Geometry,stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds

Alkaline-earth (Ae) metals have attracted a wealth of interdependent research from synthetic chemists. In Ae-catalyzed organometallic reactions, β-diketiminate is a typical ligand used to stabilize Ae catalysts by forming six-membered rings comprising Ae metals. Herein, studies focusing on the configuration of β-diketiminate-coordinated Ae compounds observed that the CC and CN bonds are homogeneous and unchanged. Furthermore, energetic studies observed that the formation of the Ae-incorporated six-membered rings results in enhanced stability of >20 kcal/mol. The nucleus-independent chemical shifts, anisotropy of the induced current density, and molecular orbital analyses demonstrated the non-aromaticity of the β-diketiminate-coordinated Ae compounds. The improved stability of these compounds can be explained by the delocalization of the π electrons derived from the β-diketiminate moiety.     

2022年中国重大科学、技术和工程进展

本着分门别类、本刊推荐、专家遴选、宁缺毋滥、叙述事实的原则,从国内外著名科技期刊和科技新闻媒体所报道的中国科技成果中,按科学、技术、工程3个类别,由《科技导报》编辑部遴选、推荐候选条目,经《科技导报》编委、审稿人等专家通信评选,推选出2022年中国重大科学、技术和工程进展30项。（1）2022年中国重大科学进展10项：探测到重复快速射电暴密近环境的动态演化;解析新冠病毒突变株奥密克戎免疫逃逸的分子机制;发现黏附类GPCR识别和激活新机制;实现世界纪录效率的全钙钛矿叠层太阳能电池制备新途径;测定超高热导率半导体砷化硼载流子迁移率;发现促使胆固醇排出体外的降脂新方法;揭示火星乌托邦平原浅表精细结构和物性特征;发现志留纪化石库为解答有颌脊椎动物起源提供确凿证据;实现光催化剂光生电荷转移过程的全时空成像;开创海水原位电解制氢新原理与新方法。（2）2022年中国重大技术进展10项：在高温超导体中诱导出奇异金属态;实现超快激光三维极端制造重大突破;实现三原子分子的量子相干合成;建立蛋白质从头设计新方法;制备出亚1 nm栅极长度的晶体管;发现并编辑KRN2基因可同时提高水稻玉米产量;提出全新诱导人多...     

Observational study of the circulation in the southern South China Sea

CTD data from two oceanographic survey cruises, conducted by “Shiyan No. 3” R/V during two reversing monsoons, were employed to calculate and analyze the distributions of temperature, salinity and geopotential anomaly in the southern South China Sea (SSCS). Based on these distributions, the horizontal structures of the SSCS circulation are described systematically. Study results show that the SSCS circulation structure could be classified as a two-layer (the upper and the lower) pattern, and that the main circulation in the upper layer (0–400 m) is driven by the South China Sea monsoons and is opposite in direction to the reversal of the monsoons. The distributions of principal current systems and their features are presented. Two important local phenomena, local eddy and oceanic front, were observed.     

南海夏季风活动激发的大气遥相关型

北半球夏季,南海地区是全球大气热状况变化最为激烈的区域之一,而南海夏季风则是该地区最为活跃的天气事件,它的演变必将导致其它地区大气环流的响应．通过相关计算、合成分析等手段,揭示与南海夏季风活动相关联的北半球大气遥相关型的存在．该波列状的遥相关型与东亚地区相连,经北太平洋延伸至北美西岸．最高的相关位于西太平洋副热带高压区域,因而它可能对我国旱涝天气产生重要影响．     

一个中国湿地植物资源分类系统

提出了一个中国湿地植物资源分类系统,并将我国湿地植物资源分为３大类２４小类,这个系统根据湿地植物用途建立系统框架,将植物群落的建群种,分布广的植物,生物量大的植物,湿地特有植物和与水禽,野生动物栖息地,繁殖地,隐蔽地相关的植物作为选择资源植物类别的标准。     

贺兰山苔藓植物物种多样性,生物量及生态学作用的研究

研究了贺兰山不同海拔高度主要林型种苔藓植物物种多样性,生物量和生态学作用,结果表明,云杉林下藓类地层的生物量最高,９１４７．７ｋｇ／ｈｍ＾２,是林灌木和草本植物总生物量的９．２倍,在饱和吸水状态下,可贮存水２０１７４．５ｋｇ／ｈｍ＾２,通过随机取样按海拔高度,林型和土壤类型等梯度对贺兰苔藓植物被进行了调查,影响苔藓植物生长和分布的主要生态因子是光照,相对湿度,海拔高度和土壤ｐＨ对出现在群落中包拓苔     

CLIMATIC CHANGE SINCE LITTLE ICE AGE RECORDED BY DUNDE ICE CAP

The climatic change since the Little Ice Age recorded in the Dunde Ice Cap is presentedin this paper. There have been three cold periods and three warm periods since 1400AD.Among them, the coldest one was in the 17th century. Many evidences verified the three coldand warm variations recorded in the Dundc Ice Cap. But it was found from the comparison between the Dunde Icc Cap climatic record and thewinter temperature record in Shanghai that there was a temporal dfference in climatic changebetween East China and West China. The general trend is that the cooling and warmingprocesses in West China were earlier than that in East China. In the Dunde Ice Cap, it isnow in an anomalous warm period, while it is not as warm as in Dunde Ice Cap recordaccording to the winter temperature in Shanghai. In addition to the possible cause of temporaldifference in climatic change between West China and East China, another possible cause isthat the greenhouse effect of CO_2 may already be recognizable in the Dunde Ice Cap a     

NMR determination of absolute site-specific natural isotope ratios of hydrogen in organic molecules. Analytical and mechanistic applications

It has been shown that the “internal” isotope distribution within a given molecular species at the natural abundance level is accessible by a new method, SNIF-NMR, which is based on deuterium NMR. Relative internal factors, R_i/j,have been defined which enable the isotope content of a given site, i, to be compared to that of another molecular site, j, taken as the reference. Several referencing methods intended to provide direct access to relative $\text{externals}$, T_i , and $\text{absolute}$, (D/H)_i , site-specific parameters, are now discussed from both the theoretical and the experimental points of view. In the $\text{intramolecular referencing method}$, which involves a time-consuming chemical transformation of the sample, the risk exists of more or leas systematic errors resulting from discriminating fractionation effects. However this technique offers, conversely, an interesting way of investigating kinetic isotope effects without the need for specific labelling. In spite of its lower spectral precision the $\text{external referencing method}$ has the advantage of being fast and less sensitive to systematic errois and may be used for direct rough routine determinations of the site-specific isotope contents. More precise results can be obtained, at the price of contaminating the sample, when an $\text{intermolecular reference}$ is added and signal heights are used, remembering however that the intensity parameters then have no strict physical meaning in terms of absolute isotope contents. The site-specific parameters, T_i and (D/H)_i thus accessible, provide new information on the mechanisms of the fractionation effects occurring in natural conditions and examples are considered.     

光度分析

本文是《分析试验室》定期评述中“光度分析”的第六篇文章，评述了１９９４．７～１９９６．６期间我国光度分析的概况，内容包括：学术会议，专著，标准，综述，新试业色体系，动力学光度法，萃取，浮选和离心光度法，双波长光度法，其他新光度法，以及这两年我国学者在国际杂志上发表的有关光度分析论文目录，引用文献１３７１篇。