全文获取类型
收费全文 | 3769篇 |
免费 | 352篇 |
国内免费 | 450篇 |
专业分类
化学 | 1151篇 |
晶体学 | 17篇 |
力学 | 55篇 |
综合类 | 22篇 |
数学 | 123篇 |
物理学 | 2016篇 |
综合类 | 1187篇 |
出版年
2024年 | 11篇 |
2023年 | 49篇 |
2022年 | 104篇 |
2021年 | 108篇 |
2020年 | 110篇 |
2019年 | 105篇 |
2018年 | 101篇 |
2017年 | 114篇 |
2016年 | 120篇 |
2015年 | 109篇 |
2014年 | 133篇 |
2013年 | 270篇 |
2012年 | 154篇 |
2011年 | 185篇 |
2010年 | 114篇 |
2009年 | 173篇 |
2008年 | 187篇 |
2007年 | 197篇 |
2006年 | 229篇 |
2005年 | 189篇 |
2004年 | 154篇 |
2003年 | 164篇 |
2002年 | 209篇 |
2001年 | 201篇 |
2000年 | 182篇 |
1999年 | 147篇 |
1998年 | 94篇 |
1997年 | 97篇 |
1996年 | 74篇 |
1995年 | 88篇 |
1994年 | 69篇 |
1993年 | 41篇 |
1992年 | 49篇 |
1991年 | 42篇 |
1990年 | 33篇 |
1989年 | 29篇 |
1988年 | 17篇 |
1987年 | 13篇 |
1986年 | 10篇 |
1985年 | 16篇 |
1984年 | 15篇 |
1983年 | 6篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1979年 | 6篇 |
1978年 | 8篇 |
1977年 | 6篇 |
1976年 | 9篇 |
1975年 | 5篇 |
1973年 | 3篇 |
排序方式: 共有4571条查询结果,搜索用时 710 毫秒
81.
82.
83.
84.
On Chalcogenolates. 206. N-Thioacetyl Dithiocarbamates and Esters of N-Thioacetyl Dithiocarbamic Acid Thioacetamide reacts with carbon disulfide in the presence of KH to form via the tetrabutyl ammonium salt dark yellow N-thioacetyl dithiocarbamates M[S2C? NH? CS? CH3], where M = K, Rb, Cs. The salts as well as the methyl and ethyl ester have been characterized by means of electron absorption, infrared, nuclear magnetic resonance (1H and 13C), and mass spectra. Attempts to synthesize N-thioacetyl dithiocarbamic acid were not successful. 相似文献
85.
Kozyr AV Kolesnikov AV Aleksandrova ES Sashchenko LP Gnuchev NV Favorov PV Kotelnikov MA Iakhnina EI Astsaturov IA Prokaeva TB Alekberova ZS Suchkov SV Gabibov AG 《Applied biochemistry and biotechnology》1998,75(1):45-61
DNA-hydrolyzing activity of IgG autoantibodies from sera of patients with various types of lymphoproliferative diseases was
investigated. The association of DNA-hydrolyzing activity with the antibody (Ab) fraction has been proved by newly developed
affinity-capture assay. Study of abzyme incidence in blood tumors and systemic lupus erythematosis (SLE) revealed linkage
of anti-DNA Ab catalysts to mature B-cell tumors, and increased probability of DNA-abzymes formation on the background of
autoimmune manifestations. These data suggest possible similarity between mechanisms of abzyme formation in SLE and B-cell
lymphomas. A new mechanism of formation of DNA-specific catalytic Abs has been proposed based on the increased crossreactivity
of polyclonal DNA-abzymes to DNA-depleted nuclear matrix proteins. The possibility of the abzyme production as Ab to the energetically
destabilized ground state of the antigen has been discussed. Preliminary results were obtained that indicate the complement-independent
cytotoxicity of anti-DNA autoantibodies isolated from blood of patients with SLE and chronic lymphocytic leukemia. 相似文献
86.
