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11.
12.
Flavonols are plant pigments that are ubiquitous in nature. Morin and other related plant flavonols have come into recent
prominence because of their usefulness as anticancer, anti-tumor, anti-AIDS, and other important therapeutic activities of
significant potency and low systemic toxicity. The heat of combustion of morin (molecular formula, C15H10O7·H2O) in oxygen was measured by a rotating-bomb type combustion calorimeter, the standard molar enthalpy of combustion of morin
at T = 298.15 K was determined to be Δc
H
m⦵ (C15H10O7·H2O, s) = −(5 937.99 ± 2.99) kJ · mol−1. The derived standard molar enthalpy of the formation of morin in solid powder state at T = 298.15 K, Δf
H
m⦵ (C15H10O7·H2O, s), was −(1 682.12 ± 3.58) kJ · mol−1, which provide an accurate data of the stability of morin to the pharmacy and pharmacology.
Biography: HOU Hanna(1956–), female, Visiting researcher, Associate professor of Hubei University of Education, research direction:
thermochemistry. 相似文献
13.
14.
A new method is described for the determination of antimony based on the cathodic adsorptive stripping of Sb(III) complexed with 2′,3,4′,5,7-pentahydroxyflavone(morin) at a static mercury drop electrode (SMDE). The reduction current of the adsorbed antimony complex was measured by 1.5th-order derivative linear-sweep adsorption voltammetry. The peak potential is at −0.51 V (vs. SCE). The effects of various parameters on the response are discussed. The optimized analytical conditions were found to be: supporting electrolyte, chloroacetic acid (0.04 mol/l, pH 2.3); concentration of morin, 5×10−6 mol/l; accumulation potential, −0.25 V (vs. SCE); scan rate, 100 mV/s. The limit of detection and the linear range were 7×10−10 mol/l and 1.0×10−93.0×10−7 mol/l Sb(III) for a 2-min accumulation time, respectively. This method has been applied to the determination of Sb(III) in steel and brass samples and satisfactory results were obtained. The adsorptive voltammetric characteristics and composition of the Sb(III)–morin complex were studied. 相似文献
15.
The study presents a new analytical method for speciation analysis in fractionation of aluminium fluoride complexes and free Al3+ in soil samples. Aluminium speciation was studied in model solutions and soil extract samples by means of high performance ion chromatography (HPIC) with UV-VIS detection using post-column reaction with tiron for the separation and detection of aluminium fluoride complex and Al3+ forms during one analysis. The paper presents particular stages of the chromatographic process optimization involving selecting the appropriate eluent strength, type of elution or concentration and quantity of derivatization reagent. HPIC was performed on a bifunctional analytical column Dionex IonPac CS5A. The use of gradient elution and the eluents A: 1 M NH4Cl and B: water acidified to pH of eluent phase, enabled full separation of fluoride aluminium forms as AlF2+, AlF30, AlF4− (first signal), AlF2+ (second signal) and form Al3+ in a single analytical procedure. The proposed new method HPIC-UVVIS was applied successfully in the quantitative and qualitative analysis of soil samples. 相似文献
16.
A model for the complete system of bioaccumulation, transport, and biotransformation of polyphenolic compounds (flavonols)
that includes hemoglobin-containing red blood cells and serum albumin was proposed. The distribution of flavonols between
the erythrocyte fraction and albumin was studied. Hemoglobin was shown to play a role in the biotransformation of flavonols.
The formation of several intermediate and final products of pseudoperoxidase oxidation of flavonols catalyzed by methemoglobin
was established by UV spectrophotometry and RP-HPLC.
Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 153-157, March-April, 2009. 相似文献
17.
18.
在pH2.1的硫酸-2.96×10-6mol/L桑色素-0.172mol/L氯酸钾底液中,钼在-0.43V(SCE)有一灵敏的极谱催化波,可用于测定微量钼.线性范围1.04×10-9~2.50×10-8mol/L,检出限1.88×10-10mol/L. 极谱催化波法直接应用于三氧化钨光谱标样中微量相的测定,方法简便,准确可靠。 相似文献
19.
We have studied the fluorescent properties of flavonols (quercetin, fisetin, morin, rutin) with the aim of studying possible
interaction with hemoglobin and bovine serum albumin (BSA). We observed an increase in the intensity of intrinsic fluorescence
for all the flavonols except rutin in the presence of BSA. From the changes in the fluorescence spectra, we concluded that
tautomeric forms are formed on interaction with hemoglobin. We determined the interconnection between the structure of related
flavonols and their fluorescent properties on interaction with proteins, and we determined the binding constants for binding
with BSA and hemoglobin.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 5, pp. 659–664, September–October, 2007. 相似文献
20.
用荧光光谱法、分光光度法研究了3种黄酮类药物(染料木素、木犀草素和桑色素)与牛血清白蛋白(BSA)的相互结合作用.实验表明染料木素、木犀草素和桑色素与牛血清白蛋白的相互结合作用均为单一的静态猝灭过程,猝灭常数Ksv为4.22×104~4.83×105 L·mol-1,在溶液中结合作用强烈(结合常数KB为1.92×103~3.23×105 mol·L-1),形成稳定的配合物,求算了给体(BSA)与受体(黄酮类药物)作用距离r(3.35~4.80 nm).首次发现药物与BSA结合作用同羟基数目直接相关:随着药物分子中羟基数目(染料木素为3、木犀草素为4、桑色素为5)的增加,猝灭荧光峰位蓝移增大,作用距离r变小,结合作用逐渐加强;猝灭常数Ksv增大,更容易形成配合物;结合常数KB增大,形成的配合物更稳定. 相似文献