首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10134篇
  免费   797篇
  国内免费   1355篇
化学   3903篇
晶体学   43篇
力学   948篇
综合类   76篇
数学   2050篇
物理学   1368篇
综合类   3898篇
  2024年   22篇
  2023年   139篇
  2022年   240篇
  2021年   267篇
  2020年   346篇
  2019年   273篇
  2018年   276篇
  2017年   304篇
  2016年   331篇
  2015年   337篇
  2014年   498篇
  2013年   614篇
  2012年   570篇
  2011年   682篇
  2010年   514篇
  2009年   618篇
  2008年   589篇
  2007年   729篇
  2006年   673篇
  2005年   615篇
  2004年   542篇
  2003年   478篇
  2002年   359篇
  2001年   321篇
  2000年   302篇
  1999年   239篇
  1998年   232篇
  1997年   185篇
  1996年   178篇
  1995年   122篇
  1994年   159篇
  1993年   101篇
  1992年   99篇
  1991年   75篇
  1990年   63篇
  1989年   58篇
  1988年   31篇
  1987年   27篇
  1986年   20篇
  1985年   17篇
  1984年   11篇
  1983年   5篇
  1982年   5篇
  1981年   2篇
  1980年   6篇
  1979年   3篇
  1978年   4篇
  1976年   2篇
  1955年   1篇
  1936年   1篇
排序方式: 共有10000条查询结果,搜索用时 12 毫秒
991.
In the present note, we investigate schemes S in which each element s satisfies ns2 and ns*s≠2. We show that such a scheme is schurian. More precisely, we show that it is isomorphic to G//t, where G is a finite group and t an involution of G weakly closed in CG(t).

Groups G with an involution t weakly closed in CG(t) have been described in Glauberman's Z*-Theorem [G. Glauberman, Central elements in core-free groups, J. Algebra 4 (1966) 403–420] with the help of the largest normal subgroup of G having odd order.  相似文献   

992.
We study the L^l-error estimates for the upwind scheme to the linear advection equations with a piecewise constant coefficients modeling linear waves crossing interfaces. Here the interface condition is immersed into the upwind scheme. We prove that, for initial data with a bounded variation, the numerical solution of the immersed interface upwind scheme converges in L^l-norm to the differential equation with the corresponding interface condition. We derive the one-halfth order L^l-error bounds with explicit coefficients following a technique used in [25]. We also use some inequalities on binomial coefficients proved in a consecutive paper [32].  相似文献   
993.
Locally-one-dimensional difference schemes for the fractional diffusion equation in multidimensional domains are considered. Stability and convergence of locally one-dimensional schemes for this equation are proved.  相似文献   
994.
采用分子生物物理学原理探讨了蛋白质的平均分子量、水化面积、极性、憎水性、柔性及电荷分布与酶作用的关系.研究表明:改性蛋白质的平均分子量与水解度成反比例关系;水化面积随水解度的增加成对数关系增大;极性与平均分子量成反比例关系;柔性与平均分子量成负指数函数关系;净电荷数在pH、温度和蛋白质浓度一定的条件下,随水解度的增加成正比例关系增大.改性蛋白质的憎水性由两部分构成,分别为肽键断裂引起憎水性的变化和构象变化引起的变化.其中肽键断裂引起憎水性变化与水解度成正比关系.总之,改性蛋白质的结构性质变化与酶作用之间存在明显的定量关系,而且结构性质的变化还与酶特异性有关.  相似文献   
995.
A combination of iridium‐catalyzed C H activation/borylation and atom transfer radical polymerization (ATRP) was used to generate polar graft copolymers of syndiotactic polystyrene (sPS). The borylation at aromatic C H bonds of sPS and subsequent oxidation of boronate ester proceeded without negatively affecting the molecular weight properties and the tacticity of sPS. A macroinitiator suitable for ATRP could be synthesized by the esterification of 2‐bromo‐2‐methylpropionyl bromide and hydroxy‐functionalized sPS. The graft polymerizations of methyl methacrylate and tert‐butyl acrylate from the macroinitiator using ATRP afforded polar block grafted sPS materials, syndiotactic polystyrene‐graft‐poly(methyl methacrylate) (sPS‐g‐PMMA) and syndiotactic polystyrene‐graft‐poly(tert‐butyl acrylate) (sPS‐g‐PtBA). The latter was hydrolyzed to yield an amphiphilic graft copolymer, syndiotactic polystyrene‐graft‐poly(acrylic acid) (sPS‐g‐PAA). The structures of the copolymers were characterized by NMR and FTIR spectroscopies. Size exclusion chromatography and 1H NMR spectroscopy were used to study any changes in the molecular weight properties from the parent polymer. A decrease in the hydrophobicity of the graft copolymers was confirmed by water contact angle measurements. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6655–6667, 2009  相似文献   
996.
A technical problem in cellulosic nanocomposite materials is the weak interaction between hydrophilic cellulose and hydrophobic polymer matrices. One approach to solve this difficulty is to chemically graft monomers of the matrix polymer onto the cellulose surface. An important question is to understand the effect such surface modification has on the interfacial properties. Semi-empirical approaches to estimate work of adhesion based on surface energies do not provide information on specific molecular interactions. Details about these interactions were obtained using molecular dynamics (MD) simulation. Cellulose interfaces with water and caprolactone medium were modeled with different amounts of grafted caprolactone. The modification lead to an increased work of adhesion between the surface and its surrounding medium. Furthermore, the MD simulations showed that the interaction between cellulose, both modified and non-modified, and surrounding medium is dominated by Coulomb interactions, predominantly as hydrogen bonds.  相似文献   
997.
In this paper numerical solutions of mixed hyperbolic problems are computed using a discrete eigenfunctions method combined with an implicit difference scheme. This new numerical technique preserves the qualitative properties of the analytic solution due to the Sturm-Liouville structure of the underlying discrete linear boundary-value problem and has computational stability advantages vs other methods. Illustrative examples are included.  相似文献   
998.
Strong convergence theorems for approximation of common fixed points of asymptoticallyφ-quasi-pseudocontractive mappings and asymptoticallyφ-strictly- pseudocontractive mappings are proved in real Banach spaces by using a new compos- ite implicit iteration scheme with errors.The results presented in this paper extend and improve the main results of Sun,Gu and Osilike published on J.Math.Anal. Appl.  相似文献   
999.
根据吕梁市岚县铁矿项目供水工程的设计要求,从取水口、输水线路、管道材料3个方面对太铜岚县项目供水工程总体方案进行了比选。  相似文献   
1000.
针对新钢烧结厂115m^2烧结机主抽同步电机存在的励磁系统故障问题,对其进行了技术改造,采取使用两套KGLF-2C型全数字同步电动机励磁装置相互备用的措施,最大限度地缩短可能发生的故障时间,提高大型电气设备的作业率。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号