Novel hybrids of Cu2+ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline（or bipyridine） intercalated in Mg/Al-NO3-layered double hydroxide

Four Cu²⁺ complexes of salicylidene-amino acid Schiff base with 1,10-phenanthroline（Phen） or 2,2’- bipyridine（Bipy） were successfully intercalated in interlayer galleries of Mg/Al-NO₃-layered double hydroxide（LDH） by the swelling-restored method.The hybrids were characterized by elemental analysis,X-ray diffraction,FT-IR spectra,UV-vis DRS,TG-DTA and SEM observation.Good protection of the complexes by LDH in neutral and weak acidic solutions was revealed by UV spectra,cyclic voltammograms and luminescence spectra.     

A central limit theorem in nonlinear filtering

It is shown that the probability law of a diffusion process conditioned on weakly corrupted observations is asymptotically Gaussian when properly scaled. The method of proof involves Fisher information matrices and a Cramér-Rao inequality.     

IR-Spectral Study of Self-Association Effects of 2-Aminopyridine in Solution

A comparative IR-spectral study of solute-solute hydrogen bond formation in carbon tetrachloride and chloroform solutions of 2-amino-pyridine is reported. The presence of chain-like self-associates is confirmed in contrast to the solid state where the stabilization of the cyclic dimeric structure takes place. This conclusion is suggested on the basis of the NH₂ stretching region data obtained by changing the solute concentration as well as by comparing with the corresponding data about melted and solid state 2-aminopyridine and 3-aminopyridine samples.     

Spectroscopic Investigation on the Acrolein Hydration

The progress with time of the UV and ¹H NMR spectra of an aqueous solution of acrolein shows that, contrary to assumptions of previous authors, hydracrylaldehyde is not the only reaction product: in addition to it and its hydrated form, spontaneous oxidation products are present.     

Accurate integration over atomic regions bounded by zero‐flux surfaces

The approach for the integration over a region covered by zero‐flux surface is described. This approach based on the surface triangulation technique is efficiently realized in a newly developed program TWOE . The elaborated method is tested on several atomic properties including the source function. TWOE results are compared with those produced by using well‐known existing programs. Absolute errors in computed atomic properties are shown to range usually from 10^?6 to 10^?5 au. The demonstrative examples prove that present realization has perfect convergence of atomic properties with increasing size of angular grid and allows to obtain highly accurate data even in the most difficult cases. It is believed that the developed program can be bridgehead that allows to implement atomic partitioning of any desired molecular property with high accuracy. © 2012 Wiley Periodicals, Inc.     

Effect of gap and flow orientation on two-phase flow in an oil-wet gap: Relative permeability curves and flow structures

Naturally fractured reservoirs contain about 25–30% of the world supply of oil. In these reservoirs, fractures are the dominant flow path. Therefore, a good understanding of transfer parameters such as relative permeability as well as flow regimes occurring in a fracture plays an important role in developing and improving oil production from such complex systems. However, in contrast with gas–liquid flow in a single fracture, the flow of heavy oil and water has received less attention. In this research, a Hele-Shaw apparatus was built to study the flow of water in presence of heavy oil and display different flow patterns under different flow rates and analyze the effect of fracture orientations on relative permeability curves as well as flow regimes. The phase flow rates versus phase saturation results were converted to experimental relative permeability curves. The results of the experiments demonstrate that, depending on fracture and flow orientation, there could be a significant interference between the phases flowing through the fracture. The results also reveal that both phases can flow in both continuous and discontinuous forms. The relative permeability curves show that the oil–water relative permeability not only depends on fluid saturations and flow patterns but also fracture orientation.     

浅析高校图书馆毕业季主题活动及其人文内涵——以湖南理工学院图书馆为例

分析了全国图书馆毕业季主题活动研究现状,阐述了湖南理工学院图书馆多年来的毕业季主题活动情况,探讨了毕业季主题活动背后的人文内涵。     

热轧中宽带钢凸度控制模型开发与应用

以国内某热轧带钢厂的新建项目为背景,分析了影响热轧中宽带钢凸度的主要因素,介绍了凸度预设定模型、工作辊热凸度和磨损计算模型及凸度和平直度反馈控制模型的主要功能及架构;针对典型产品的轧制过程设计了精轧机组工作辊的正弦辊形曲线.根据某产品轧制过程的工程记录数据,绘制了精轧机组的比例凸度分配曲线,结合多功能仪实测数据分析了模型的控制效果,带钢出口凸度保持在(40±20)μm的比例占带钢全长的100%,平直度为(0±10)I的比例占带钢全长的98%以上.     

The efficient in‐situ reduction and cyclization reaction of aromatic aldehyde, 1,3‐cyclopentanedione (tetronic acid), and nitro‐compound under SnCl2·2H2O‐THF medium

An efficient in‐situ reduction and cyclization reaction for the synthesis of pyrazolo[4,3‐f]quinoline, pyrazolo[3,4‐f]quinoline, and pyrazolo[3,2‐f]quinoline derivatives directly form 5‐nitroindazole, 6‐nitroindazole and 5‐nitroindole in the presence of SnCl₂·2H₂O was reported. Compared to traditional synthetic methods, this approach has the advantages of stable reagents, easy obtaining raw material, and high yields. In this research, SnCl₂·2H₂O is the efficient reducing agent for the in‐situ reduction and cyclization reaction of nitro‐compound. In addition, this process provided an alternative approach for the synthesis of target compounds.     

The inventory models under conditional trade credit in a supply chain system

In several recent investigations dealing with the economic order quantity with permissible delay in payments, the following assumptions are made: