Trace determination of parabens in cosmetics and personal care products using fabric‐phase sorptive extraction and high‐performance liquid chromatography with UV detection

A simple, fast, and sensitive analytical protocol using fabric‐phase sorptive extraction followed by high performance liquid chromatography with ultraviolet detection has been developed and validated for the extraction of five parabens including methylparaben, ethylparaben, propylparaben, butylparaben, and benzylparaben. In the present work, sol‐gel polyethylene glycol coated fabric‐phase sorptive extraction membrane is used for the preconcentration of parabens (polar) from complex matrices. The use of fabric‐phase sorptive extraction membrane provides a high surface area which offers high sorbent loading, shortened equilibrium time, and overall decrease in the sample preparation time. Various factors affecting the performance of fabric‐phase sorptive extraction, including extraction time, eluting solvent, elution time, and pH of the sample matrix, were optimized. Separation was performed using a mobile phase consisting of water:acetonitrile (63:37; v/v) at an isocratic elution mode at a flow rate of 0.9 mL/min with wavelength at 254 nm. The calibration curves of the target analytes were prepared with good correlation coefficient values (r² > 0.9955). The limit of detection values range from 0.252 to 0.580 ng/mL. Finally, the method was successfully applied to various cosmetics and personal care product samples such as rose water, deodorant, hair serum, and cream with extraction recoveries ranged between 88 and 122% with relative standard deviation <5%.     

浅谈信息时代的档案管理和档案资源开发

新时期全新的档案管理体系要求档案工作者不断提高自身素质,根据社会需求,主动开发档案信息资源,创新档案管理体系,以充分发挥档案的价值作用。     

浅谈科技档案价值的实现方式

科技档案价值的实现是当前科技档案工作的一项重要任务。结合工作实践,就如何充分挖掘、发挥科技档案的直接价值与间接价值进行了有益的探索。     

我国建立个人信用体系的问题探讨

完善的市场经济离不开信用经济,我国目前的个人信用经济还不太发达,主要是信用保证缺失,没有完善的个人信用体系。要发展我国的个人信用经济就要打破这个桎梏,学习外国先进经验,结合我们自身的实际,阶段性地建立我国的个人信用体系。     

增强现实技术在PDA上的应用

将增强现实技术与移动终端PDA相结合,在PDA上实现真实场景与虚拟增强信息的融合。系统采用基于Fourier_Mellin变换的2D图像匹配技术获取用户的视点参数,利用已标定的来自不同视点的图像作为参考图像库。采用客户/服务器构架减轻PDA的运算负担。研制的基于PDA移动终端的增强现实系统轻巧灵便,易于携带,通用性高,能够应用于户外场景。     

基于Ultra Search的桌面搜索设计与实现

提出一种基于Ultra Search的桌面搜索设计和实现方案,简要介绍了Ultra Search体系架构和各个组件的功能,然后给出该桌面搜索的框架和各个组件的实现细节,并和多个桌面搜索工具在相同的数据源上进行测试,结果表明,该桌面搜索有不错的搜索性能。     

基于J2ME的教师个人信息助理软件

随着高校教师越来越多地同时从事教学、科研和行政等各方面工作,有必要对各类相关信息进行简单方便的管理查询。笔者利用手机携带方便的特点,在基于Java 2 Micro Edition(J2ME)规范的手机上研制了教师个人信息助理软件。该软件功能系结合高校实际情况而设计,解决了手机数据导入和更新的问题。经过在多种手机上使用,证明该软件可以正常使用,并有助于提高教师的工作效率。     

Direct Potentiometric Study of Cationic and Nonionic Surfactants in Disinfectants and Personal Care Products by New Surfactant Sensor Based on 1,3-Dihexadecyl−1H-benzo[d]imidazol−3-ium

A novel, simple, low-cost, and user-friendly potentiometric surfactant sensor based on the new 1,3-dihexadecyl−1H-benzo[d]imidazol−3-ium-tetraphenylborate (DHBI–TPB) ion-pair for the detection of cationic surfactants in personal care products and disinfectants is presented here. The new cationic surfactant DHBI-Br was successfully synthesized and characterized by nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR) spectrometry, liquid chromatography–mass spectrometry (LC–MS) and elemental analysis and was further employed for DHBI–TPB ion-pair preparation. The sensor gave excellent response characteristics for CTAB, CPC and Hyamine with a Nernstian slope (57.1 to 59.1 mV/decade) whereas the lowest limit of detection (LOD) value was measured for CTAB (0.3 × 10⁻⁶ M). The sensor exhibited a fast dynamic response to dodecyl sulfate (DDS) and TPB. High sensor performances stayed intact regardless of the employment of inorganic and organic cations and in a broad pH range (2−11). Titration of cationic and etoxylated (EO)-nonionic surfactant (NSs) (in Ba²⁺) mixtures with TPB revealed the first inflexion point for a cationic surfactant and the second for an EO-nonionic surfactant. The increased concentration of EO-nonionic surfactants and the number of EO groups had a negative influence on titration curves and signal change. The sensor was successfully applied for the quantification of technical-grade cationic surfactants and in 12 personal care products and disinfectants. The results showed good agreement with the measurements obtained by a commercial surfactant sensor and by a two-phase titration. A good recovery for the standard addition method (98–102%) was observed.     

个人住房抵押贷款模式及应用

提出了等比还贷,等差还贷,基于等额的灵活还贷和混合还贷4种模式,举例分析并指出了各模式适合的客户类型,最后对贷款利率调整时各模式的有关变化作了进一步的探讨,各种还贷模式可根据具体情况在实践中推广应用。     

国内个人知识管理研究文献的综述与分析

以KNS5．0平台检索关于个人知识管理研究的文献为依据，对我国现阶段个人知识管理的相关研究文献进行综述，根据摘要、主题词和内容，析出了关于个人知识管理的主要研究主题，并对主要和显著增长的几类分别从学者、文献、机构等方面进行概述和分析，最后，在对相关文献进行评述的基础上对未来的研究提出了建议．同时预测了国内未来个人知识管理研究的新主题和方向．