Wavelength-independent ultrafast dynamics and coherent oscillation of a metal–carbon stretch vibration in photodissociation of Cr(CO)6 in the region of 270–345 nm

In the group-6 metal hexacarbonyls a number of metal-to-ligand charge-transfer (MLCT) and ligand-field (LF or d → d) states can be excited in the near UV. The latter are repulsive. In equilibrium geometry, most of them are higher than the MLCT states. We probed the dynamics of photodissociation of M(CO)₆ → M(CO)₅ + CO (M = Cr; some data also for M = Mo) with improved time resolution (10–40 fs), pumping at different wavelengths (mainly 270–345 nm) and probing by nonresonant photoionization. The initial relaxation (e.g. within 12.5 fs from T_1u excited at 270 nm) is assigned to direct crossing over to the repulsive surface, from where the subsequent dissociation is also remarkably fast (18 fs in this example). That is, there is no detour via the lowest excited singlet state, in contrast to the usual assumption. Also with 318 and 345 nm excitation a direct MLCT → LF relaxation seems to occur before dissociation. The product M(CO)₅ is generated in the S₁ state, also at pump wavelengths (345 nm) with barely sufficient energy. It relaxes to S₀ through a Jahn–Teller induced conical intersection along pseudorotation coordinates, which stimulates a coherent oscillation in S₀ in this vibration. A higher-frequency oscillation, assigned to totally symmetric MC stretch vibrations, is already found in the Franck–Condon region; it persists (with different wavenumbers) also during dissociation and over the subsequent product states. This vibration is transverse to the valley of dissociation, which is barrierless. The wavelength-independent mechanism also implies that there is no triplet contribution (which was previously supposed at long wavelengths) to photochemical dissociation of the hexacarbonyls.     

Global classical solutions to the compressible micropolar viscous fluids with large oscillations and vacuum

In this paper, we consider the three dimensional Cauchy problem of the compressible micropolar viscous flows. We prove the existence of unique global classical solution for smooth initial data with small initial energy but possibly large oscillations and the initial density may allowed to contain the interior and far field vacuum states. Furthermore, the large time behavior of the solution is obtained as well.     

中立型二阶非线性微分方程振动性的判据

Abstract. In this paper ,the oscillation criteria for the solutions of the nonlinear differential e-quations of neutral type of the forms:     

On the frequency of oscillations in the pair plasma generated by a strong electric field

We study the frequency of the plasma oscillations of electron–positron pairs created by the vacuum polarization in a uniform electric field with strength E   in the range 0.2Ec<E<10Ec$0.2E_c<E<10E_c$. Following the approach adopted in Ruffini, et al. (2007) [1] we work out one second order ordinary differential equation for a variable related to the velocity from which we can recover the classical plasma oscillation equation when E→0$E\to 0$. Thereby, we focus our attention on its evolution in time studying how this oscillation frequency approaches the plasma frequency. The time-scale needed to approach to the plasma frequency and the power spectrum of these oscillations are computed. The characteristic frequency of the power spectrum is determined uniquely from the initial value of the electric field strength. The effects of plasma degeneracy and pair annihilation are discussed.     

Flow induced oscillation of two rigid rectangular plates in a side-by-side configuration

The present work is an experimental study of two oscillating rigid plates placed in side-by-side configuration, hinged at their leading edges, subjected to low subsonic flow. This problem is investigated using smoke-wire flow visualization, hot-wire anemometry, and time resolved particle image velocimetry. It is found that beyond a critical Reynolds number, the plates set into oscillatory motion. This critical Reynolds number depends on the gap between the plates. It is also seen that this value of Reynolds number, at lower values of gap to thickness ratio (<7) is significantly higher than that of the single plate configuration value. The frequency and amplitude of the oscillating plates at various gaps and Reynolds numbers have been studied and compared with the characteristics of an oscillating single plate. It is also found that depending on the gap and acceleration of the free-stream, there exist two modes of oscillation - (i) in-phase and (ii) out-of-phase. For gap to thickness ratio less than 10, only in-phase oscillations take place for all values of free-stream velocity considered in the present work, whereas, when this ratio is greater than 10, the mode of oscillation depends on the initial conditions up to a certain free-stream velocity, beyond which the plates switch to in-phase mode. Smoke wire flow visualization technique along with time resolved particle image velocimetry reveal that the vorticity distributions around the plates are responsible for the initiation of the two modes of oscillations.     

