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61.
62.
Partition coefficients P of the HNCS, HNCO and HN3 hydropseudohalic acids between a number of organic solvents and water were determined. It has been found that log P increases with pKa of the acid and with the basicity of the solvent, but the effect of pKa on P is the smaller the more basic is the solvent. The relationships have been explained in terms of hydrogen bond formation between undissociated acid and solvent molecules. H-bonding between the pseudohalic acids and organic solvents has been confirmed by IR spectra on the example of HN3 in benzene. Association constants for H-bonding between the three acids and water, benzene, dibutyl ether and tri-n-butyl phosphate were determined from partition data. It has been found that H-bonding increases with the strength of the acid, whereas the contribution to partition from non-specific interactions with water and organic solvents depends on the molecular surface area of the acid molecule. 相似文献
63.
修正的分子连接性指数mL用于氯代苯、醇、酯的QSAR/QSRR研究 总被引:15,自引:0,他引:15
在分子拓扑理论的基础上,提出了1个改进的连接性指数气^mL并用气研究了氯代苯、醇、酯的正辛醇-水分配系数及气相色谱保留指数,^mL不仅对这些有机化合物有良好的结构选择性,而且与其正辛醇-水分配系数、气相色谱保留指数有良好的相关性;由方程得出的预测值与实验测定值之间能较好地吻合。 相似文献
64.
Filiz Taneri Tamer Güneri Zolt%aacute;n Aigner Michael Kata 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):257-260
Highly-soluble cyclodextrin derivatives, such as hydroxypropyl--cyclodextrin(HP--CD) and methyl--cyclodextrin (MEB), were tested as solubilizingagents for ketoconazole, with the aim of improving the physicochemical andbiopharmaceutical properties of this lipophilic imidazole antifungal agent. Productswere prepared in four molecular ratios by physical mixing, kneading and spray-dryingmethods. The kneaded products in a ratio of 1:2 and the spray-dried products exhibitedthe highest dissolution rates. The phase solubility diagrams of ketoconazole with thesecyclodextrins at 25 °C in water and in simulated intestinal medium wereconstructed. A solubility diagram of AL type was obtained with HP--CD, and one of AP type with MEB. The complexes were characterized by thermal methods(DSC, TG, DTG and DTA). Multicomponent systems were prepared with tartaric acid.The effects of water-soluble polymers, e.g., polyvinylpyrrolidone, on the aqueous solubility of ketoconazole were investigated. Particle size distribution, surface area, partition coefficient, heat of dissolution and wettability studies were also carried out. The formation of inclusion complexes was observed by means of thermoanalytical studies. 相似文献
65.
通过对烷烃,醇类等有机物在五种不同极性固定相上的气相色谱保留值的测定,提出了从有机物气相色谱保留值测定其正辛醇/分配系数的公式,研究了从不同极性固定相上测得的保留值来测定其分配系数的准确性,得出烷烃类在所有柱上测得的保留值与其分配系数间均具有很好的关联,烷烃醇类在极性相异柱上的保留值之比值与其分配系数间也有很好的相关性,从而为烷烃及醇类等有机物分配系数的测定提供了一种简单、可靠,易行的新方法。 相似文献
66.
《Analytical letters》2012,45(11):795-805
Abstract Reverse phase partition chromatography on a 10 micron silica-bonded octadecyl hydrocarbon substrate is applied to the separation of neutral tetradentate chelates of copper (II), nickel (II) and palladium (II) with a range of non-fluorinated and fluorinated beta-ketoamine and salicylaldimine ligands. Variation of retention and resolution with respect to changes in ligand structure and metal chelated is investigated using acetonitrile, methanol and water solvent systems. Detection limits (254 nm) and linearity ranges of response are indicated. 相似文献
67.
