川东北部飞仙关组鲕滩气藏的发现及气藏特征

阐述了川东北地区从1963年石油沟构造巴3井首次在飞一段钻获天然气开始,到福成寨、板东、黄草峡构造上相继发现飞仙关组气藏,渡口河构造的渡1井在飞仙关组钻遇孔隙型白云岩,获天然气流,罗家寨、铁山坡、金珠坪等一批飞仙关组鲕滩整装气藏的勘探历程。分析了川东北地区飞仙关组鲕滩气藏的烃源条件、储集条件、盖层条件,指出飞仙关组天然气主要为原油裂解气,上二叠统及飞仙关组自身为其主要烃源;其储集岩类型主要为鲕粒云岩和溶孔鲕粒灰岩两大类。评价预测了储层发育有利区带。分析了气藏的形成过程,认为可划分为古油藏阶段、大气藏阶段、古气藏调整定型阶段等三个阶段。从地质构造、沉积相分布、圈闭要素等角度剖析了罗家寨等构造飞仙关组鲕滩储层的形成机理和气藏特征。     

还原剂对高磷鲕状赤铁矿还原焙烧铁磷分离的影响

研究还原剂种类及用量对高磷鲕状赤铁矿还原焙烧铁磷分离的影响.添加脱磷剂Na2CO3,在提铁降磷的同时能降低还原铁的硫含量;还原剂用量的增加都能促进铁还原,但使用灰分和固定碳含量较高或挥发分含量较低的还原剂时,不利于降磷.焙烧产物的X射线衍射分析表明:添加脱磷剂Na2CO3时,随着还原剂用量的增加,焙烧产物中金属铁含量增加,浮氏体和石英含量降低;使用灰分含量较高的还原剂时,随其用量的增加,灰分会消耗Na2 CO3,从而减弱其对于铁还原的促进作用;还原剂用量相同时,石煤、烟煤、焦炭和褐煤所得焙烧产物中金属铁含量逐渐增加,浮氏体含量逐渐降低.总体来看,褐煤作为还原剂时铁磷分离效果最好,其次为烟煤,焦炭和石煤.     

巴西某镜铁精粉的烧结特性及强化工艺

通过润磨单一镜铁矿或其与石灰石的混合料以提高镜铁矿表面性质和高温反应性能.测定润磨预处理前后巴西镜铁矿的润湿热、粒度组成及变形温度等指标,揭示其作用机理.通过烧结杯试验,考察润磨预处理强化烧结的效果.研究结果表明：采取预处理措施可提高巴西镜铁矿的润湿热和表面亲水性,降低变形温度,提高巴西镜铁矿的高温反应性能;烧结矿产量和质量大幅度提高,成品率增加3.7%,转鼓强度提高3.33%,固体燃耗降低4kg/t左右,利用系数提高22.4%,烧结矿质量完全满足高炉生产的需要.     

以赤铁矿为主配加磁铁矿制备的氧化球团矿显微结构

在链篦机 回转窑模拟装置中制备氧化球团矿,采用显微镜和扫描电镜研究单一赤铁矿及以赤铁矿为主配加磁铁矿制备的氧化球团矿显微结构.研究结果表明:当单一赤铁矿球团在焙烧温度为1320℃、焙烧时间为20min时,球团矿抗压强度达2439N/个,其显微结构较松散,并存在少量细小裂纹;当赤铁矿球团中添加20%(质量分数,下同)的秘鲁磁铁矿,在焙烧温度为1300℃、焙烧时间为20min时,球团矿抗压强度达3045N/个,其显微结构致密,Fe2O3晶体互连性较好.这表明在制备氧化球团矿时,添加磁铁矿降低了球团焙烧温度,改善了球团矿的显微结构,提高了抗压强度.     