利用线化和校正法求非线性振动近似解

非线性问题研究是当今工程应用研究的热点问题之一,常规方法有多尺度法、积分法、平均法、同伦摄动法等。但常规方法所能解决的非线性问题仍然十分有限。本文应用线化和校正法,研究了Duffing方程的非线性振动,分别求出了Duffing方程非线性振动周期的精确解和近似解,利用Maple9.0绘图分别作出了Duffing方程周期、绝对误差和相对误差随参数k的变化曲线。所得结论为Duffing方程周期随参数k的增加而减小,相对误差随参数k的增加而增加;Duffing方程周期近似解与精确解比较,具有简单实用、精度高、相对误差低等优点。该方法在求解非线性振动中具有较强的理论价值和实用价值。     

一类与单种群模型有关的非线性泛函微分方程解的振荡性

给出了一类一阶非线性泛函微分方程解的振荡性的充分性判据,并用例子说明了用线性化方程的振荡性判据去给出非线性方程的振荡性的判据有时是错误的。同时,得到了时滞的单种群方程的解的振荡性的一些充分性判据。     

Turbulent Channel Flow with an Artificial Two-Dimensional Wall Layer

Turbulent flow of an incompressible fluid in a plane channel with parallel walls is considered. The three-dimensional time-dependent Navier-Stokes equations are solved numerically using the spectral finite-difference method. An artificial force which completely suppresses lateral oscillations of the velocity is introduced in the near-wall zone (10 % of the channel half-width in the neighborhood of each wall). Thus, the three-dimensional flow zone, in which turbulent oscillations can develop, is separated from the wall by a fluid layer. It is found that the elimination of three-dimensionality in the neighborhood of the walls leads to a significant reduction in the drag. However, complete laminarization does not occur. The flow in the stream core remains turbulent and can be interpreted as a turbulent flow in a channel with walls located on the boundary of the two-dimensional layer and traveling at the local mean-flow velocity. The oscillations developing inside the two-dimensional layer, which have significant amplitude, distort the flow only in the adjacent zone. Beyond this zone the distributions of the mean characteristics and the structure of instantaneous fields completely correspond to ordinary turbulent flow in a channel with rigid walls. The results obtained confirm the hypothesis of the unimportance of the no-slip boundary conditions for the fluctuating velocity component in the mechanism of onset and self-maintenance of turbulence in wall flows.     

On the fundamental sloshing frequency in the ice-fishing problemSur la fréquence de ballottement principale dans le problème de la glace avec trous pour pêcher

The sloshing problem is considered in a half-space covered by a rigid dock with apertures. The dependence of the fundamental sloshing frequency on the shape of the free surface region is studied. It is proved that the inequality holds between the fundamental eigenvalues corresponding to two different regions if some conditions are fulfilled. These conditions are verified for particular classes of regions of a fixed area in order to demonstrate that the disk yields the maximum of the fundamental eigenvalue for each of these classes. On the other hand, examples of regions are constructed for which the fundamental eigenfrequency is larger than that for the circular aperture of the same area and even as large as one wishes. To cite this article: V. Kozlov, N. Kuznetsov, C. R. Mecanique 330 (2002) 723–728.     

正负双向脉冲式爆炸及其诱导的簇发振荡

簇发振荡普遍存在.探索通向簇发振荡的可能路径是簇发研究的热点问题之一."脉冲式爆炸(pulsed-shaped explosion,PSE)"是一种最近被报道的可以诱发簇发振荡的新机制,其特征为平衡点和极限环表现出了与参数变化相关的脉冲式急剧量变.PSE会导致系统轨线急剧跃迁,从而诱发典型的簇发振荡.然而,目前报道的PSE中仅含有"单向的尖峰",未发现"双向的尖峰",且由其诱发的簇发振荡仅含单向的振荡簇.本文以多频激励Rayleigh系统为例,旨在揭示PSE的不同表现形式以及与此相关的簇发动力学.利用频率转换快慢分析法得到了Rayleigh系统的快子系统和慢变量.针对快子系统的分析表明,PSE表现出了较为复杂的动力学特性,其特征是PSE包含了正负双向两个不同的尖峰,此即所谓的正负双向PSE.其急剧量变行为,导致了系统轨线在单个振荡周期内出现正向和负向的多次跃迁,由此得到了由正负双向PSE所诱发的簇发振荡.根据吸引子类型分别揭示了点--点型和环--环型两类簇发振荡模式的产生机制.本文的研究给出了PSE的不同表现形式,丰富了多时间尺度下的簇发振荡的诱发机制.