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61.
黄大明柳小妮 宋百敏陈俊 Masae Shiyomi 王昱生 Shigeo Takahashi Yoshimichi Hori Yasuo Yamamura 《清华大学学报》2007,12(4):413-423
The vegetation spatial heterogeneity and ecological characteristics in different soil regions were analyzed by surveying the vegetation in 12 different soil regions of Inner Mongolia, China, including conifer- ous-broadleaf deciduous forests, shrub, grassland, and desert regions with 1122 large 2 cm × 2 cm quad- rats (actual size 30 km × 30 km, referred to as L-quadrat hereafter) in about 1.18 million km2. Each L- quadrat was divided into four small 1 cm × 1 cm quadrats (actual size 15 km × 15 km, S-quadrat). The vegetation was analyzed based on the beta-binomial distribution to describe the frequency of occurrence and spatial heterogeneity for each kind of vegetation. The weighted average of the heterogeneity of all vegeta- tion in the same soil region provides a measure of the soil regional landscape level heterogeneity which de- scribes the spatial complexity of the regional landscape composition of the existing vegetation. Comparison of the vegetation characteristics in the 12 soil regions shows that, the calcic gray soil has the highest average vegetation type per quadrat. The largest soil region is calcic chestnut soil and has the most vegetation types. Every soil region has its own dominant vegetation sequence which dominates in occurrence and dominant vegetation types which dominates in spatial heterogeneity. For the Inner Mongolian vegetation, the weighted average of the heterogeneity is 0.60 and the vegetation diversity index is 4.47. 相似文献
62.
D. Raghavan X. Gu T. Nguyen M. Vanlandingham 《Journal of Polymer Science.Polymer Physics》2001,39(13):1460-1470
Characterization of polymer coatings microstructure is critical to the fundamental understanding of the corrosion of coated metals. An approach for mapping the chemical heterogeneity of a polymer system using chemical modification and tapping‐mode atomic force microscopy (TMAFM) is demonstrated. This approach is based on the selective degradation of one of the phases in a multiphase polymer blend system and the ability of TMAFM to provide nanoscale lateral information about the different phases in the polymer system. Films made of a 70:30 polyethyl acrylate/polystyrene (PEA/PS) blend were exposed to a hydrolytic acidic environment and analyzed using TMAFM. Pits were observed to form in the PEA/PS blend films, and this degradation behavior was similar to that of the PEA material. Using these results, the domains in the 70:30 blend were identified as the PS‐rich regions and the matrix as the PEA‐rich region. This conclusion was confirmed by Fourier transform infrared‐attenuated total reflection analyses that revealed the hydrolysis of the PEA material. TMAFM phase imaging was also used to follow pit growth of the blend as a function of exposure time. The usefulness of the chemical modification/AFM imaging approach in understanding the degradation process of a coating film is discussed. © 2001 John Wiley & Sons, Inc. J Polym Sci B Part B: Polym Phys 39: 1460–1470, 2001 相似文献
63.
Dr. Zhicheng Yang Dr. Xiaoxiao Fan He Li Xinsheng Li Sifan Li Prof. Zhiyun Zhang Prof. Hui Lin Prof. Jun Qian Prof. Jianli Hua 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(57):14240-14249
Organic small-molecule fluorophores with near-infrared IIa (NIR-IIa) emission have great potential in pre-clinical detection and inoperative imaging due to the high-spatial resolution and deep penetration. However, developments of the NIR-IIa fluorophores are still facing considerable challenges. In this work, a series of diketopyrrolopyrrole (DPP)-based fluorophores were designed and synthesized. Subsequently, nanomaterial T25@F127 with significant NIR-IIa emission properties was rationally prepared by encapsulating DPP-based fluorophore T25 , and was selected for fluorescence angiography and cerebral vascular microscopic imaging with nearly 800 μm penetrating depth and excellent signal-background ratio of 4.07 and 2.26 (at 250 and 400 μm), respectively. Furthermore, the nanomaterial T25@cRGD with tumor targeting ability can image tiny metastatic tumor on intestine with a small size of 0.3 mm×1.0 mm and high-spatial resolution (SBR=3.84). This study demonstrates that the nanomaterials which encapsulated T25 behave as excellent NIR-IIa fluorescence imaging agents and have a great potential for in vivo biological application. 相似文献
64.