矿粉粒度及反应温度对高磷鲕状赤铁矿制备碳化铁的影响

为探索利用高磷鲕状赤铁矿作为炼钢原料的新途径,在CH4-H2气氛下对高磷鲕状赤铁矿制备碳化铁进行了实验研究,探讨了矿粉粒度对还原和碳化的影响。采用热重法、SEM-EDS和XRD分别对实验中试样还原失重过程、高磷鲕状赤铁矿矿相和碳化产物进行了分析。实验得到120~160目粒度矿粉的反应活化能最低,还原反应活化能为44.95kJ/mol,碳化阶段表观活化能为9.71kJ/mol。从反应速率的角度,利用高磷鲕状赤铁矿制备碳化铁的最佳温度为1 023K,矿粉的最佳粒度为120~160目,总体来讲,温度比矿粉粒度对高磷鲕状赤铁矿制备碳化铁反应速率的影响大。     

Hematite thin films: growth and characterization

We have grown hematite (α–Fe ₂ O ₃) thin films on stainless steel and (001)-silicon single-crystal substrates by RF magnetron sputtering process in argon atmosphere at substrate temperatures from 400 to 800°C. Conversion Electron Mössbauer (CEM) spectra of the sample grown on stainless steel at 400°C exhibit values for hyperfine parameter characteristic of bulk hematite phase in the weak ferromagnetic state. Also, the relative line intensity ratio suggests that the magnetization vector of the polycrystalline film is aligned preferentially parallel to the surface. The X-ray diffraction (XRD) pattern of the polycrystalline thin film grown on steel substrates also corresponds to α–Fe ₂ O ₃. The samples were also analyzed by Atomic Force Microscopy (AFM), those grown on stainless steel reveal a morphology consisting of columnar grains with random orientation, given the inhomogeneity of the substrate surface.     

Mössbauer spectroscopy study of mechanically alloyed Fe2O3–(Al, Co and WC) systems

Mössbauer spectroscopy revealed that a central hyperfine interaction doublet and an additional sextet characterized the appearance of new phases in the mechanically alloyed Fe₂O₃–Al and Fe₂O₃–Co systems. In the Fe₂O₃–Al system, the intensity of the central super paramagnetic doublet which represents small particles of iron, increased with increasing milling time from 5 to 30 h of mechanical alloying. The magnetic sextet characterizing hematite vanished in the room temperature Mössbauer spectra of samples produced after 25 h of mechanically alloying the 50% Fe₂O₃ and 50% Al system. In general XRD peak broadening was observed as a result of extensive material structural distortion and formation of small particles. Fe, Al₂O₃ and mixed iron–aluminium oxide phases were identified in the XRD patterns with a small persistence of the iron oxide up to 20 h of mechanically alloying the 1:1 system Al–Fe₂O₃. In the 50% Co–50% Fe₂O₃ system, a 55% abundant new phase CoFe₂O₄ was observed, from the Mössbauer spectra of the system. The presence of this new phase was confirmed by the XRD analysis. The high energy ball milling of WC–Fe₂O₃ revealed a more effective grinding compared to hematite alone. The hematite particles were reduced to nanosized particles.     

脉动高梯度磁选中冲程冲次对选矿指标的影响

本文介绍了周期式脉动高梯度磁选机的工作原理,从理论上分析了冲程冲次对脉动高梯度磁选指标的影响,用黑钨矿和赤铁矿进行了验证试验,证实了脉动对消除脉石的机械夹杂和提高磁性精矿品位有重要作用。通过理论分析和试验研究,提出了脉动高梯度磁选的捕集图。     

添加离子对α—Fe2O3气敏性能影响的研究

本文通过对各种添加微量金属离子的α-FeOOH脱水转变为α-Fe_2O_3的热力学数据及其粒子形貌和其相应材料制备成气敏元件的性能研究,对添加离子于α-FeOOH粒子生成的影响以及脱水后相应α-Fe_2O_3气敏性能影响的原因进行了讨论。并且,根据对添加不同量Sn~(4+)的α-Fe_2O_3样品进行穆斯堡尔谱的测定,讨论了添加离子对α-Fe_2O_3气敏性能影响的机理。     

椭球形α—Fe2O3微粒子合成研究

研究了利用Fe(NO_3)_3水溶液强迫水解制备均匀椭球形α-Fe_2O_3微粒子的多种影响因素,比较了密闭的静态环境和沸腾回流的动态开放环境下的水解反应。实验发现加入微量NaH_2PO_4后,Fe(NO_3)_3在较高起始浓度(0.2M)和较短水解时间内(5h～7h)可制备颗粒完整、尺寸比较均匀的椭球形α—Fe_2O_3微粒子。这为用新方法生产NP磁粉作了有意义的尝试。还对反应机理作了探讨。