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161.
The research on aggregation-induced emission (AIE) has drawn increasing interests in the past decade. With the efforts scientists paid, a variety of AIE systems have been developed, among which the tetraphenylethelene and silole derivatives are the most studied. Development of new AIE systems could further enrich the AIE molecules and promote the development of AIE area. In this communication, we prepared a new AIE system based on 1,2,4,6-tetraphenylpyridinium ions according to the restriction of intramolecular rotation mechanism. These molecules could be facilely synthesized via one-step and one-pot reaction. The ionic AIE-active molecules could find wide application in sensing and optoelectronic areas. 相似文献
162.
On the construction of periodic solutions of kaplan-yorke type for some differential delay equations
In this paper we point out the main idea to yield periodic solutions of Kaplan-Yorke type of differential delay equations. Some new sufficient conditions for the existence of Kaplan-Yorke type periodic solutions have been given. Many interesting examples are also disscused. 相似文献
163.
Solid state NMR spectroscopy is swiftly emerging as useful tool to characterize the structure, composition and dynamic properties of lead halide perovskites. On the other hand, interpretation of solid state NMR signatures is often challenging, because of the potential presence of many overlapping signals in small range of chemical shifts, hence complicating the extraction of detailed structural features. Here, we demonstrate the reliability of periodic Density Functional Theory in providing theoretical support for the NMR characterization of halide perovskite compounds, considering nuclei with spin I=1/2. For light 1H and 13C nuclei, we predict NMR chemical shifts in good agreement with experiment, further highlighting the effects of motional narrowing. Accurate prediction of the NMR response of 207Pb nuclei is comparably more challenging, but we successfully reproduce the downshift in frequency when changing the halide composition from pure iodine to pure bromine. Furthermore, we confirm NMR as ideal tool to study mixed halide perovskite compounds, currently at the limelight for tandem solar cells and color-tunable light emission. 相似文献
164.
《Analytical letters》2012,45(16):2613-2625
Caloric restriction increases the life-span of a number of organisms. The relationship between the increase in life-span and the extent of caloric restriction, however, varies among species. The underlying mechanisms are yet unknown, but appear to be related to changes in metabolism. In order to investigate the metabolic response of caloric restriction of rats, here is presented the first nuclear magnetic resonance (NMR) spectroscopy-based study of how blood metabolite profiles are influenced by graded levels of caloric restriction. The study involved three groups of obese rats exposed to 0, 20, and 40 percent caloric restriction for five days. Blood serum from each individual was analyzed by 1H NMR and the resulting spectra were subjected to multivariate analysis by unsupervised principal component analysis and supervised orthogonal-partial least square discriminant analysis. The analyses revealed that a response to caloric restriction was present at 20 percent caloric restriction. The metabolites that distinguished the profiles at 20 percent restriction deviated from those at 40 percent restriction. The changes induced by caloric restriction were most clearly observed as an increased level of 3-hydroxybutyrate, and decreased levels of lipids and pyruvate. The metabolic responses of rats exposed to caloric restriction are in good agreement with a switch in metabolism from anabolic pathways towards fatty acid catabolism and gluconeogenesis, which is consistent with previous observations for mice. 相似文献
165.
考虑非线性时滞微分方程组周期解的存在性问题,应用Leray-Schauder不动点定理,证明了非线性微分方程组周期解新的存在性结果. 相似文献
166.
Yongkun Li Tianwei Zhang 《Communications in Nonlinear Science & Numerical Simulation》2012,17(2):904-913
This paper is concerned with some dynamic behavior of enterprises cluster constituted by n satellite enterprises and a dominant enterprise. We present a model involving time-varying delays and feedback controls based on ecology theory, which effectively describe the competition and cooperation of enterprises cluster in real economic environments. Applying the comparison theorem of differential equations and constructing a suitable Lyapunov functional, sufficient conditions which guarantee the existence of a unique globally asymptotically stable nonnegative almost periodic solution of the system are obtained. Finally, we present an example to explain the economical significance of mathematical results. 相似文献
167.
《Physics letters. A》2014,378(5-6):480-483
We have shown in [1] that the invariant varieties of periodic points (IVPP) of all periods of some higher dimensional rational maps can be derived, iteratively, from the singularity confinement (SC). We generalize this algorithm, in this paper, to apply to any birational map, which has more invariants than the half of the dimension. 相似文献
168.
Primal, dual and saddle-point characterizations of optimality are given for convex programming in the general case (nondifferentiable functions and no constraint qualification). 相似文献
169.
170.