首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2516篇
  免费   200篇
  国内免费   179篇
化学   332篇
晶体学   20篇
力学   87篇
综合类   23篇
数学   352篇
物理学   466篇
综合类   1615篇
  2024年   10篇
  2023年   18篇
  2022年   33篇
  2021年   53篇
  2020年   44篇
  2019年   37篇
  2018年   54篇
  2017年   53篇
  2016年   52篇
  2015年   60篇
  2014年   166篇
  2013年   121篇
  2012年   143篇
  2011年   160篇
  2010年   143篇
  2009年   141篇
  2008年   132篇
  2007年   169篇
  2006年   127篇
  2005年   132篇
  2004年   131篇
  2003年   113篇
  2002年   137篇
  2001年   115篇
  2000年   90篇
  1999年   76篇
  1998年   55篇
  1997年   43篇
  1996年   51篇
  1995年   35篇
  1994年   39篇
  1993年   32篇
  1992年   26篇
  1991年   24篇
  1990年   26篇
  1989年   13篇
  1988年   14篇
  1987年   9篇
  1986年   8篇
  1985年   1篇
  1984年   3篇
  1982年   2篇
  1979年   1篇
  1978年   1篇
  1974年   2篇
排序方式: 共有2895条查询结果,搜索用时 15 毫秒
101.
研究了每一补货间隔内需求为服从某一概率分布的随机变量的各零售商集体和一个地区分销中心组成的地区分销系统.分销系统中各零售商可独立决定自身的最优补到水平,补货周期是确定值;分销中心巡回给各零售商送货,循环周期是固定的,且各零售商的补货周期等于分销中心送货循环周期.针对在补货间隔内零售商需求为某一区间内的均匀分布和某一泊松分布两种情况,假定零售商的顾客需求是均匀发生的,给出了零售商补到水平最优控制策略和分销中心库存控制策略.最后通过一个算例验证了模型的有效性.  相似文献   
102.
《Physics letters. A》2020,384(32):126832
We propose a novel method for detection of the faint machinery vibration at the nanometer resolution based on the spin magnetic resonant effect. A suspension magnet acts as a vibration sensor to transfer the vibration signals as the magnetic field fluctuation to excite the spin magnetic resonance. Due to the high sensitivity of the magnetic field of the nitrogen-vacancy center in diamond, the theoretical detection limit of mechanical vibration is as high as 5.7 nm, and the actual measurement resolution reached 12.8 nm, and proved the potential for further improvement to ∼pm resolution. The feasibility of this method is verified by dynamic tests. This method provides a novel approach for the detection of micro-mechanical vibrations.  相似文献   
103.
Conventional biomechanical analyses of human movement have been generally derived from linear mathematics. While these methods can be useful in many situations, they fail to describe the behavior of the human body systems that are predominately nonlinear. For this reason, nonlinear analyses have become more prevalent in recent literature. These analytical techniques are typically investigated using concepts related to variability, stability, complexity, and adaptability. This review aims to investigate the application of nonlinear metrics to assess postural stability. A systematic review was conducted of papers published from 2009 to 2019. Databases searched were PubMed, Google Scholar, Science-Direct and EBSCO. The main inclusion consisted of: Sample entropy, fractal dimension, Lyapunov exponent used as nonlinear measures, and assessment of the variability of the center of pressure during standing using force plate. Following screening, 43 articles out of the initial 1100 were reviewed including 33 articles on sample entropy, 10 articles on fractal dimension, and 4 papers on the Lyapunov exponent. This systematic study shows the reductions in postural regularity related to aging and the disease or injures in the adaptive capabilities of the movement system and how the predictability changes with different task constraints.  相似文献   
104.
By using the methods of Picard-Fuchs equation and Riccati equation, we study the upper bound of the number of zeros for Abelian integrals in a kind of quadratic reversible centers of genus one under polynomial perturbations of degree $n$. We obtain that the upper bound is $7[(n-3)/2]+5$ when $n\ge 5$, $8$ when $n=4$, $5$ when $n=3$, $4$ when $n=2$, and $0$ when $n=1$ or $n=0$, which linearly depends on $n$.  相似文献   
105.
