Simultaneous acquisition of X-ray spectra using a multi-wire, position-sensitive gas flow detector

A multi-wire, gas-filled position-sensitive detector has been developed for the simultaneous recording of wavelength-dispersed X-ray signals that enables X-ray fluorescence spectrometry with a limited multi-element capability in the low Z element range. Details of the modular construction of the detector are given. The detector performance was characterized using Al–K radiation and a variable slit system. The detector has been applied in a laboratory spectrometer equipped with an electron source and a double multilayer mirror device as the wavelength-dispersing element. Spectra from Al and Si obtained in the simultaneous acquisition mode show good agreement with calculations performed using a ray-tracing model.     

Analysis of Terbumeton and its Major Metabolites by SPE and DAD-HPLC in Soil Bulk Water

A rapid and inexpensive method for simultaneous quantification of terbumeton (TER), and its major potential metabolites (TED; terbumeton-desethyl, TOH; terbumeton-2-hydroxy and TID; terbumeton-deisopropyl) in soil bulk water (SBW) samples is proposed. The analytical method involves extraction–concentration from SBW samples using a graphitized carbon black (GCB) cartridge followed by their separation–detection by reversed-phase high-performance liquid chromatography analysis using a C₁₈ column and a diode array detector. A mobile phase of acetonitrile−0.005 mol L⁻¹ phosphate buffer (pH 7.0) (35:65, v/v) at a flow rate of 0.8 mL min⁻¹ in isocratic elution mode has been used. After optimization of the extraction and separation conditions, this method can be used for the simultaneous determination of investigated compounds in the range of the international limits of 0.1 μg L⁻¹. For TER the detection limit was 0.009 μg L⁻¹ and it was 0.100, 0.550, and 0.480 μg L⁻¹ for TED, TOH, and TID, respectively. The recoveries of TER, TED, TOH, and TID from SBW samples, measured at three levels of concentration range, were found to be between 48.0 and 102.0%. The intra-day precision measured by relative standard deviation (RSD) was always lower than 9.0%.     

Synthesis of mono meso-pyridyl 21,23-dithiaporphyrins and unsymmetrical non-covalent porphyrin dimers

A new method has been developed to synthesize 21,23-dithiaporphyrins having one pyridyl group at the meso position. The method required easily available unknown precursors and the condensation resulted in mono meso-pyridyl 21,23-dithiaporphyrins as single products in 8-11% yield. Two of the three mono meso-pyridyl N₂S₂ porphyrins were used to synthesize non-covalent unsymmetrical porphyrin dimers containing one N₂S₂ and one N₄ porphyrin cores.     

可变2n点流水线FFT处理器的设计与实现

设计一种可以连续计算N点复数序列傅里叶变换(FFT)的流水线结构处理器,其序列长度N(为2的幂)可变.流水线结构由乒乓存储器将基本运算模块级联而成,对输入数据的顺序以及流水运算的级数加以控制便可计算不同长度序列FFT.给出了由序列长度控制输入数据倒序、旋转因子寻址以及数据输出的实现方法.数据采用块浮点表示,提高了运算精度.用硬件描述语言VHDL在寄存器传输级(RTL级)进行描述,并在单片FPGA上实现.该芯片可工作在80 MHz,连续计算时,处理长度为1 024点的序列仅需12.8 μs.     

相控线阵声波测井辐射器驱动信号源的设计与测试

介绍了相控线阵声波测井辐射器的工作原理，根据辐射器各个阵元的性能参数设计了两种供实验使用的激励信号源，即5通道Burst信号源和4通道脉冲信号源。Burst信号源输出电压峰值连续可调（6～30V），相邻通道之间的延迟时间可调（0～22μs），步长为1μs，输出频率可根据换能器的频带在10-250kHz选择。脉冲信号源输出电压幅度连续可调（50～150V），延迟时间为0～7vs可调，步长为0.25μs,脉冲宽度为1～4μs。利用这两种信号源可以对相控线阵声波辐射器进行相位和幅度加权控制。在实验室内对这两种信号源进行了性能测试，结果表明，两个信号源均能满足实验要求。     

浅析C语言指针的灵活运用及常见错误

针对学生在学习指针过程中遇到的困难及使用指针过程中出现的常见错误,讨论指针的概念、指针与数组的关系、指针与函数的关系、指针作为函数参数的实质,帮助学生克服困难和错误。     

VB控件的动态增减

论述了VB中动态增减控件的实现方法,给出了程序或语法实例,并指出了各自的适用条件和编程方式,为VB应用程序开发提供了有意义的参考.     

非线性随机效应模型的若干统计推断

该文利用非线性随机效应模型在欧氏空间的BW几何结构，求出了固定效应参数估计的渐近性质与随机展开式。利用随机展开式，求出固定效应参数的偏差和方差的曲率表示式。     

一种结构紧凑的新型微带单脉冲天线阵

该文提出了一种新的“十”字型微带结构单脉冲天线和差网络。用这种网络成功地设计并加工了微带单脉冲阵列天线。这个天线阵由 4个 8× 8幅度为均匀分布的微带天线子阵组成。和差网络和天线阵处于同一平面 ,因而具有结构紧凑、简单 ,加工方便和成本低的优点。根据实测结果 ,水平方向的和方向图与差方向图均与理论预估吻合良好 ,表明和差网络的设计是成功的。如果天线阵的幅度分布按低副瓣设计 ,则也可以用在微带低副瓣天线阵上。分析和实测都表明 ,这种天线阵还具有比常规天线阵带宽更宽的优点。     

二维金纳米微粒有序阵列的制备

对于用十二烷基硫醇包覆的金纳米微粒，用Langmuir-Blodgett(LB)技术制备了二维金纳米微粒有序阵列．在单纯的硫醇包覆的金纳米微粒形成的LB膜中，由于硫醇分子之间的疏水相互作用，容易导致金纳米微粒的自组织而在LB膜中形成缺陷．为了改善金纳米微粒的成膜性能和提高金纳米微粒阵列的有序性，正十二醇作为添加剂和润滑剂加入到金纳米微粒的氯仿溶液中与金纳米微粒一起形成LB膜．用透射电子显微镜对金纳米微粒的二维阵列进行了表征．结果表明，正十二醇的加入可以有效地减少用LB技术制备的二维金纳米微粒阵列中的缺陷，提高金纳米微粒阵列的有序性．