 球壳量子点中极化子和量子比特的声子效应. 数值计算表明: 声子效应使极化子的基态(或激发态)能量小于电子的基态(或激发态)能量, 使量子比特的振荡周期减小, 且内径给定时, 随着外径的增大声子效应对极化子和量子比特振荡周期的影响越大; 声子效应不改变量子比特内电子概率密度分布的幅值, 量子比特内中心球面处概率密度幅值最大, 界面处概率密度为零, 其它处的概率密度幅值介于最大和最小之间, 且各个空间点的概率密度随半径和方位角的变化而变化, 随时间做周期性振荡.     

Experimental and theoretical assessment of Fe-doped indium-oxide-based dilute magnetic semiconductors

Specimens of iron-doped indium oxide (In_1-xFe_x)₂O₃ with x?=?0.015, 0.03, 0.045 and 0.06, amalgamated through a traditional solid-state reaction method followed by H₂/air sintering, were characterised using an X-ray diffractometer (XRD), a vibrating sample magnetometer (VSM), and a scanning electron microscope (SEM) to investigate their structural, magnetic and morphological properties respectively. According to XRD plots, all the specimens exhibit cubic bixbyite structures along with ancillary phases. Magnetic assessment showed that In₂O₃ has a negative susceptibility, exhibiting diamagnetic behaviour at room temperature. The doping of Fe ions induces ferromagnetic (FM) ordering, which is enhanced with increasing doping content. The strength of the magnetisation increases when the specimens are exposed to H₂ but is reduced on further air sintering. A bound magnetic polaron (BMP) model is successfully fitted to the observed FM data involving localised carriers and magnetic cations. A multivariate assessment viz. a hierarchical cluster analysis (HCA) was used to corroborate and strengthen the experimental determined magnetic properties. A homogeneous particle distribution was observed in all SEM micrographs and is validated through MATLAB-based simulation by applying a watershed segmentation algorithm. Surface plots also confirm the change in magnetic properties with increase in doping concentration.     

Magnetic polaron-related optical properties in Ni(Ⅱ)-doped Cd S nanobelts: Implication for spin nanophotonic devices

Emissions by magnetic polarons and spin-coupled d-d transitions in diluted magnetic semiconductors(DMSs)have become a popular research field due to their unusual optical behaviors.In this work,high-quality NiI₂(Ⅱ)-doped CdS nanobelts are synthesized via chemical vapor deposition(CVD),and then characterized by scanning electron microscopy(SEM),x-ray diffraction,x-ray photoelectron spectroscopy(XPS),and Raman scattering.At low temperatures,the photoluminescence(PL)spectra of the Ni-doped nanobelts demonstrate three peaks near the band edge:the free exciton(FX)peak,the exciton magnetic polaron(EMP)peak out of ferromagnetically coupled spins coupled with FXs,and a small higher-energy peak from the interaction of antiferromagnetic coupled Ni pairs and FXs,called antiferromagnetic magnetic polarons(AMPs).With a higher Ni doping concentration,in addition to the d-d transitions of single Ni ions at 620 nm and 760 nm,two other PL peaks appear at 530 nm and 685 nm,attributed to another EMP emission and the d-d transitions of the antiferromagnetic coupled Ni²⁺-Ni²⁺pair,respectively.Furthermore,single-mode lasing at the first EMP is excited by a femtosecond laser pulse,proving a coherent bosonic lasing of the EMP condensate out of complicated states.These results show that the coupled spins play an important role in forming magnetic polaron and implementing related optical responses.     

钛酸锶晶体的光致介电常数激增以及超顺电大极化子理论

钙钛矿类化合物钛酸锶具有明显的光致介电增长的性质,这是由于被光激发至Ti⁴⁺的3d能带上的电子具有良好的巡游特性,为了进一步揭示光致介电增长的微观机理,这里假设巡游电子同时与两类声子发生耦合作用,一方面,电子与A_1g模式的晶格呼吸子发生强相互作用,另一方面,电子还与T_1u模式的非简谐声子具有相对较弱的耦合.通过变分法计算可得,这种复杂的电声耦合作用在晶体中形成两种极化子:自陷极化子和超顺电大极化子.正是由于超顺电大极化子的形成,导致了光致介电激增的现象.     

零温极性－极性晶体中界面磁极化子的性质

计入电子与纵光学（ＬＯ）声子和界面光学（ＩＯ）声子的互作用，进一步研究了界面磁极化子的性质，并给出了磁极化子的能级，重整化回旋质量和自陷能的表达式．结果表明，重整化回旋质量也依赖于纵向量子态和磁场强度；而自陷能也与横向量子态和磁场强度有关．     

三元混合晶体AxB1—xC中的极化子

本文讨论了弱耦合下三元混合晶体A_xB_(1-x)C中的极化子问题.在绝对零度下,用微扰法导出了极化子基态能量和有效质量表达式,对几种三元混合晶体进行了数值计算.在浓度x=0和x=1时,得出的结果与对应的二元晶体——BC,AC的结果完全等价.     

Charge transport in poly(methylphenylsilane): The case for superimposed disorder and polaron effects

Careful analysis of the temperature dependence of the hole mobility in poly (methylphenylsilane) indicates that the functional dependence is between an Arrhenius law and a ln μ ∝ T^?2 law as predicted by a model of disorder-controlled hopping. This is attributed to the superposition of disorder and polaron effects. A method is presented for separating the two contributions. The evolution of time-of-flight photocurrent transients with decreasing temperature is consistent with the disorder parameter derived from the temperature dependence of the mobility. © 1994 John Wiley & Sons, Inc.     

多原子极性半导体中体极化子的内部激发态

研究多原子极性半导体中强耦合体极化子内部激发态的性质，采用线性组合算符和么正变换方法计算多原子极性半导体中强耦合体极化子的基态能量，第一内部激发态能量和激发能量。