数字图像处理技术对影响投篮命中相关因素的分析   总被引:1,自引:1,他引:0  
以基础力学理论对篮球飞行轨迹进行运算和分析,近年来专业体育科研机构也开始利用该方法对体育运动项目进行辅助分析。文章利用数字图像处理的基本技术,对影响篮球投篮命中率的相关因素进行研究,实验结果表明对提高运动技术水平具有一定的参考意义。  相似文献   
106.
李秀梅  王庆伟  李丹  赵霞  高广刚 《结构化学》2007,26(11):1341-1344
A new one-dimensional copper coordination polymer chain has been prepared and fully characterized by single-crystal X-ray diffraction,elemental analyses and IR spectroscopy. The compound {[Cu2(C2O4)2(inta)4](inta)}n1 crystallizes in the triclinic system,space group P1,with a=8.4722(5),b=10.9825(6),c=11.6128(6),α=104.8050(10),β=102.5740(10),γ= 109.6890(10)o,V=927.18(9)3,Mr=929.79,Z=1,Dc=1.665 g/cm3,F(000)=475,μ=1.231 mm-1,R=0.0453 and wR=0.1185 for 3290 observed reflections (I > 2σ(I)). Of the compound,the Cu center is octahedrally coordinated with oxalate acting as a tetra-dentate ligand coordinated to the copper atom and each inta serving as a terminal ligand by employing only one N-donor to coordinate with the Cu center. An infinite {Cu2(C2O4)2}∞ chain is formed along the c axis. Furthermore,the 1D chains are held together via extensive hydrogen-bonding interactions to generate a three-dimensional network with 1D channels (ca. 5.491×11.507) where inta molecules are filled.  相似文献   
107.
Four kinds of AliBu_2OB' with different R' were synthesized. The effect of AliBu_2OR'/AliBu_3 mole ratio on the conversion, the [η] of copolymer and catalytic efficiency were studied. The conversion was increased obviously and the catalytic efficiency was 2.7 times higher than before. The effect of the amount of AliBu_2OR' on the valence state of vanadium ion and the change of the valence state of vanadium ion with reaction temperature and time were studied. The VIS and IR spectra of the trinary-component catalyst system were measured. The model of active center including AliBu_2OR' was proposed. The function of AliBu_2OB was explained.  相似文献   
108.
The number of active centers (C_p)-t and k_p-t profiles of Solvay type TiCl_3 - AlR_3 (R=C_2H_5, i-C_4H_9) or Stauffer AA TiCl_3-Al (C_2H_5)_3 catalyzed 1-octene polymerization were determined by using an acetyl chloride quenching method as well as kinetic data. The results show that in the studied systems k_p decreases when C_p increases, indicating the presence of two or more types of different active centers. The C_(p~(-t)) plots of the Solvay TiCl_3-AlR_3 systems show the presence of both stable active centers and unstable centers which decay in the polymerization process. The phenomena are explained based on a model of active center plurality. The increases of C_p in the induction periods are also discussed.  相似文献   
109.
Construction of the polyaryl quaternary unit through a ZnBr2 catalyzed tandem coupling/semipinacol rearrangement participated by allylic cations was reported for the first time.  相似文献   
110.
使用大规模自旋极化密度泛函理论计算研究了表面修饰和尺寸对金刚石纳米线(DNs)中氮空位(NV)色心的几何结构、 电子结构、 磁性和稳定性的影响. 理论上设计了几种不同的DNs, 这些DNs具有不同的表面修饰(干净、 氢化和氟化), 并且直径达数百个原子. 实验结果证明, 中性(NV0)和带1个负电荷(NV-)的NV色心的电子结构不受半导体表面修饰和DNs直径大小的影响, 但NV色心的稳定性对这两个因素具有不同的响应. 此外, 研究中还发现, 由于DNs中存在圆柱形表面电偶极子层, 对DNs中掺杂的NV-色心的稳定性, 表面改性诱导了不依赖尺寸的长程效应. 特别地, 对于n型氟化金刚石表面, 掺杂在DN中的NV-色心可以稳定存在, 而对于p型氢化表面, NV0则相对更稳定. 因此, 表面修饰为控制金刚石纳米线中的NV色心的电子结构和稳定性提供了一种精确有效的调控方法.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号