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排序方式: 共有495条查询结果,搜索用时 15 毫秒
71.
Chinmay Das Muhiddin Elguweri Peijun Jiang Shuhui Kang Mauritz Kelchtermans Tom C. B. McLeish Matthew Parkinson Daniel J. Read Michael P. Redlich Pradeep P. Shirodkar Johannes M. Soulages 《大分子反应工程》2019,13(3)
The flow response of branched entangled resins is dominated by the branching topology of the constituent molecules, a property that is not directly accessible using experimental analytical tools for industrially relevant complex resins. In this paper, the controlled terpolymerization of ethylene, 1,9‐decadiene, and either hexene or octene in a continuous stirred tank reactor with a metallocene catalyst, is reported. The synthesized samples are characterized extensively with various analytical tools and their rheological properties are measured with small amplitude oscillatory shear and start‐up uniaxial extension experiments. A model is developed for the polymerization process with the mass balance during synthesis providing strong constraints on the rate constants. In silico ensembles of molecules, generated via Monte Carlo sampling, are used to reproduce the experimental results. The computer model allows us to infer the detailed branching structure of the molecules and to predict the optimum range of reactor conditions for this synthesis. 相似文献
72.
涂钼热解石墨管电热原子吸收测定痕量镓的研究 总被引:1,自引:1,他引:0
比较了不同基体改进剂 ,不同涂层对镓在热解石墨管中原子化的影响。研究了以硝酸镍为基体改进剂 ,以涂钼热解石墨管为原子化器镓的原子化机理 ,优化了各项参数 ,找到了一种测定复杂样品中痕量镓的新方法。方法特征量为 2 1 2× 1 0 -1 1 g ,检出限为 1 4× 1 0 -1 0 g ,RSD≤ 3 6 % (n =1 1 ) ,样品回收率 97 4 %~1 0 2 7%。 相似文献
73.
Electrothermal atomization of beryllium from graphite and tungsten surfaces was compared with and without the use of various chemical modifiers. Tungsten proved to be the best substrate, giving the more sensitive integrated atomic absorption signals of beryllium. Tungsten platform atomization with zirconium as a chemical modifier was used for the determination of beryllium in several NIST SRM certified reference samples, with good agreement obtained between the results found and the certified values. The precision of the measurements (at 10 μg L−1), the limit of detection (3σ), and the characteristic mass of beryllium were 2.50%, 0.009 μg L−1 and 0.42 pg, respectively. 相似文献
74.
反相液相色谱中离子抑制剂的有机调节剂作用 总被引:1,自引:0,他引:1
系统地研究了在反相液相色谱(RPLC)流动相中作为离子抑制剂的酸、碱及缓冲溶液对中性化合物保留行为的影响,着重探讨了有机酸、有机碱离子抑制剂的有机调节剂作用,定量地考察了甲醇和乙腈、甲醇和乙酸、甲醇和三乙胺、乙腈和乙酸、乙腈和三乙胺在十八烷基硅烷键合相上洗脱强度之间的关系,为RPLC中有机调节剂的洗脱强度排序提供一种评判方法.另外,讨论了乙酸和三乙胺作为有机调节剂时不同的作用机理.本实验结果对于RPLC分离方法的快速建立和准确优化都具有一定的借鉴意义. 相似文献
75.
The use of boric acid as a modifier for the determination of trace amount of indium in high purity antimony by electrothermal atomic absorption is described. It was found that the negative influence of the hydrofluoric acid, used for the digestion could not be eliminated by using stabilized temperature platform furnace (STPF) alone. Due to the high dissociation energy (D0 = 506 kJ mol−1) of indium fluoride, it is difficult to dissociate in the gas phase and hence is lost. In presence of HF (used for the dissolution of antimony), the universal Pd-Mg modifier does not work satisfactorily. Additionally, rising corrosion and reduced tube lifetime were observed when the acid digested (HF-HNO3) antimony solution was injected in to the platform. Improvement in platform life and elimination of interferences were achieved by the addition of boric acid as a chemical modifier together with ruthenium coating of the platform. Corrosive changes of the transversely heated graphite atomizer (THGA) platform surface were examined by scanning electron microscopy. The standard addition method was applied. A characteristic mass of 36 pg was obtained. The detection limit of the proposed method is around 0.04 μg g−1. The developed method was applied to the determination of indium in real samples. The data obtained by this method were in good agreement with those obtained by ICP-MS. 相似文献
76.
研究Sr与不同变质剂复合添加对4032铝合金组织及性能的影响.通过组织观察、扫描电镜观察、能谱分析和力学性能测试发现:在几种不同的变质体系中,Sr与Na盐复合变质后的组织和性能最好;Sr+其他元素复合变质的针孔率低于Sr单独变质处理的针孔率,其中以Sr+Na盐变质的针孔率最低;共晶型铝硅合金添加Sr和Na变质组织呈亚共晶状态,而经P变质后组织呈过共晶状态. 相似文献
77.
Masoud Zabet‐Moghaddam Aarif L. Shaikh Satomi Niwayama 《Journal of mass spectrometry : JMS》2012,47(12):1546-1553
Two cysteine‐specific modifiers we reported previously, N‐ethyl maleimide (NEM) and iodoacetanilide (IAA), have been applied to the labeling of cysteine residues of peptides for the purpose of examining the enhancement of ionization efficiencies in combination with matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry (MALDI TOF MS). The peak intensities of the peptides as a result of modification with these modifiers were compared with the peak intensities of peptides modified with a commercially available cysteine‐specific modifier, iodoacetamide (IA). Our experiments show significant enhancement in the peak intensities of three cysteine‐containing synthetic peptides modified with IAA compared to those modified with IA. The results showed a 4.5–6‐fold increase as a result of modification with IAA compared to modification with IA. Furthermore, it was found that IAA modification also significantly enhanced the peak intensities of many peptides of a commercially available proteins, bovine serum albumin (BSA), compared to those modified with IA. This significant enhancement helped identify a greater number of peptides of these proteins, leading to a higher sequence coverage with greater confidence scores in identification of proteins with the use of IAA. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
78.
合成了Cu/Al原子比分别为2.0、3.1、4.1的CuAl类水滑石样品,焙烧得到CuAl复合氧化物。在Cu/Al原子比为3.1的CuAl氧化物表面浸渍碱金属盐溶液,制备改性CuAl复合氧化物,用AES、XRD、FT-IR、BET、H2-TPR、XPS等技术对催化剂进行了结构表征,考察了CuAl复合氧化物组成、碱金属助剂类型和K的前驱物对改性催化剂在有氧气氛中催化分解N2O活性的影响。结果表明,Na、K、Cs改性CuAl复合氧化物均提高了催化剂活性,但K助剂的增强效应最显著;钾的不同前驱物改性CuAl复合氧化物的催化活性有显著差异,加入碳酸钾、草酸钾提高了催化剂的活性,而加入醋酸钾、硝酸钾反而降低了催化剂活性。优化出的K改性CuAl复合氧化物催化剂在含氧含水气氛的N2O分解反应中表现出了较高的活性。 相似文献
79.
80.
石墨炉原子吸收光谱法测定痕量镉的基体改进效应研究及其应用 总被引:7,自引:1,他引:6
胡勇平 《理化检验(化学分册)》2001,37(6):266-267,269
研究了磷酸氢二钾对石墨炉原子吸收光谱法测定痕量镉的基体改进效应,试验表明,在磷酸盐存在下,镉的灰化温度能显著提高,钾对镉有一定的增感效应。以此建立了用磷酸氢二钾作基体改进剂,直接测定岩石、土壤和水系沉积物中痕量镉的方法。 相似文献