施建成 《四川大学学报(自然科学版)》2010,47(6)
本文采用数值模拟的方法研究了参数不均匀性,耦合和噪音的协作效应对单向耦合布鲁塞尔体系相干共振的影响作用,其中噪音仅加于无耦合的控制体系。研究结果发现:具有相同控制参数的耦合体系,在耦合和噪音协作效应的影响下,存在最佳的耦合强度使控制体系的相干共振在受控制体系中得到增强。对于不同控制参数的耦合体系,参数不均匀性,耦合和噪音的协作效应对控制体系相干共振的增强或维持起决定性的作用。另外,当耦合强度和噪音达到临界值时,参数不均匀性的作用消失,此时控制体系和受控制体系之间出现了动力学行为的同步现象,此时意味着体系中的相干共振信号不能进一步得到改变,整个耦合体系的动力学行为对于噪音和耦合具有鲁棒性。 相似文献
65.
Sampling errors can be divided into two classes, incorrect sampling and correct sampling errors. Incorrect sampling errors arise from incorrectly designed sampling equipment or procedures. Correct sampling errors are due to the heterogeneity of the material in sampling targets. Excluding the incorrect sampling errors, which can all be eliminated in practice although informed and diligent work is often needed, five factors dominate sampling variance: two factors related to material heterogeneity (analyte concentration; distributional heterogeneity) and three factors related to the sampling process itself (sample type, sample size, sampling modus). Due to highly significant interactions, a comprehensive appreciation of their combined effects is far from trivial and has in fact never been illustrated in detail. Heterogeneous materials can be well characterized by the two first factors, while all essential sampling process characteristics can be summarized by combinations of the latter three. We here present simulations based on an experimental design that varies all five factors. Within the framework of the Theory of Sampling, the empirical Total Sampling Error is a function of the fundamental sampling error and the grouping and segregation error interacting with a specific sampling process. We here illustrate absolute and relative sampling variance levels resulting from a wide array of simulated repeated samplings and express the effects by pertinent lot mean estimates and associated Root Mean Squared Errors/sampling variances, covering specific combinations of materials’ heterogeneity and typical sampling procedures as used in current science, technology and industry. Factors, levels and interactions are varied within limits selected to match realistic materials and sampling situations that mimic, e.g., sampling for genetically modified organisms; sampling of geological drill cores; sampling during off-loading 3-dimensional lots (shiploads, railroad cars, truckloads etc.) and scenarios representing a range of industrial manufacturing and production processes. A new simulation facility “SIMSAMP” is presented with selected results designed to show also the wider applicability potential. This contribution furthers a general exposé of all essential effects in the regimen covered by “correct sampling errors”, valid for all types of materials in which non-bias sampling can be achieved. 相似文献
66.
67.
Marie‐Anne Guerry 《商业与工业应用随机模型》2008,24(1):13-20
A methodology is presented to deal with heterogeneity due to observable variables in modeling personnel systems. For a manpower system, a model based on personnel profiles is introduced. The proposed algorithm concerns an analysis of the evolution of personnel profiles under time‐discrete Markov assumptions. In this way, based on an historical personnel database, the estimation of transition probabilities of profiles as well as the computation of forecasts on the evolution of the manpower system can be found. Based on the presented procedure, a policy supporting software package has been developed for the Belgian Federal Government (research project financed by Federaal Wetenschapsbeleid). Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
68.
We present an overview of the potential applicability of fractal concepts to various aspects of transport phenomena in heterogeneous porous media. Three examples of phenomena where a fractal approach should prove illuminating are presented. In the first example we consider pore level heterogeneities as typified by pore surface roughness. We suggest that roughness may be usefully modelled by fractal curves and surfaces and also cite experimental evidence for regarding pores as fractals. In the second example we consider a fractal network approach to modelling large-scale heterogeneities. The presence of features on all length scales in simple fractal models should capture the essential role played by the presence of heterogeneities on many scales in natural reservoirs. Studies of transport phenomena in such models may yield valuable insights into the problems of macroscopic dispersion. The final example concerns dispersion in multiphase flow. Here the fractal character is attributed to the distribution of the fluid phases rather than the porous medium itself. Again studies of transport phenomena in simple fractal models should help to clarify various problems associated with the corresponding phenomena in real reservoirs. 相似文献
69.
70.
The adsorption isotherms of four activated carbons (Norit RB1, Chemviron BPL, Monolit, and Ambersorb-572) have been examined by nitrogen adsorption at 77.5 K. A method for adsorption potential distribution calculation has been proposed based on the adsorption isotherms. This distribution provides information about possible changes in the Gibbs free energy caused by the energetic and geometrical heterogeneities of an activated carbon as well as by the adsorbate-related entropic effects. The general character of the adsorption potential distribution is clearly visible by its simple relation to the micropore and mesopore distribution. 相似文献