Si微电阻桥温度分布与热传导特性的显微Raman光谱研究

采用显微Raman光谱方法对红外目标模拟器中重掺杂Si微电阻桥单元的热传导特性进行研究，根据Si桥的实际特性建立相应的Raman散射模型，通过测量Raman峰位的移动得到高功率激光辐照下测量点的温度.对Si桥桥面分别进行了沿某些特殊线段的逐点线扫描和覆盖全部桥面的面扫描，得到各点的温升及其分布.用基于有限元分析的软件结合Si桥结构参数对各测量点的温升进行了模拟计算，其结果在热导分布的基本趋势上与实验相一致.实验细致地揭示了热导分布的局域起伏，反映出实际器件的不均匀性，为改进器件设计、优化器件性能提供了实验依据. 关键词： Raman光谱 Si桥 温度分布 热导     

中外低保管理面面观

目前我国城市居民最低生活保障制度的执行情况进展良好。低保政策的执行在保障下岗和失业人员基本生活及促进就业和再就业等方面发挥了明显的作用。但贫困问题是一个世界性问题 ,我们应借鉴各国在缓解贫困方面的作法 ,促进我国城市扶贫工作的顺利进行     

炼镁还原罐材质的成份设计

本文针对炼镁还原罐在使用条件下的破坏形式及对该材质的成份设计进行了分析 ,还原罐材质在具有单一奥氏体的基础上 ,进行良好的合金化处理是提高其抗蠕变性和热强性的有效方法 ,对提高材质的使用寿命起到良好的作用。     

加热炉内板坯粘塑性下桡变形的研究

在加热妒内，由于高温及重力作用，板坯两端的悬臂将产生下桡变形。悬臂越长，下桡将越大，导致悬臂下桡部分与出口端墙相碰，影响出料而造成事故。本文对加热炉内板坯的下桡变形进行了分析计算。首先，建立了板坯的二维非稳态导热模型并用有限差分法计算了炉内板坯随时间的温度变化；然后建立了板坯悬臂粘塑性变形模型，用有限元法计算了高温条件下由重力引起的悬臂的下桡变形。由此理论模型计算出的板坯抽出温度与悬臂端下桡量与实测结果吻合良好，说明该理论模型及模型计算方法是正确的，可用于对装钢生产进行指导。     

超导在现代移动通信系统基站中的应用

在简要介绍现代移动通信系统的基础上．描述了在移动通信系统的基站中高温超导的一个应用事例——高温超导接收机前端。此项应用可以明显提高基站的灵敏度并增强其选择性。     

大型电站锅炉主蒸汽温度的模块化阶梯式动态矩阵控制

针对淮南平圩电厂#1锅炉主蒸汽温度难以自动调节的问题,在充分了解系统特性、综合考虑各个扰动因素后,作者引入10个影响因素,提出了采用模块化、阶梯式动态矩阵控制方案,成功地解决了该厂2008t/h锅炉主蒸汽温度难以自动调节的问题,使其控制指标达到540±3℃之内,优于国家标准540±4℃.这一实施方案能解决大惯性、大时延及多扰动系统控制问题,具有在线辨识、滚动优化和实时反馈等优点.     

Temperature‐modulated differential scanning calorimetry studies on the origin of double melting peaks in isothermally melt‐crystallized poly(L‐lactic acid)

In this work, the melting behaviors of nonisothermally and isothermally melt‐crystallized poly(L ‐lactic acid) (PLLA) from the melt were investigated with differential scanning calorimetry (DSC) and temperature‐modulated differential scanning calorimetry (TMDSC). The isothermal melt crystallizations of PLLA at a temperature in the range of 100–110 °C for 120 min or at 110 °C for a time in the range of 10–180 min appeared to exhibit double melting peaks in the DSC heating curves of 10 °C/min. TMDSC analysis revealed that the melting–recrystallization mechanism dominated the formation of the double melting peaks in PLLA samples following melt crystallizations at 110 °C for a shorter time (≤30 min) or at a lower temperature (100, 103, or 105 °C) for 120 min, whereas the double lamellar thickness model dominated the formation of the double melting peaks in those PLLA samples crystallized at a higher temperature (108 or 110 °C) for 120 min or at 110 °C for a longer time (≥45 min). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 466–474, 2007     

Lanthanum nitrate decomposition by both temperature programmed heating and citrate gel combustion

Thermal decomposition of lanthanum nitrate to lanthanum oxide was carried out by both temperature programmed heating (TPH) and citrate-gel combustion. The temperature programmed heating was carried out under flow of oxidizing (air), neutral (nitrogen) and reducing (25 vol.% hydrogen+argone mixture) gases, and the processes were controlled by simultaneous thermogravimetry and differential thermal analysis. It was shown that hydrogen atmosphere helps to reduce temperatures of all decomposition steps. The results of TPH were utilized to check the nature of residues in the products of lanthanum nitrate-to-oxide conversion performed via citrate-gel combustion technique.     

Amine‐blocked polyisocyanates. I. Synthesis of novel N‐methylaniline‐blocked polyisocyanates and deblocking studies using hot‐stage fourier transform infrared spectroscopy

A series of substituted N‐methylaniline‐blocked polyisocyanates based on 4,4′‐methylenebis(phenyl isocyanate) and poly(tetrahydrofuran) were prepared and characterized thoroughly with FTIR, ¹H NMR, and ¹³C NMR spectroscopy methods. Compared with unsubstituted N‐methylaniline, a blocking agent with an electron‐releasing substituent at the para position took a shorter time, whereas those with an electron‐releasing substituent at the ortho position or an electron‐withdrawing substituent at the ortho and para positions took longer times for the blocking reaction. The thermal dissociation reactions of blocked polyisocyanates were carried out with an FTIR spectrophotometer attached to hot‐stage accessories under dynamic and isothermal conditions. The dynamic method was used to determine the deblocking temperature, and the isothermal method was used to calculate the deblocking kinetics and activation parameters. The cure times of blocked polyisocyanates with hydroxyl‐terminated polybutadiene were also determined. The deblocking temperatures, the results of cure‐time studies, and the kinetic parameters revealed that the thermal dissociation of the N‐methylaniline‐blocked polyisocyanates was retarded by electron‐donating substituents and facilitated by electron‐withdrawing substituents. The action of N‐methylanilines as blocking agents for isocyanate was explained by the formation of a four‐center, intramolecularly hydrogen‐bonded ring structure during the thermal dissociation of the blocked polyisocyanates. The formation of such a hydrogen‐bonded ring structure was confirmed and supported by variable‐temperature ¹H NMR studies and entropy parameters, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1557–1570, 2007     

热连轧精轧机组温度模型的改进

从实际生产数据入手,研究了温度模型设定精度的现状及设定精度与各影响因素之间的关系,同时还消化了原来的温度模型程序并将其移植到微机上.经大量的离线统计回归分析,提出了一个行之有效的温度模型改进方案.该改进方案的思路同样适合其他热轧生产线.