NMR spectra of chiral smectic liquid crystals differing in helical parameters

Chiral liquid crystals with three-ring rigid core were examined. The method based on the selectively reflected light was used to determine the helical pitch. The helical twist sense was worked out using the polarimetry method. ¹H and ¹³C NMR measurements were performed. The influence of three molecular structure parameters: the type of chiral centre, the length of non-chiral chain and substitution of benzene ring by fluorine atoms, on helical pitch, handedness of helical structure and values of chemical shift in proton and carbon spectra was determined. The change of the length of non-chiral terminal chain has the most significant influence on the temperature dependence of helical pitch. All tested parameters have the biggest influence on the values of chemical shift of atoms in the chiral centre.     

Low power operated highly luminescent ferroelectric liquid crystal doped with CdSe/ZnSe core/shell quantum dots

We report the enhancement in the molecular ordering of ferroelectric liquid crystal (FLC) doped with CdSe/ZnSe graded core/shell (CZ) quantum dots (QDs) by using optical methods. Significant decrease in operating voltage and enhancement in optical brightness are assigned to the large primary order parameter (θ) and hence anchoring of FLC molecules by CZ QDs. The enhancement in photoluminescence is conjectured to be due to an increase in molecular alignment yielding higher absorption which is confirmed by excitation spectra. These observations would definitely offer a promising tool to get superior core/shell QD incorporated FLC-based display devices.     

螺距和孔隙对螺栓连接自松弛的影响

为了研究螺距和孔隙对螺栓连接自松弛的影响,建立了带螺纹的三维螺栓连接有限元模型,使用Newmark算法进行了螺栓连接横向振动瞬态求解,分析了不同螺距和孔隙对螺栓连接横向振动自松弛的影响。研究结果表明:在横向循环载荷作用下,粗牙螺纹的螺栓连接相比细牙螺纹的预紧力下降速度要慢、螺纹啮合面和承压面的滑移要剧烈,因此细牙螺纹较粗牙螺纹不容易发生自松弛;孔隙越大螺栓连接预紧力下降速度越快、螺纹啮合面和承压面的滑移越剧烈,因此，孔隙越大越容易发生自松弛。     

大型双排四点接触球轴承载荷分布影响因素研究

为充分研究大型双排四点接触球轴承的载荷分布,采用超单元法模拟滚珠滚道接触,用等效梁法模拟螺栓,得到大型双排四点接触球轴承有限元简化模型,并通过与理论模型及经验公式结果对比,验证了该模型的正确性。在此基础上,利用此模型分析螺栓预紧力、安装表面平面度及变桨同步度对轴承载荷分布的影响。结果表明:随着均布螺栓预紧力的增加,轴承最大接触载荷先降低后小幅增加;非均布螺栓预紧力使轴承接触载荷波动加剧;平面度误差会造成轴承接触载荷分布不规则突变;当变桨同步度为负时,轴承的接触载荷增大。     

Double UV polymerisation with variable temperature-controllable selective reflection of polymer-stabilised liquid crystal (PSLC) composites

In this study, a method of preparing wide-band reflection cholesteric liquid crystals (CLCs) films by UV-radical polymerisation in combination with UV-cationic polymerisation is proposed. Because the helical twisting power (HTP) of the chiral dopant decreases with increasing temperature and the polymerisation rate of UV-initiated free radical polymerisation is faster than UV-initiated cationic polymerisation, by adjusting the temperature, broadband reflective films with non-uniform pitch distribution are obtained. The fractured surface of the polymer network of the broadband reflective films is observed by scanning electron microscopy (SEM), which reveals the presence of non-uniform pitch distribution. In addition, the influences of monomer concentration, UV light intensity and UV curing time on the consequent non-uniform pitch distribution have been studied.     

兆瓦级风力发电机组液压系统的设计与应用

针对兆瓦级风电机组的偏航系统、风轮锁定、主轴制动液压系统的设计及应用问题,进行了研究探讨并提出相应的解决方案。     

三爪离合器螺旋面在数控加工中的数学处理

对螺旋面在数控加工中涉及的数值计算进行了全面分析,给出了刀具轨迹坐标计算的完整公式,为计算机辅助计算提供了数学依据。所用的方法也适应于斜螺旋面和渐开线螺旋面的数学处理。     

螺距累积误差对数控机床精度的影响与对策

分析了机床定位精度对数控机床精度的影响 ,探讨了丝杠螺距累积误差对数控机床定位精度的影响 ,最后提出用软件补偿的办法来减少螺距累积误差对CNC机床的影响。     

音乐错觉研究进展

概述了音乐错觉研究的历史,归纳和总结了国外学者在音乐错觉研究中已取得的研究成果。将音乐错觉研究成果归纳为2大类：第一类为双通道音乐错觉,包括八度错觉和音节错觉;第二类为半八度错觉,并介绍了半八度错觉与语言的关系的研究。指出当前音乐错觉研究所处的状态以及今后研究的方向。