矿山排水泵站微机通信测控系统

针对目前平庄矿务局元宝山露 天矿的实际情况,利用ＭＣＳ－９６系列单片机成了矿山排水泵站微机通信测控系统。该系统由调度端和终端站组成,调度端与终端站之间的信息伟递采用无线通讯方式。且具有多机通信功能,故系统具有高可靠性和高性能价格比。     

水文自动测报系统的体系结构研究

研究了水文自动测报系统的层次和借分和网络互连。在此基础上,仿照“物理构成”和“逻辑构成”分开的原则,建立了多媒体通信网络的水文自动测报系统的“逻辑构成”体系结构。即多媒体通信网络化的水文自动测报系统的体系结构参考模式,简称ＨＤＡＳ－ＲＭ。     

多媒体通信是信息时代的一大技术特征

本文就几年来从事图象与多媒体通信技术研究开发的经历,首先回顾了近二十年来信息技术的进程及不同阶段发展的主要标志,从信息化社会开始进入多媒体时代的高度比较规范和系统地介绍了多媒体及多媒体通信概念、关键技术及其发展动态和社会应用前景。其中涉及从事国家高科技规划＂８６３＂项目研究及其主要成果的内容概括,企图对读者系统了解多媒体通信及其时代意义有所帮助。     

A refined physico-chemical model of solute retention in reversed-phase high-performance liquid chromatography with ternary mobile phases

Summary In our previous publication we have introduced a new model of solute retention in RP-HPLC systems with ternary mobile phases of the B+AB₁+AB₂ type (B: acetonitrile or tetrahydrofuran; AB₁: methanol; AB₂: water). That model proposed no stoichiometric differentiation between acetonitrile and tetrahydrofuran, alternatively present in the solvent system; moreover, it made some very rough assumptions only as to the intermolecular interactions among the mobile phase constituents.This paper introduces a significant refinement to the already established retention model, which is based on the simple quantitative relationships between acetonitrile and tetrahydrofuran, and the remaining components of the ternary liquid system. The refined model is tested with same experimental data.     

A Siloxane Homopolymer with Interacting Ferrocenes as a New Material for the Preparation of Sensors Based on the Detection of Hydrogen Peroxide

The electrochemical characterization of a hydrogen peroxide sensor based on a ferrocene‐containing polymer electrochemically deposited onto a platinum electrode is described. The redox polymer consists of a siloxane‐based homopolymer, with pendant electronically communicated ferrocenyl moieties. The electrodes were used as the transducer for glucose and lactate‐sensing enzyme sensors. Amperometric biosensors were prepared by immobilization of glucose oxidase (Gox) or lactate oxidase (Lox) onto these modified electrodes. The steady‐state amperometric response of the sensors is investigated as a function of the applied potential and substrate concentration. Interferences, sensitivity and stability of the sensors were also studied.     

Thin-layer adsorption chromatography with mixed mobile phases. 4. Extension of Ościk's equation to heterogeneous adsorbents

In this paper the equation for thin-layer adsorption chromatography with multicomponent mobile phases, proposed by O?cik in 1965 is extended to energetically heterogeneous solid surfaces. Other forms of this equation, more convenient in practical applications, are presented. Model calculations are made for TLC with binary mobile phases according to the modified form of O?cik's equation. Finally, this equation is compared with that of Snyder.     

青蒿素及其一类物结构和合成的研究——Ⅸ.全合成青蒿素中若干关键化合物的合成

青蒿素是一个含有过氧基团的新型倍半萜内酯~([1]),它具有突出的抗疟作用~([2])。本文报道     

用L-脯氨酸衍生物作为手性流动相添加剂拆分对映异构体

用自制的N-十二酰基-L-脯氨酸和N-十二酰基-L-脯氨酸-3，5-二甲基苯胺两种L-脯氨酸衍生物作手性流动相添加剂，在氨丙基硅烷化硅胶柱上，用正己烷／异丙醇作流动相，对多种手性化合物进行了高效液相色谱拆分。实验结果表明：用N-十二酰基-L-脯氨酸作添加剂拆分的12种手性化合物，有8种手性化合物能得到拆分，具有较好的手性选择性。虽然用N-十二酰基-L-脯氨酸-3，5-二甲基苯胺作添加剂，手性选择性也较好，但由于含有苯环，紫外吸收增强，基线波动严重。     

锗的市场结构变化与光纤通信

介绍了锗在光纤通信中的作用，分析了世界光纤市场的变化及其对锗的市场结构的影响，预测近期国内锗的市场结构不会有大的变化。     

Computerized optimization of gradient elution conditions with ternary solvent mobile phases in RPLC

Summary In this work, an optimization procedure for gradient RPLC separation, using ternary mobile phases, is described. This procedure requires eight preliminary experiments in gradient elution mode to predict the retention surface for each solute over the whole triangular space. This is followed by computerized calculations to determine the best ternary gradient elution profile with respect to both selectivity and analysis time. The efficiency of this procedure from the point of view of rapidity and of accuracy, is illustrated for the specific separation of twelve phenyl urea herbicides.