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51.
A solution to the BBGKY hierarchy for nonequilibrium distribution functions is obtained within modified boundary conditions. The boundary conditions take into account explicitly both the nonequilibrium one-particle distribution function as well as local conservation laws. As a result, modified group expansions are proposed. On the basis of these expansions, a generalized kinetic equation for hard spheres and a generalized Bogolubov–Lenard–Balescu kinetic equation for a dense electron gas are derived within the polarization approximation. 相似文献
52.
激光感生碰撞能量转移的四能级理论模型 总被引:6,自引:2,他引:4
首次考虑了两个中间态对激光感生碰撞能量转移的影响,发展了激光感生碰撞能量转移的四能级理论模型,推导出态振幅的运动方程,并给出碰撞截面的近似表达式,通过对Eu-Sr和Cs-Sr系统的数值计算表明,当频率差│ω21│大小和│ω43│可以相比时,利用三能级近似理论就难以获得令人满意的计算结果,而四能级理论模型则适合于任何情况下的激光感生碰能量转移。 相似文献
53.
Carlo Cercignani 《Journal of statistical physics》1990,58(5-6):817-823
The problem of finding the summational collision invariants for the Boltzmann equation is tackled with the aim of proving that the most general solution of the problem is not different from the standard one even when the equation defining a collision invariant is only satisfied almost everywhere inR
3×R
3×S
2. The collision invariant is assumed to be in the Hilbert spaceH
of the functions which are square integrable with respect to a Maxwellian weight. 相似文献
54.
Nanoscale organization of the pathogen receptor DC-SIGN mapped by single-molecule high-resolution fluorescence microscopy. 总被引:3,自引:0,他引:3
Bärbel I. de Bakker Dr. Frank de Lange Dr. Alessandra Cambi Dr. Jeroen P. Korterik Erik M. H. P. van Dijk Dr. Niek F. van Hulst Prof. Carl G. Figdor Prof. Maria F. Garcia‐Parajo Prof. 《Chemphyschem》2007,8(10):1473-1480
DC-SIGN, a C-type lectin exclusively expressed on dendritic cells (DCs), plays an important role in pathogen recognition by binding with high affinity to a large variety of microorganisms. Recent experimental evidence points to a direct relation between the function of DC-SIGN as a viral receptor and its spatial arrangement on the plasma membrane. We have investigated the nanoscale organization of fluorescently labeled DC-SIGN on intact isolated DCs by means of near-field scanning optical microscopy (NSOM) combined with single-molecule detection. Fluorescence spots of different intensity and size have been directly visualized by optical means with a spatial resolution of less than 100 nm. Intensity- and size-distribution histograms of the DC-SIGN fluorescent spots confirm that approximately 80 % of the receptors are organized in nanosized domains randomly distributed on the cell membrane. Intensity-size correlation analysis revealed remarkable heterogeneity in the molecular packing density of the domains. Furthermore, we have mapped the intermolecular organization within a dense cluster by means of sequential NSOM imaging combined with discrete single-molecule photobleaching. In this way we have determined the spatial coordinates of 13 different individual dyes, with a localization accuracy of 6 nm. Our experimental observations are all consistent with an arrangement of DC-SIGN designed to maximize its chances of binding to a wide range of microorganisms. Our data also illustrate the potential of NSOM as an ultrasensitive, high-resolution technique to probe nanometer-scale organization of molecules on the cell membrane. 相似文献
55.
用铜(Ⅱ)—L—精氨酸配体交换薄层色谱拆分氨基酸对映体 总被引:2,自引:0,他引:2
报道了一种新的配体交换薄层色谱拆分氨基酸对映体的方法。以醋酸铜-L-精氨酸的络合物为配体交换剂,用浸渍的方法吸附在硅胶薄层板上,制成配体交换薄层,用PRISMA优化法选择出展开剂的最佳组成为:甲醇/乙腈/四氢呋喃/水=80:8.2:5.8:6,在此色谱条件下,十对氨基酸对映体得到良好的分离,D-和L-氨基酸的相对比移值在1.09-2.40之间。文中对配体交换薄层的制备方法,样品的分子结构及色谱行为 相似文献
56.
T. Katsuki 《Russian Chemical Bulletin》2004,53(9):1859-1870
The recent development of asymmetric Baeyer—Villiger oxidation of prochiral and racemic ketones is briefly summarized, focusing on the regio- and stereocontrol of the oxidation attained by regulating the stereoelectronic demand in the step of rearrangement of the Criegee intermediate.Based on the report presented at the International Conference Modern Trends in Organoelement and Polymer Chemistry dedicated to the 50th anniversary of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences (Moscow, May 30–June 4, 2004).Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1784–1794, September, 2004. 相似文献
57.
58.
光学活性化合物的工业合成 总被引:9,自引:0,他引:9
本文介绍了光学活性化合物研究现状及发展趋势。并从技术和经济角度论述了工业合成光学活性化合物的可能性 相似文献
59.
Frost R. L. Weier M. L. Erickson Kristy L. 《Journal of Thermal Analysis and Calorimetry》2004,76(3):1025-1033
Struvite (NH4MgPO4·6H2O) is a mineral often found in urinary tracts and kidneys. Thermal decomposition using slow low heating shows that the 'kidney'
stone can be decomposed at temperatures below 40°C. At this temperature both ammonia and water are evolved. If more rapid
heating is employed the decomposition occurs at around 80°C. The implication of this work rests with the use of low slow heat
for the decomposition of the kidney stones.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
60.