火力发电厂汽机房屋盖结构选型分析

本文对汽机房屋盖结构的两种受力体系进行了技术经济比较,阐述了空间网架在我国的应用情况,介绍了平板型网架应用在火力发电厂汽机房屋盖中的可行性及经济性。根据工业厂房建筑中的传力路线,分析了用于汽机房屋盖结构的平板型网架考虑吊车水平刹车力作用时的内力分布特点及其应用,提出了汽机房屋盖结构使用平板型网架的观点     

非平稳正态过程水平上穿过的期望次数

设｛Ｘ（ｔ）,０≤ｔ≤Ｔ｝是标准正态过程且以概率１有连续的样本函数。探讨了对于水平ｎ〉０过程中穿过的期望次数,给出了几个涉及相关函数的条件。     

关于Scott拓扑的core紧性

ＤＣＰＯ Ｌ被称作Σ－ｃｏｒｅ紧的,如果当Ｌ赋以Ｓｃｏｔｔ拓扑后是一个ｃｏｒｅ紧空间,长期以来,从序结构的角度刻划那些Σ－ｃｏｒｅ紧的ＤＣＰＯ一直是悬而未解的问题。在一定的限制条件下讨论上述问题,并得到了一些结果。     

Modeling of the relationship between electroosmotic flow and separation parameters in capillary zone electrophoresis using artificial neural networks and experimental design

The prediction of migration time of electroosmotic flow (EOF) marker was achieved by applying artificial neural networks (ANN) model based on principal component analysis (PCA) and standard normal distribution simulation to the input variables. The voltage of performance, the temperature in the capillary, the pH and the ionic strength of background electrolytes (BGE) were applied as the input variables to ANN. The range of the performance voltage studied was from 15 to 27 kV, and that of the temperature in the capillary was from 20 to 30 °C. For the pH values studied, the range was from 5.15 to 8.04. The range of the ionic strength investigated in this paper was from 0.040 to 0.097. The prediction abilities of ANN with different pre-processing procedure to the input variables were compared. Under the same performance conditions, the average prediction error of the migration time of the EOF marker was 5.46% with RSD = 1.76% according to 10 parallel runs of the optimized ANN structure by the proposed approach, and that of the 10 parallel predictions of the optimal ANN structure for the different performance conditions was 12.95% with RSD = 2.29% according to the proposed approach. The study showed that the proposed method could give better predicted results than other approaches discussed.     

The relationship between the linear (oscillatory) and nonlinear (steady-state) flow properties of a series of polymer and colloidal systems

The Cox-Merz empirical relationship between the linear (oscillatory) and nonlinear (steady-state) viscosities has been shown to be valid for many polymeric systems. Here, we present an equivalent expression to relate the linear (G) and nonlinear (N ₁) elastic properties of viscoelastic systems. Like the Cox-Merz relationship, it uses a combination of elastic and viscous parameters. The modified form of the storage modulus is then equivalent to the Cox-Merz complex viscosity. It can be used to correlate with (half) the normal force at numerically equal circular frequency and shear rate, respectively.This new expression and the Cox-Merz rule are tested for a range of polymeric and colloidal systems. It is found that both expression work for the polymeric systems considered, but fail for the colloidal systems. In the latter, the steady state values of viscosity and elasticity are consistently low, and replacing them by the complex viscosity and our new elastic expression only makes matters worse.For polymer systems, we suggest this is a general but not universal observation, since we are aware of exceptions to the rule that polymeric systems obey the Cox-Merz rule for viscosity and our rule for elasticity. For colloidal systems we find that neither rule is obeyed for any of our systems.     

Resolution of (+/-)-ibuprofen using (-)-brucine as a chiral selector by thin layer chromatography

The enantiomeric resolution of (+/-)-ibuprofen into its enantiomers was achieved by TLC on silica gel plate using optically pure (-)-brucine as a chiral selector and acetonitrile-methanol (5:1, v/v) as the solvent system. Spots were located in an iodine chamber. The detection limit was 4.9 microg. The effect of concentration of the chiral selector, temperature and pH on resolution has been studied.     

Vibrational spectra of 2-biphenylmethanol. Spectrum simulation and molecular structure

The vibrational spectra of a solid crystalline sample of 2-biphenylmethanol have been measured at room temperature. The IR absorption spectra were recorded in the range 400 cm^–1–3600 cm^–1; Raman spectra were measured in the range 10 cm^–1–1640 cm^–1. The direct mechanical and optoelectronic problems were solved using the fragment method realized as Lev-100 software; the intensity distribution in the IR spectrum of 2-biphenylmethanol was obtained by the same method. The experimental Raman and IR absorption spectra were interpreted by analyzing the calculated data on the frequencies and forms of normal vibrations and their intensities in the IR spectra. IR absorption spectra were simulated for several models of 2-biphenylmethanol conformers that differ in the mutual orientation of fragments. Based on the results of simulation and comparison of the calculated and experimental spectra of conformers we suggested a model for the conformer realized in the solid phase under normal conditions.Original Russian Text Copyright © 2004 by L. M. Babkov, J. Baran, N. A. Davydova, J. I. Kukielskii, and S. V. TrukhachevTranslated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 4, pp. 624–631, July–August, 2004.This revised version was published online in April 2005 with a corrected cover date.     

A class of multiple shrinkage estimators

Based on a sample of size n, we investigate a class of estimators of the mean of a p-variate normal distribution with independent components having unknown covariance. This class includes the James-Stein estimator and Lindley's estimator as special cases and was proposed by Stein. The mean squares error improves on that of the sample mean for p3. Simple approximations imations for this improvement are given for large n or p. Lindley's estimator improves on that of James and Stein if either n is large, and the coefficient of variation of is less than a certain increasing function of p, or if p is large. An adaptive estimator is given which for large samples always performs at least as well as these two estimators.     

The effect of a coriolis force on Taylor-Couette flow

Taylor-Couette flow subject to a Coriolis force is studied experimentally and numerically. In the experiment, the Couette apparatus is mounted on a turntable with the axis of the cylinders orthogonal to the rotation vector of the turntable. The Coriolis force stabilizes the fluid against the onset of Taylor vortices and alters the velocity fields, both above and below the transition from the initial flow. At small dimensionless turntable frequencies, the transition yields time-independent Taylor vortices which are tilted with respect to the cylinder axis. At larger there is a direct transition to turbulence. We determine the first-order correction to the classical Couette initial flow, to account for the effects of the Coriolis force, by expanding in powers of. We present numerical results for the axial velocity (the only nonvanishing correction term to order) in the infinite-cylinder approximation.