Spectroscopic Interrogation of Layer-by-layer Assembled Films of Conjugated Polyelectrolytes

Layer-by-layer fluorescent conjugated polyelectrolyte films have been studied. The photoluminescence of conjugate polyelectrolytes was observed to be highly tunable during this film assembly process. Efficient photoinduced electron transfer from thus prepared highly luminescent film to a natural electron-transfer protein cytochrome c has also been observed.     

[Co（H2o）4（NCS）2]（18—C—6）的薄层光谱电化学研究

利用光谱电化学方法来研究冠醚类化合物的文章尚未见报导.本文在测定用凝胶法合成的[Co(H_2O)(NCS)_2](18-C-6)的核磁共振谱和红外光谱的基础上,使用循环伏安法和薄层光谱电化学技术,在金微栅电极上测定了此配合物在乙腈溶剂中的第一步克式量电势(E~0′)和电子转移数(n),并推测了电还原反应机理.     

Stainless steel capillary columns for high temperature gas chromatography

A layer of elemental silicon has been deposited on the surface of stainless steel tubing by means of chemical vapor deposition (CVD). Two kinds of capillary column were prepared from the deactivated tubing: cross-linked, silanol-terminated polydime-thylsiloxane wall coated open tubular (WCOT) columns and molecular sieve 13X porous layer open tubular (PLOT) columns. Unlike fused silica capillary columns, stainless steel WCOT and PLOT columns can be operated at temperatures in excess of 400°C. High temperature simulated distillation has been performed successfully with a macro bore WCOT column and rapid PNA (paraffin, naphthene, and aromatic) analysis with a multidimensional gas solid chromatographic (GSC) system using PLOT columns.     

The preparation of thick-film glass capillary columns

A detailed method for the routine preparation of glass capillary columns is presented. The method consists of coating a glass tube with quartz powder prior to pulling the tube into a capillary. The inner surface of the capillary consists of an even distribution of quartz particles fused to the walls. This surface has been found readily deactivated by standard procedures and ideal for the preparation of thick-film glass capillary columns. The method has been thoroughly tested in two independent laboratories to ensure that the procedures described are reproducible.     

边界层对粗糙单裂隙溶质运移影响试验

为探究非费克(non-Fickian)运移表现出的峰值提前到达和拖尾等现象,开展了粗糙单裂隙溶质运移试验,总结了粗糙单裂隙中溶质运移特征及运移机理,结合边界层理论对峰值提前到达和拖尾现象进行了分析和解释。结果表明：峰值时间和拖尾时间与边界层厚度之间存在较好的线性相关关系;边界层对裂隙介质溶质运移有较为显著影响,即水流速度越小,边界层厚度越大,滞留在边界层内部的溶质越多,溶质获取率越低;粗糙单裂隙中溶质穿透曲线的峰值提前和拖尾现象是由裂隙中心处以惯性力主导的主流区和裂隙壁面以黏性力主导的边界层区共同作用造成的,其中峰值时间主要由主流区的对流因素控制,而边界层区域的存在对拖尾时间影响较大。     

带背景激波系的凹腔流动特性研究

凹腔作为超燃冲压发动机的一种火焰稳定器受到广泛关注,凹腔剪切层与背景激波系的相互作用影响凹腔火焰稳定器的性能。为深入分析背景激波系对凹腔流动的影响,设计了长深比为13.3的闭式凹腔,将凹腔模型前缘激波和风洞上壁面干扰激波作为背景激波系,在Ma=2的直连式风洞中开展了背景激波系与凹腔剪切层的相互作用的试验,采用高速纹影系统对瞬态流场进行了捕捉,重点关注背景激波系和凹腔剪切层的动态变化特性。采用纹影序列的本征正交分解来研究流场中的主要相干结构,采用快速傅里叶变换和连续小波变换对流场的频率域特征进行了分析。结果表明：在背景激波与剪切层相互作用下,激波结构产生大尺度振荡,凹腔内流动结构产生小尺度脉动。通过对激波位置的傅里叶变换分析,发现激波振荡的主导频率集中在90～400 Hz的范围内。通过对纹影图像的空间傅里叶变换分析,发现5 kHz以下的流场振荡主要由激波振荡引起,5 kHz以上的流场脉动主要由凹腔内流动结构引起。     

Lamination Design Optimization for Continuous Fiber Reinforced Composites of Variable Thicknesses北大核心CSCD

由于具备高的比强度、比刚度,利用连续纤维增强复合材料代替传统金属材料以实现结构轻量化正受到设计者们的广泛关注。然而,结构的复杂性给复合材料的铺层设计与优化带来了很大的挑战。针对航空用复合材料铺层设计约束多的问题,通过逐步构建设计变量准确表达结构的铺层信息。基于经典遗传算法框架,结合各设计变量特点,定义了铺层优化算法中的遗传算子,通过引入“修复”策略保证了每一代解都能满足设计约束,分布在可行域区间内。最后利用精英保留策略提高了算法的局部寻优能力,可以降低复杂复合材料结构铺层设计的计算成本。通过解决经典benchmark问题并与已有优化结果的比较,验证了前述铺层优化算法的全局、局部寻优能力,为工程实际中的复合材料铺层设计优化提供了理论支撑。     

计算旋转螺旋面三维边界层的一种积分方法

本文将计算二维层流边界层的Thwaites方法和计算二维湍流边界层的Truckenbrodt方法推广,用以求解旋转系统的“准三维”边界层方程,得到了计算旋转螺旋面上三维边界层的一种可迭代求解的积分方法.应用此方法进行了两例计算.计算结果与理论精确解或实验测量的对比表明,本文方法是有效的.     

Direct analysis of thin-layer chromatographic spots of narcotics by means of diffuse reflectance Fourier transform infrared spectroscopy

The technique of diffuse reflectance Fourier transform infrared spectrometry (DRIFT) as an in situ detection method was used for the qualitative and quantitative analysis of drugs (heroin, cocaine and codeine) separated by thin layer chromatography.It was found that at a given interferometer throughput and detector sensitivity the quality of the spectrum depends strongly in the type of the chromatographic thin layer used. A detection limit of approx. 2 g was attained on a microcrystalline cellulose thin layer with a dynamically aligned Bio-Rad Digilab FTS 60A/896 type interferometer and room temperature DTGS detector. A reliable qualitative analysis can be made with as little as 10 to 15 g drug per spot.     

Lyotropic effect in surface charge,electrokinetics, and coagulation of a rutile dispersion

Potentiometric, electrokinetic, and coagulation experiments with a rutile dispersion in the pH region above the point of zero charge exhibit an inverse lyotropic sequence for counterions: Li⁺>K⁺>Cs⁺. The potentiometric and electrokinetic data were interpreted by a surface complexation model assuming the Stern-Gouy-Chapman structure of the interfacial layer, which yielded the values of inner layer capacitances,C, and the intrinsic equilibrium constants,K _ass ⁰ , characterizing the specificity of each counterion. These parameters were used to explain the order of lyotropic sequences in the adsorption, coagulation, and electrokinetic phenomena.