Nitrogen ion implantation (24 keV, 4.6 × 1017 cm?2) into (100) a p‐type silicon wafer material and a subsequent electron beam annealing at 1100 °C for 15 s under high vacuum conditions leads to the formation of an uneven surface in the implanted region caused by nitrogen bubbles beneath the surface. Annealing at 1200 °C for 300 s results in surface cavities with a mean diameter of 350 nm and a surface coverage of 3–4% and an average depth of ~60 nm. Nuclear reaction analysis reveals that the nitrogen concentration in the as‐implanted state exceeds 57 at%, the value of stoichiometric Si3N4. Annealing at 1100 °C for 15 s slightly reduces the nitrogen peak concentration, whereas annealing at 1200 °C for 300 s induces a significant alteration to the shape of the nitrogen depth profile coupled with the lowering of the concentration close to the stoichiometry of Si3N4. The results present a new method of producing sub‐micrometre cavities embedded in a thin silicon nitride film on wafer silicon which may lead to novel micro‐electronic and biotechnology applications. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
87.
Accurate lower and upper bounds for the nonrelativistic lowest energies1
E
0 and3
E
0 of the singlet and triplet-system of the4He-Isotop are calculated with the linearized method of variance minimization. The same was done for1
E
1 the energy of the first excitedS-state 21
S.
The results especially for1
E
0 and3
E
0 in a.u. are −2.90330769975 ≤1
E
0 ≤ −2.90330769218 −2.17493242637 ≤3
E
0 ≤ −2.17493242459 i.e. the values are determined with an absolute error smaller than 0.00167 cm−1 for1
E
0 and 0.00039 cm−1 for3
E
0. 相似文献
88.
Kin-Ho Law Pui-Ling Chan Wai-Sum Lau Yin-Chung Cheng Yun-Chung Leung Wai-Hung Lo Hugh Lawford Hoi-Fu Yu 《Applied biochemistry and biotechnology》2004,114(1-3):361-372
Plastic wastes constitute a worldwide environmental problem, and the demand for biodegradable plastics has become high. One
of the most important characteristics of microbial polyesters is that they are thermoplastic with environmentally degradable
properties. In this study, pUC 19/PHA was cloned and transformed into three different Escherichia coli strains. Among the three strains that were successfully expressed in the production of polyhydroxyalkanoates (PHA), E. coli HMS174 had the highest yield in the production of poly-(3-hydroxybutyrate-co-3-hydroxyvalerate) (P[HB-HV]). The cell dry
weight and PHA content of recombinant HMS174 reached as high as 10.27 g/L and 43% (w/w), respectively, in fed-batch fermentor
culture. The copolymer of PHA, P(HB-HV), was found in the cells, and the biopolymers accumulated were identified and analyzed
by gas chromatography, proton nuclear magnetic resonance spectroscopy, and differential scanning calorimetry. We demonstrated
clearly that the E. coli host for PHA production has to be carefully selected to obtain a high yield. The results obtained indicated that a superior
E. coli with high PHA production can be constructed with a desirable ratio of P(HB-HV), which has potential applications in industry
and medicine. 相似文献
89.
A novel transesterification reaction between acetylated maritime pine sapwood (Pinus pinaster Soland) and methyl benzoate (MB), in the presence of dibutyltin oxide (DBTO) as a catalyst, was performed. Reaction was confirmed by Fourier-transform infrared spectroscopy (FTIR) and 13C nuclear magnetic resonance cross-polarisation with magic-angle spinning (NMR CP MAS) analysis: signals corresponding to benzoylated wood were identified and, when transesterification was performed with ethyl trimethylsilylacetate (ETMSA), characteristic trimethylsilyl groups were detected. The acetyl/benzoyl exchange rate was found to increase with increasing amount of DBTO, temperature and reaction time and a concurrent deterioration of the woody material was evidenced. 相似文献
90.
G. G. Kasparov 《K-Theory》1991,5(1):47-49
We provide a straightforward proof of one of the main results of the Baum-Douglas K-homology theory: If A is a separable nuclear C
*-algebra and I an ideal of A, then the natural restriction map K
0(A, I) K
0(I) is an isomorphism of Abelian groups. 相似文献