Multi-temperature thermal plasmas have often to be considered to account for the nonequilibrium effects. Recently André et al. have developed the calculation of concentrations in a multi-temperature plasma by artificially separating the partition functions into a product by assuming that the excitation energies are those of the lower levels (electronic, vibration, and rotation). However, at equilibrium, differences, increasing with temperature, can be observed between partition functions calculated rigorously and with their method. This paper presents a modified method where it has been assumed that the preponderant rotational energy is that of the vibrational level v=0 of the ground electronic state and the preponderant vibrational energy is that of the ground electronic state. The internal partition function can then be expressed as a product of series expressions. At equilibrium for N
2
and N
2
+
partition functions the values calculated with our method differ by less than 0.1% from those calculated rigorously. The calculation has been limited to three temperatures: heavy species Th
, electrons Te
, and vibrational T
v
temperatures. The plasma composition has been calculated by minimizing the Gibbs free enthalpy with the steepest descent numerical technique. The nonequilibrium properties have been calculated using the method of Devoto, modified by Bonnefoi and Aubreton. The ratio =Te/Th
was varied between 1 and 2 as well as the ratio
v
=T
v
/T
h
for a nitrogen plasma. At equilibrium the corresponding equilibrium transport properties of Ar and N
2
are in good agreement with those of Devoto and Murphy except for T>10,000 K where we used a different interaction potential for N–N
+
. The effects of v
and e
on thermodynamic and transport properties of N
2
are then discussed. 相似文献
68.
Mohamad Toutounji 《International journal of quantum chemistry》2011,111(9):1885-1892
Exact closed forms of the equilibrium partition functions in terms Jacobi elliptic functions are derived for a particle in a box and Rosen–Morse (Poschl–Teller) oscillator (perfect for modeling bending vibrational modes). An exact form of the equilibrium partition function of Morse oscillator is reported. Three other approximate forms of Morse partition function are presented. Having an exact closed‐form for the vibrational partition function can be very helpful in evaluating thermodynamic state functions, e.g., entropy, internal energy, enthalpy, and heat capacity. Moreover, the herein presented closed forms of the vibrational partition function can be used for obtaining spectroscopic and dynamical information through evaluating the two‐ and four‐point dipole moment time correlation functions in anharmonic media. Finally, a closed exact form of the rotational partition function of a particle on a ring in terms of the first kind of complete elliptic integral is derived. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
69.
煤中Se、Cd在焦化过程中迁移规律的研究 总被引:1,自引:0,他引:1
利用现代分析测定仪器和实验室模拟手段,以煤及固相(焦炭)、液相焦化产物(焦油、氨水)、气相焦化产物(煤气)中有害微量元素镉(Cd)、硒(Se)为研究对象。通过测定,比较不同煤化度煤种微量元素的含量,并归纳探讨了配合煤中Cd、Se元素在焦化过程中的迁移规律。发现煤化度不同的煤中,镉元素随着煤变质程度升高而减少;硒元素含量对比:QFFM,JM和SM中含量相差不大。在模拟焦化温度1 000℃环境下,分别有45%的硒和48%的镉元素转移到焦炭中,2%的硒和7%的镉转移到氨水中,12%的硒和15%的镉转移到焦油中,并通过物料衡算,发现有41%的硒和30%的镉释放到煤气中。 相似文献
70.
Mangosteen fruit pericarp (MFP) is a rich source of xanthones, which has shown remarkable pharmacological activities. To isolate xanthones, previous methods included labor intensive and time‐consuming solid‐phase extractions (Sephadex LH20, silica gel) and sequential solvent extraction. In this study, major xanthones (α‐ and γ‐mangostins) in MFP were isolated at high purity in one step utilizing high‐performance centrifugal partition chromatography with solvent system composed of petroleum ether, ethyl acetate, methanol and water (10:5:5:1). In one run, 200 mg crude extract of MFP was injected and 55.4 mg α‐mangostin and 12.4 mg γ‐mangostin were obtained with the purity of 93.6 and 98.4%, respectively. The yields of them were 86.3 and 76.3%, respectively. As α‐ and γ‐mangostins are reported to show potent antioxidant, anti‐inflammatory and anticancer activities, this method can be used for the large‐scale production of them for future in vitro and in vivo biological studies. 相似文献